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298-14-6

Basic Information
CAS No.: 298-14-6
Name: Potassium hydrogencarbonate
Molecular Structure:
Molecular Structure of 298-14-6 (Potassium hydrogencarbonate)
Formula: KHCO3
Molecular Weight: 100.11 .
Synonyms: Monopotassium carbonate;EPA Pesticide Chemical Code 073508;Purple K;Potassium acid carbonate;Kaligreen;potassium hydroxyformate;Potassium hydrogen carbonate;Carbonic acid,compounds,monopotassium salt;
EINECS: 206-059-0
Density: 2,17 g/cm3
Melting Point: 292 °C
Boiling Point: 333.6 °C at 760 mmHg
Flash Point: 169.8 °C
Solubility: 1 M at 20 °C in water
Appearance: white powder or crystals
Hazard Symbols: FlammableF, ToxicT, CorrosiveC, IrritantXi
Risk Codes: 22-35
Safety: 24/25-45-36/37/39-26
Transport Information:
PSA: 60.36000
LogP: -1.11230
Synthetic route
124-38-9

carbon dioxide

201230-82-2

carbon monoxide

584-08-7

potassium carbonate

A

590-29-4

potassium formate

B

583-52-8

potassium oxalate

C

298-14-6

potassium hydrogencarbonate

Conditions
ConditionsYield
In neat (no solvent) High Pressure; 2 h at 380°C; cooling, dissolution in water, addn. of HClO4; HPLC;A 0%
B 1%
C 0.8%
124-38-9

carbon dioxide

584-08-7

potassium carbonate

298-14-6

potassium hydrogencarbonate

Conditions
ConditionsYield
In ethylene glycol; diethylene glycol at 22℃; for 1h;
at 71 - 130℃;
at 71 - 130℃;

uranyl(VI) nitrate

584-08-7

potassium carbonate

A

uranyl hydroxide

B

298-14-6

potassium hydrogencarbonate

Conditions
ConditionsYield
In not given orange red ppte.;;
In not given orange red ppte.;;
7783-06-4

hydrogen sulfide

584-08-7

potassium carbonate

A

potassium hydrosulfide

B

298-14-6

potassium hydrogencarbonate

Conditions
ConditionsYield
In not given
In not given desulfuration of gases under pressure;

potassium hydrosulfide

124-38-9

carbon dioxide

A

7783-06-4

hydrogen sulfide

B

298-14-6

potassium hydrogencarbonate

Conditions
ConditionsYield
In not given

potassium chromate

A

potassium dichromate

B

298-14-6

potassium hydrogencarbonate

Conditions
ConditionsYield
With carbon dioxide; water In water under CO2 pressure;
7758-09-0

potassium nitrite

7748-25-6

potassium chloroacetate

A

75-52-5

nitromethane

B

298-14-6

potassium hydrogencarbonate

Conditions
ConditionsYield
With water In water byproducts: KCl;
With H2O In water byproducts: KCl;

potassium sulfate

calcium carbonate

syngenite

B

298-14-6

potassium hydrogencarbonate

Conditions
ConditionsYield
With carbon dioxide; water In water reactn. of K2SO4 with CaCO3 in presence of H2O and CO2 under pressure at normal or lowered temp.; obtaining KHCO3 in soln. and K2Ca(SO4)2*H2O as bottom compound;;
With carbon dioxide; water In water reactn. of K2SO4 with CaCO3 in presence of H2O and CO2 under pressure at normal or lowered temp.; obtaining KHCO3 in soln. and K2Ca(SO4)2*H2O as bottom compound;;

ammonium carbonate

584-08-7

potassium carbonate

298-14-6

potassium hydrogencarbonate

Conditions
ConditionsYield
In not given 75°C,from concd. K2CO3 soln.,then cooling;
In not given 75°C,from concd. K2CO3 soln.,then cooling;
124-38-9

carbon dioxide

584-08-7

potassium carbonate

298-14-6

potassium hydrogencarbonate

Conditions
ConditionsYield
In neat (no solvent) from anhydrous materials;0%
in presence of aq. ethanol;
With potato starch flour In not given from concd. K2CO3 soln.,evapn. to dry,glowing,react. with CO2;
1633-05-2

