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Basic Information
CAS No.: 2916-68-9
Name: 2-(Trimethylsilyl)ethanol
Article Data: 22
Molecular Structure:
Molecular Structure of 2916-68-9 (2-(Trimethylsilyl)ethanol)
Formula: C5H14OSi
Molecular Weight: 118.251
Synonyms: 4-04-00-03951 (Beilstein Handbook Reference);Silane, (2-hydroxyethyl)trimethyl-;2-trimethylsilylethanol;Ethanol, 2- (trimethylsilyl)-;
EINECS: 220-844-5
Density: 0.819/cm3
Melting Point: 0oC
Boiling Point: 144.962 °C at 760 mmHg
Flash Point: 50.556 °C
Solubility: soluble in water
Appearance: clear colourless liquid
Hazard Symbols: IrritantXi,FlammableF
Risk Codes: 10-36/37/38
Safety: 16-37/39-26
Transport Information: UN 1987 3/PG 3
PSA: 20.23000
LogP: 1.31690
Synthetic route
72610-05-0

B-<2-(trimethylsilyl)ethyl>9-borabicyclo<3.3.1>nonane

A

2916-68-9

2-(Trimethylsilyl)ethanol

B

23418-82-8

cis-1,5-cyclooctanediol

Conditions
ConditionsYield
With sodium hydroxide; dihydrogen peroxide In water for 1h; Heating;A 100%
B n/a

Trimethylsilanyl-(2,8,9-trioxa-5-aza-1-germa-bicyclo[3.3.3]undec-1-yl)-acetic acid methyl ester

2916-68-9

2-(Trimethylsilyl)ethanol

Conditions
ConditionsYield
With lithium aluminium tetrahydride In diethyl ether for 16h; Ambient temperature;98%
754-05-2

ethenyltrimethylsilane

A

13246-39-4

(+-)-1-(trimethylsilyl)ethanol

B

2916-68-9

2-(Trimethylsilyl)ethanol

Conditions
ConditionsYield
With oxonium; oxygen; diisobutyl(2,6-di-tert-butyl-4- methylphenoxy)aluminum Product distribution; regioselectivity of hydroalumination;A 12%
B 88%
With sodium hydroxide; borane-THF; water; dihydrogen peroxide In tetrahydrofuran at 0℃; for 0.25h; Product distribution; other temperatures, other times, other stoichiometry;
Yield given. Multistep reaction. Yields of byproduct given;
Stage #1: ethenyltrimethylsilane With triethylsilane; boron trichloride at -78 - 20℃;
Stage #2: With sodium hydroxide; dihydrogen peroxide In tetrahydrofuran at 50 - 55℃; for 1h; Further stages. Title compound not separated from byproducts.;
Stage #1: ethenyltrimethylsilane With diisopinocamphenylboron chloride
Stage #2: With sodium hydroxide; dihydrogen peroxide Further stages. Title compound not separated from byproducts.;
4071-88-9

trimethylsilanyl-acetic acid ethyl ester

2916-68-9

2-(Trimethylsilyl)ethanol

Conditions
ConditionsYield
With borane-THF In tetrahydrofuran for 48h; Ambient temperature;78.1%
With lithium aluminium tetrahydride In diethyl ether Heating;
3938-95-2

2,2-dimethyl-propanoic acid ethyl ester

2916-68-9

2-(Trimethylsilyl)ethanol

Conditions
ConditionsYield
With lithium aluminium tetrahydride
2916-76-9

methyl (trimethylsilyl)acetate

2916-68-9

2-(Trimethylsilyl)ethanol

Conditions
ConditionsYield
With lithium aluminium tetrahydride
50-00-0

formaldehyd

13170-43-9

(trimethylsilyl)methylmagnesium chloride

2916-68-9

2-(Trimethylsilyl)ethanol

5578-41-6

(2-acetoxy-ethyl)-dichloro-methyl-silane

676-58-4

methylmagnesium chloride

2916-68-9

2-(Trimethylsilyl)ethanol

Conditions
ConditionsYield
In diethyl ether
754-05-2

ethenyltrimethylsilane

2916-68-9

2-(Trimethylsilyl)ethanol

Conditions
ConditionsYield
(i) NaBH4, BF3-Et2O, diglyme, (ii) aq. H2O2, NaOH; Multistep reaction;
16046-10-9

2-(trimethylsilyl)ethyl acetate

A

2916-68-9

2-(Trimethylsilyl)ethanol

B

64-19-7

acetic acid

Conditions
ConditionsYield
With sodium chloride at 25℃; Rate constant; Equilibrium constant; acetylcholinesterase, pH 7.8;
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    Product Name: 2-(Trimethylsilyl)ethanol Synonyms: 2-HYDROXYETHYLTRIMETHYLSILANE;2-(TRIMETHYLSILYL)ETHANOL;2-(TRIMETHYLSILYL)ETHANAL;2-(trimethylsilyl)-ethano;TIMTEC-BB SBB009030;2-(TRIMETHYLSILYL)ETHANOL, 97%2-(TRIMETHYLSILYL)ETHANOL, 97%2-(TRI

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Chemistry

   The molecular formula of  2-(Trimethylsilyl)ethanol(2916-68-9) is C5H14OSi and its formula weight is 118.25g/mol.Its EINECS is 220-844-5.Its liansport information is UN 1987.The density of  2-(Trimethylsilyl)ethanol(2916-68-9) is 0.825g/cm3 and it has a melting point of  -46.18°C.The boiling point is 145 °C at  760 mmHg.The refractive index is about n20/D 1.423(lit.) and molar refractivity is 35.46 cm3.Molar volume is 144.3 cm3 and  polarizability is 14.05 10-24cm3. Surface tension is 20.4 dyne/cm and enthalpy of vaporization is 44.5 kJ/mol.Its flash point is 50.6 °C  and the vapor pressure is 1.97 mmHg at 25°C.
   The chemical synonyms of 2-(Trimethylsilyl)ethanol(2916-68-9) are 2-HYDROXYETHYLTRIMETHYLSILANE;2-(TRIMETHYLSILYL)ETHANOL;2-(TRIMETHYLSILYL)ETHANAL;TIMTEC-BB SBB009030;2-(trimethylsilyl)-ethano;Ethanol, 2-(trimethylsilyl)-;Silane, (2-hydroxyethyl)trimethyl- and trimethylsilylethanol.Its product categories is Alcohols and Derivatives;Si (Classes of Silicon Compounds);Si-(C)4 Compounds;Silicon Compounds (for Synthesis) and Synthetic Organic Chemistry.The molecular structure of 2-(Trimethylsilyl)ethanol(2916-68-9) is .

Safety Profile

Hazard symbols is Xi, F.
Risk statements is 10-36/37/38.
10:  Flammable.
36/37/38:  Irritating to eyes, respiratory system and skin.
Safety statements is 16-37/39-26. 
16:  Keep away from sources of ignition - No smoking.
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
37/39:  Wear suitable gloves and eye/face protection.
Hazard note is flammable.
HazardClass is 3.

Specification

Its extinguishing agents is foam ,carbon dioxide, water spray and sand.