CAS No.3077-12-1,2,2'-(P-TOLYLIMINO)DIETHANOL Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	3077-12-1
Name:	2,2'-(P-TOLYLIMINO)DIETHANOL
Article Data:	9

Formula:	C₁₁H₁₇NO₂
Molecular Weight:	195.261
Synonyms:	Ethanol,2,2'-(p-tolylimino)di- (6CI,7CI,8CI);2,2'-(p-Tolylimino)diethanol;Diethylol-p-toluidine;N,N-Bis(2-hydroxyethyl)-4-methylaniline;N,N-Bis(2-hydroxyethyl)-4-toluidine;N,N-Bis(2-hydroxyethyl)-p-toludine;N,N-Bis(2-hydroxyethyl)-p-toluidine;N,N-Bis(b-hydroxyethyl)-p-toluidine;N,N-Di(b-hydroxyethyl)-p-toluidine;N,N-Diethanol-p-methylphenylamine;N,N-Diethanol-p-toluidine;N-(4-Methylphenyl)diethanolamine;N-(p-Methylphenyl)-N,N-diethanolamine;N-(p-Methylphenyl)diethanolamine;N-p-Tolyldiethanolamine;NSC 103354;PT 2HE;Plexilith 492;
EINECS:	221-359-1
Density:	1.137 g/cm³
Melting Point:	49-53 °C(lit.)
Boiling Point:	339 °C at 760 mmHg
Flash Point:	208.9 °C
Solubility:	19.8g/L at 20℃
Appearance:	colorless to pale yellow solid
Hazard Symbols:	Xi, Xn
Risk Codes:	36/37/38-52/53-41-37/38-22
Safety:	26-36-61-39
PSA:	43.70000
LogP:	0.78600

Synthetic route

: 96-49-1
[1,3]-dioxolan-2-one

: 106-49-0
p-toluidine

A: 2933-74-6
2-[(4-methylphenyl)amino]-ethanol

B: 3077-12-1
N,N-bis-(2-hydroxyethyl)-P-toluidine

Conditions

Conditions	Yield
With Na-Y zeolite In Triethylene glycol dimethyl ether for 1.5h; Heating;	A 86% B 9 % Chromat.
With tri-i-butyl(methyl)phosphonium tosylate at 150℃; for 18h; Ionic liquid; Neat (no solvent);	A n/a B 70%

...Expand

: 75-21-8
oxirane

: 106-49-0
p-toluidine

A: 2933-74-6
2-[(4-methylphenyl)amino]-ethanol

B: 3077-12-1
N,N-bis-(2-hydroxyethyl)-P-toluidine

Conditions

Conditions	Yield
man trennt die Basen durch Destillation;

...Expand

: 75-21-8
oxirane

: 106-49-0
p-toluidine

: 3077-12-1
N,N-bis-(2-hydroxyethyl)-P-toluidine

: 75-21-8
oxirane

: 106-49-0
p-toluidine

A: 2933-74-6
2-[(4-methylphenyl)amino]-ethanol

B: 3077-12-1
N,N-bis-(2-hydroxyethyl)-P-toluidine

C: 3367-48-4
1,4-bis(4-methylphenyl)piperazine

Conditions

Conditions	Yield
at 25℃; anschliessend man destilliert das Reaktionsprodukt;

...Expand

: 106-49-0
p-toluidine

: 107-07-3
2-chloro-ethanol

: 3077-12-1
N,N-bis-(2-hydroxyethyl)-P-toluidine

Conditions

Conditions	Yield
With water; calcium carbonate

: 75-21-8
oxirane

: 106-49-0
p-toluidine

A: 2933-74-6
2-[(4-methylphenyl)amino]-ethanol

B: N-oxyethyl-N-(hydroxyethyloxyethylen)-tolyl-4-amine

C: 3077-12-1
N,N-bis-(2-hydroxyethyl)-P-toluidine

Conditions

Conditions	Yield
With 1-amino-3-methylbenzene at 120℃; for 15h;

...Expand

: 75-21-8
oxirane

: 106-49-0
p-toluidine

A: N-oxyethyl-N-(hydroxyethyloxyethylen)-tolyl-4-amine

B: 3077-12-1
N,N-bis-(2-hydroxyethyl)-P-toluidine

Conditions

Conditions	Yield
With sodium methylate at 120 - 140℃; under 1050.11 - 1882.69 Torr; for 15h; Product distribution / selectivity;
With sodium methylate; 1-amino-3-methylbenzene at 120℃; under 1050.11 - 1882.69 Torr; for 15h; Product distribution / selectivity;
With sodium hydroxide at 120℃; under 1050.11 - 1882.69 Torr; for 15h; Product distribution / selectivity;