strontium(II) carbonate

barium carbonate

298-14-6

potassium hydrogencarbonate

Conditions
ConditionsYield
in 3 weeks;0%
in 3 weeks;0%
1633-05-2

strontium(II) carbonate

7646-93-7

potassium hydrogensulfate

298-14-6

potassium hydrogencarbonate

Conditions
ConditionsYield
in 3 weeks;0%
in 3 weeks;0%
124-38-9

carbon dioxide

7440-09-7

potassium

A

590-29-4

potassium formate

B

298-14-6

potassium hydrogencarbonate

ammonium carbonate

dipotassium hydrogenphosphate

A

potassium dihydrogenphosphate

B

298-14-6

potassium hydrogencarbonate

Conditions
ConditionsYield
In water byproducts: KH2PO4;
In water byproducts: KH2PO4;

potassium sulfate

barium carbonate

A

barium sulfate

B

298-14-6

potassium hydrogencarbonate

Conditions
ConditionsYield
In water 70-80°C,in autoclave,2 atm CO2-pressure,2 h; crystn. by cooling;
In water 70-80°C,in autoclave,2 atm CO2-pressure,2 h; crystn. by cooling;
Conditions
ConditionsYield
With water cooling; leaching at 30-40°C,filtering,crystg.;
With H2O cooling; leaching at 30-40°C,filtering,crystg.;

trimethylammonium bicarbonate

124-38-9

carbon dioxide

potassium chloride

298-14-6

potassium hydrogencarbonate

Conditions
ConditionsYield
In not given excess of trimethylammonium hydrocarbonate, lower temp., higher pressure, stirring;
In not given excess of trimethylammonium hydrocarbonate, lower temp., higher pressure, stirring;
124-38-9

carbon dioxide

potassium chloride

298-14-6

potassium hydrogencarbonate

Conditions
ConditionsYield
Electrolysis; elect. of a KCl soln. contg. KHCO3, addn. of KCl, satn. with CO2 to precipitate KHCO3; soln. is recycled;
With ammonia In ammonia react. of the formed potassium carbonate with CO2-NH3-compounds;
With ammonia In ammonia react. of the formed potassium carbonate with CO2;

ammonium carbamate

sylvite

A

144-55-8

sodium hydrogencarbonate

B

298-14-6

potassium hydrogencarbonate

dipotassium hydrogenphosphate

1066-33-7

ammonium bicarbonate

A

potassium dihydrogenphosphate

B

298-14-6

potassium hydrogencarbonate

Conditions
ConditionsYield
In water
In water
589-97-9, 16645-68-4

potassium percarbonate

298-14-6

potassium hydrogencarbonate

Conditions
ConditionsYield
With water; mercury In water byproducts: H2O2, O2; catalytic decompn. of K2C2O6 soln. by shaking with Hg;;

dipotassium DL-malate

A

584-08-7

potassium carbonate

B

298-14-6

potassium hydrogencarbonate

Conditions
ConditionsYield
manganese(II) sulfate In water Irradiation (UV/VIS); illumination for several days;
iron(III) sulfate In water Irradiation (UV/VIS); illumination for several days;
uranyl sulfate In water Irradiation (UV/VIS); illumination for several days;

A

584-08-7

potassium carbonate

B

298-14-6

potassium hydrogencarbonate

Conditions
ConditionsYield
manganese(II) sulfate In water Irradiation (UV/VIS); illumination for several days;
iron(III) sulfate In water Irradiation (UV/VIS); illumination for several days;
uranyl sulfate In water Irradiation (UV/VIS); illumination for several days;

potassium carbonate sesquihydrate

124-38-9

carbon dioxide

298-14-6

potassium hydrogencarbonate

A

584-08-7

potassium carbonate

B

298-14-6

potassium hydrogencarbonate

Conditions
ConditionsYield
manganese(II) sulfate In water Irradiation (UV/VIS); illumination for several days;
iron(III) sulfate In water Irradiation (UV/VIS); illumination for several days;
uranyl sulfate In water Irradiation (UV/VIS); illumination for several days;
124-38-9

