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CAS No.: 3084-50-2
Name: TRIBUTYLPHOSPHINE SULFIDE
Article Data: 25
Molecular Structure:
Molecular Structure of 3084-50-2 (TRIBUTYLPHOSPHINE SULFIDE)
Formula: C12H27 P S
Molecular Weight: 234.386
Synonyms: Tributylphosphinesulfide
Density: 0.906g/cm3
Boiling Point: 302.1°Cat760mmHg
Flash Point: 136.5°C
Risk Codes: R36/38
Safety: Moderately toxic by ingestion and skin contact. A skin and eye irritant. When heated to decomposition it emits toxic fumes of POx and SOx
PSA: 41.90000
LogP: 5.51680
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Chemistry

IUPAC Name: Tributyl(sulfanylidene)-λ5-phosphane 
Molecular Formula: C12H27PS
Molecular Weight: 234.42
EINECS: 221-393-7
Density: 0.906g/cm3
Boiling Point: 302.1°C at 760mmHg
Flash Point: 136.5°C
Properties: a liquid or pale-yellow oil
Solubility: sol in common org solvs
Freely Rotating Bonds: 9
Polar Surface Area: 41.9 Å2
Index of Refraction: 1.467
Molar Refractivity: 71.77 cm3
Molar Volume: 258.6 cm3
Polarizability: 28.45 ×10-24 cm3
Surface Tension: 33.7 dyne/cm
Enthalpy of Vaporization: 52.06 kJ/mol
Vapour Pressure: 0.00181 mmHg at 25°C
The Cas Register Number  of Tributylphosphine sulfide is 3084-50-2.The chemical synonyms of Tributylphosphine sulfide (CAS NO.3084-50-2) are Borane-tributylphosphine complex 98 ; (Tri-n-butyl)phosphine--borane ; Borane-tributylphosphine complex ; Borane-tributylphosphine complex 98% .Product categories of Tributylphosphine sulfide (CAS NO.3084-50-2) are Phosphine Oxides and Sulfides .The molecular structure of Tributylphosphine sulfide (CAS NO.3084-50-2) is.

Uses

 Tributylphosphine sulfide (CAS NO.3084-50-2)  is usually handled using air-free techniques.

Toxicity Data With Reference

1.    

skn-rbt 10 mg/24H open MLD

    AIHAAP    American Industrial Hygiene Association Journal. 23 (1962),95.
2.    

skn-rbt 100 mg/24H MOD

    85JCAE    Prehled Prumyslove Toxikologie; Organicke Latky Marhold, J.,Prague, Czechoslovakia.: Avicenum,1986,1119.
3.    

eye-rbt 500 mg/24H MLD

    85JCAE    Prehled Prumyslove Toxikologie; Organicke Latky Marhold, J.,Prague, Czechoslovakia.: Avicenum,1986,1119.
4.    

orl-rat LD50:930 mg/kg

    AIHAAP    American Industrial Hygiene Association Journal. 23 (1962),95.
5.    

skn-rbt LD50:1000 mg/kg

    AIHAAP    American Industrial Hygiene Association Journal. 23 (1962),95.

Safety Profile

Moderately toxic by ingestion and skin contact. A skin and eye irritant. When heated to decomposition it emits toxic fumes of POx and SOx.
Hazard Codes: IrritantXi
Risk Statements: 36/38 
R36/38: Irritating to eyes and skin.
Safety Statements: 41 
S41: In case of fire and / or explosion do not breathe fumes.
WGK Germany: 3