...Expand

: 3077-12-1
N,N-bis-(2-hydroxyethyl)-P-toluidine

: 30880-19-4
(dimethylamino)dimethylarsine

: Dimethylarsinigsaeure-(3-p-tolyl-3-aza-pentan-1,5-diyl)ester

Conditions

Conditions	Yield
In diethyl ether Heating;	95%

: 41813-33-6
Bis(dimethylamino)methylarsan

: 3077-12-1
N,N-bis-(2-hydroxyethyl)-P-toluidine

: 2-Methyl-6-p-tolyl-(1,3,6,2)dioxarsocan

Conditions

Conditions	Yield
In diethyl ether Heating;	90%

: 6596-96-9
tri(dimethylamino)arsenic

: 3077-12-1
N,N-bis-(2-hydroxyethyl)-P-toluidine

: Dimethyl-(6-p-tolyl-(1,3,6,2)dioxarsocan-2-yl)amin

Conditions

Conditions	Yield
In diethyl ether Heating;	90%

Raw Materials

96-49-1

107-07-3

106-49-0

75-21-8

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Specification

The N,N-Dihydroxyethyl-p-toluidine is an organic compound with the formula C₁₁H₁₇NO₂. The IUPAC name of this chemical is 2-[N-(2-hydroxyethyl)-4-methylanilino]ethanol. With the CAS registry number 3077-12-1, it is also named as 2,2'-[(4-Methylphenyl)imino]diethanol. Besides, it should be stored in a closed cool and dry place. It is used as dye intermediates, pharmaceutical intermediates and unsaturated resin accelerator.

Physical properties about N,N-Dihydroxyethyl-p-toluidine are: (1)ACD/LogP: 1.27 ; (2)ACD/LogD (pH 5.5): 0.74; (3)ACD/LogD (pH 7.4): 1.26; (4)ACD/BCF (pH 5.5): 1.61; (5)ACD/BCF (pH 7.4): 5.28; (6)ACD/KOC (pH 5.5): 34.53; (7)ACD/KOC (pH 7.4): 113.6; (8)#H bond acceptors: 3; (9)#H bond donors: 2; (10)#Freely Rotating Bonds: 7; (11)Polar Surface Area: 21.7 Å²; (12)Index of Refraction: 1.587; (13)Molar Refractivity: 57.72 cm³; (14)Molar Volume: 171.7 cm³; (15)Polarizability: 22.88×10^-24cm³; (16)Surface Tension: 51.4 dyne/cm; (17)Density: 1.137 g/cm³; (18)Flash Point: 208.9 °C; (19)Enthalpy of Vaporization: 61.47 kJ/mol; (20)Boiling Point: 339 °C at 760 mmHg; (21)Vapour Pressure: 3.68E-05 mmHg at 25°C.

Uses of N,N-Dihydroxyethyl-p-toluidine: it can be used to produce 2-methyl-6-p-tolyl-[1,3,6,2]dioxazarsocane bt heating. It will need solvent diethyl ether. The yield is about 90%.

When you are using this chemical, please be cautious about it as the following:
It is harmful if swallowed and risk of serious damage to eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Besides, this chemical is irritating to eyes, respiratory system and skin and harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. When you are using it, wear suitable protective clothing and eye/face protection and avoid release to the environment. Refer to special instructions/safety data sheet.

You can still convert the following datas into molecular structure:
(1)SMILES: OCCN(c1ccc(cc1)C)CCO
(2)InChI: InChI=1/C11H17NO2/c1-10-2-4-11(5-3-10)12(6-8-13)7-9-14/h2-5,13-14H,6-9H2,1H3
(3)InChIKey: JUVSRZCUMWZBFK-UHFFFAOYAU
(4)Std. InChI: InChI=1S/C11H17NO2/c1-10-2-4-11(5-3-10)12(6-8-13)7-9-14/h2-5,13-14H,6-9H2,1H3
(5)Std. InChIKey: JUVSRZCUMWZBFK-UHFFFAOYSA-N