carbon dioxide

potassium hydroxide

298-14-6

potassium hydrogencarbonate

Conditions
ConditionsYield
In ethanol; water
In ethanol; water
590-29-4

potassium formate

1066-33-7

ammonium bicarbonate

298-14-6

potassium hydrogencarbonate

Conditions
ConditionsYield
in alcohol;
in alcohol;
590-28-3

potassium cyanate

A

7664-41-7

ammonia

B

298-14-6

potassium hydrogencarbonate

17455-13-9

18-crown-6 ether

298-14-6

potassium hydrogencarbonate

CHO3(1-)*C12H24KO6

Conditions
ConditionsYield
In water at 20℃; for 12h;100%
52490-94-5

[dichloro(p-cymene)(triphenylphosphane)ruthenium(II)]

298-14-6

potassium hydrogencarbonate

Ru(2-O2CO)(PPh3)(p-cymene)*H2O

Conditions
ConditionsYield
In acetone for 3h; Inert atmosphere; Schlenk technique;100%
138-41-0

4-(aminosulfonyl)-benzoic acid

298-14-6

potassium hydrogencarbonate

117662-91-6

potassium 4-sulfamoylbenzoate

Conditions
ConditionsYield
In water at 45℃; for 0.5h;98%

C13H17N*ClH

298-14-6

potassium hydrogencarbonate

C14H17NO2

Conditions
ConditionsYield
With silver carbonate In water at 50℃; for 72h; Green chemistry;98%
7758-09-0

potassium nitrite

7446-09-5

sulfur dioxide

298-14-6

potassium hydrogencarbonate

dipotassium hydroxylamine-N,N'-disulfonate dihydrate

Conditions
ConditionsYield
In water cooling down to 0°C, shaking; recrystn.;97%
298-14-6

potassium hydrogencarbonate

85100-77-2

1-n-butyl-3-methylimidazolim bromide

366491-15-8

1-butyl-3-methyl-1H-imidazol-3-iumhydrogencarbonate

Conditions
ConditionsYield
Ionic liquid; Green chemistry;97%
In methanol at 20 - 50℃; for 66h;87%
In methanol at 20℃; for 36h;
107-20-0

2-chloroethanal

298-14-6

potassium hydrogencarbonate

6291-84-5

N-Methyl-1,3-propanediamine

1580482-35-4

(RS)-1-methylhexahydro[1,3]oxazolo[3,4-a]pyrimidin-6-one

Conditions
ConditionsYield
In water at 20℃; for 10h; Green chemistry;97%

C9H11BF3N

298-14-6

potassium hydrogencarbonate

1370291-56-7

potassium benzoyltrifluoroborate

Conditions
ConditionsYield
In water; N,N-dimethyl-formamide at 20℃;97%

C7H9BF3NS

298-14-6

potassium hydrogencarbonate

1622923-64-1

potassium 3-thiophenoyltrifluoroborate

Conditions
ConditionsYield
In water; N,N-dimethyl-formamide at 20℃;97%
298-14-6

potassium hydrogencarbonate

590-29-4

potassium formate

Conditions
ConditionsYield
With hydrogen In water at 100℃; under 30003 Torr; for 10h; Temperature; Pressure; Autoclave;96.8%
With nickel; hydrogen In water at 200℃; under 45004.5 Torr; for 2h; Green chemistry;92.1%
With hydrogen; palladium In water with Pd -black,30-60 atm,70-95°C,24 h;70%
7386-43-8

2-chloro-4,6-bis-(n-butylamino)-1,3,5-triazine

298-14-6

potassium hydrogencarbonate

109-73-9

N-butylamine

16268-97-6

2,4,6-tris(n-butylamino)-1,3,5-triazine

Conditions
ConditionsYield
In water; toluene; acetonitrile96%
298-14-6

potassium hydrogencarbonate

65039-08-9

3-ethyl-1-methyl-1H-imidazol-3-ium bromide

947601-94-7

1-ethyl-3-methyl-1H-imidazol-3-ium hydrogencarbonate

Conditions
ConditionsYield
Ionic liquid; Green chemistry;96%
In methanol at 20℃; for 36h;
107-20-0

2-chloroethanal

7328-91-8

2,2-Dimethyl-1,3-diaminopropane

298-14-6

potassium hydrogencarbonate

1580482-20-7

(RS)-3,3-dimethylhexahydro[1,3]oxazolo[3,4-a]pyrimidin-6-one

Conditions
ConditionsYield
In water at 20℃; for 10h; Green chemistry;96%
934008-48-7

1,3-bis(4-iodo-2,6-diisopropylphenyl)-1H-imidazol-3-ium chloride

298-14-6

potassium hydrogencarbonate

1,3-bis(4-iodo-2,6-diisopropylphenyl)-1H-imidazol-3-ium bicarbonate

Conditions
ConditionsYield
In methanol at 20℃; for 48h;96%

C11H12BF3N2

298-14-6

potassium hydrogencarbonate

potassium trifluoro(1H-indole-5-carbonyl)borate

Conditions
ConditionsYield
In water; N,N-dimethyl-formamide at 20℃;96%
With water In N,N-dimethyl-formamide29 mg

C10H10BF6N

298-14-6

potassium hydrogencarbonate

potassium trifluoro(4-(trifluoromethyl)benzoyl)borate

Conditions
ConditionsYield
In water; N,N-dimethyl-formamide at 20℃;96%
298-14-6

potassium hydrogencarbonate

27143-12-0

ethyl chloro[(2,4-dichlorophenyl)hydrazono]acetate

ethyl 1-(2,4-dichloro-phenyl)-5-isopropyl-1H-pyrazole-3-carboxylate

Conditions
ConditionsYield
With hydrogenchloride In 2-methoxy-3-methyl-but-1-ene; water95%

copper(II) nitrate trihydrate

50-01-1

guanidine hydrochloride

584-08-7

potassium carbonate

298-14-6

potassium hydrogencarbonate

guanidinium copper double carbonate

Conditions
ConditionsYield
In water Cu(NO3)2*3H2O (0.81 mmol) dissolved in soln. of K2CO3 and KHCO3 in H2O, soln. of guanidinium chloride (4.9 mmol) in H2O added; crystals collected after 4 d, washed with water, dried in air; elem. anal.;95%

7K(1+)*4H(1+)*AsW18O62(11-)*18H2O=K7[H4AsW18O62]*18H2O

298-14-6

potassium hydrogencarbonate

α-K11[H4AsW17O61]*18H2O

Conditions
ConditionsYield
In water W complex dissolved in H2O with stirring, treated with KHCO3, stirred for 1 h; filtered, washed twice (EtOH), twice (diethyl ether), air-dried, elem. anal.;95%
501-36-0

(E)-5-[2-4-(hydroxyphenyl)ethenyl]-1,3-benzenediol

298-14-6

potassium hydrogencarbonate

(E)-2,6-dihydroxy-4-(4-hydroxystyryl)benzoic acid

Conditions
ConditionsYield
With Lyophilized E. coli whole cells overexpressed Rhizobium sp. 2,6-dihydroxybenzoic acid decarboxylase In methanol; aq. phosphate buffer at 30℃; for 24h; pH=8.5; Catalytic behavior; Reagent/catalyst; Solvent; Enzymatic reaction; regioselective reaction;95%

C12H15N*ClH

298-14-6

potassium hydrogencarbonate

C13H15NO2

Conditions
ConditionsYield
With silver carbonate In water at 50℃; for 48h; Green chemistry;95%

C17H15N*ClH

298-14-6

potassium hydrogencarbonate

C18H15NO2

Conditions
ConditionsYield
With silver carbonate In water at 50℃; for 18h; Green chemistry;95%

C10H11N*ClH

298-14-6

potassium hydrogencarbonate

C11H11NO2

Conditions
ConditionsYield
With silver carbonate In water at 50℃; for 18h; Green chemistry;95%

C15H13N*ClH

298-14-6

potassium hydrogencarbonate

C16H13NO2

Conditions
ConditionsYield
With silver carbonate In water at 50℃; for 18h; Catalytic behavior; Reagent/catalyst; Temperature; Green chemistry;95%

C12H15NO*ClH

298-14-6

potassium hydrogencarbonate

C13H15NO3

Conditions
ConditionsYield
With silver carbonate In water at 50℃; for 12h; Green chemistry;95%

C11H13BF3NO2

298-14-6

potassium hydrogencarbonate

C9H7BF3O3(1-)*K(1+)

Conditions
ConditionsYield
In water; N,N-dimethyl-formamide at 20℃;95%

K6[α-As2Mo6W12O62]*12H2O

298-14-6

potassium hydrogencarbonate

K10[α2-As2Mo5W12O61]*21H2O

Conditions
ConditionsYield
In water Mo-W complex dissolved in H2O, treated with 1 M KHCO3, settled for 45 min; filtered, washed twice (EtOH), twice (ethyl ether), dried (air), elem. anal.;94.9%
880-78-4

pentafluoronitrobenzen

298-14-6

potassium hydrogencarbonate

1193-24-4

4,6-pyrimidinediol

4,6-bis(4-nitro-3-hydroxy-2,5,6-trifluorophenoxy)pyrimidine

Conditions
ConditionsYield
With hydrogenchloride; potassium carbonate In nitrogen; water; dimethyl sulfoxide; ethyl acetate94%
107-20-0

2-chloroethanal

298-14-6

potassium hydrogencarbonate

109-76-2

Trimethylenediamine

1580482-17-2

(RS)-hexahydro[1,3]oxazolo[3,4-a]pyrimidin-6-one

Conditions
ConditionsYield
In water at 20℃; for 10h; Green chemistry;94%
298-14-6

potassium hydrogencarbonate

106-96-7

propargyl bromide

57272-05-6

prop-2-yn-1-yl hydrogen carbonate

Conditions
ConditionsYield
In 5,5-dimethyl-1,3-cyclohexadiene at 120 - 140℃; for 36h; Industrial scale;94%
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    Potassium hydrogencarbonate 298-14-6

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Chemistry

Molecular Structure:

Molecular Formula: CHKO3
Molecular Weight: 100.1151
IUPAC Name: Potassium hydrogen carbonate
Synonyms of Potassium Bicarbonate (CAS NO.298-14-6): CCRIS 3510 ; Carbonic acid, monopotassium salt ; EINECS 206-059-0 ; EPA Pesticide Chemical Code 073508 ; Monopotassium carbonate ; Potassium acid carbonate ; Potassium hydrogen carbonate ; UNII-HM5Z15LEBN ; Carbonic acid, potassium salt (1:1) ; Potassium hydrogencarbonate
CAS NO: 298-14-6
Classification Code: Pharmaceutic necessity
Product Categories: Iridoids
Melting point: 292 °C 
Flash Point: 169.8 °C
Enthalpy of Vaporization: 63.37 kJ/mol
Boiling Point: 333.6 °C at 760 mmHg
Vapour Pressure: 2.58E-05 mmHg at 25°C 
 Potassium Bicarbonate (CAS NO.298-14-6) bicarbonate is a colorless, odorless, slightly basic, salty substance.

Uses

 Potassium Bicarbonate (CAS NO.298-14-6) is used as a production of potassium carbonate, potassium acetate, potassium arsenite etc, also used in medicine, food, fire extinguishing agents, etc.

Production

 Potassium bicarbonateis (CAS NO.298-14-6) manufactured by reacting potassium carbonate with carbon dioxide and water : 
K2CO3 + CO2 + H2O → 2 KHCO3
It occurs as a crystal or a soft white granular powder.

Safety Profile

Hazard Codes: FlammableF,ToxicT,CorrosiveC,IrritantXi
Risk Statements: 22-35 
R22: Harmful if swallowed. 
R35: Causes severe burns.
Safety Statements: 24/25-45-36/37/39-26 
S24/25: Avoid contact with skin and eyes. 
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection. 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
WGK Germany  1
F: 3
 

 

Specification

 Potassium Bicarbonate (CAS NO.298-14-6) bicarbonate is very rarely found in its natural form, the mineral called kalicinite.