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309-00-2

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Basic Information
CAS No.: 309-00-2
Name: ALDRIN
Article Data: 18
Molecular Structure:
Molecular Structure of 309-00-2 (ALDRIN)
Formula: C12H8Cl6
Molecular Weight: 364.914
Synonyms: 1,4:5,8-Dimethanonaphthalene,1,2,3,4,10,10-hexachloro-1,4,4a,5,8,8a-hexahydro-, (1a,4a,4ab,5a,8a,8ab)-;1,4:5,8-Dimethanonaphthalene,1,2,3,4,10,10-hexachloro-1,4,4a,5,8,8a-hexahydro-, endo,exo- (8CI);1,2,3,4,10,10-Hexachloro-1,4,4a,5,8,8a-hexahydro-1,4-endo-exo-5,8-dimethanonaphthalene;1,2,3,4,10,10-Hexachloro-1,4,4a,5,8,8a-hexahydro-endo-1,4-exo-5,8-dimethanonaphthalene;Aldocit;Aldrex 25;Aldrex 40;Andrex;Andrex 40;Compound 118;ENT15,949;HHDN;Kortofin;Octalene;SD 2794;Seedrin;Tatuzinho;
EINECS: 206-215-8
Density: 1.73 g/cm3
Melting Point: 104℃
Boiling Point: 384.9 °C at 760 mmHg
Flash Point: 186.1 °C
Solubility: Insoluble in water
Appearance: off-white solid
Hazard Symbols: ToxicT, DangerousN, HarmfulXn, FlammableF, IrritantXi
Risk Codes: 24/25-40-48/24/25-50/53-67-65-38-11-36-20/21/22-36/37/38-39/23/24/25
Safety: 22-36/37-45-60-61-62-26-16-33-7
Transport Information: UN 2761
PSA: 0.00000
LogP: 5.27020
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Chemistry

Product Name: Aldrin 
Molecular Structure:

Molecular Formula: C12H8Cl6
Molecular Weight: 364.9099
Synonyms of Aldrin (CAS NO.309-00-2): 1,4:5,8-Dimethanonaphthalene, 1,2,3,4,10,10-hexachloro-1,4,4a,5,8,8a-hexahydro-, endo,exo- ; 1,4:5,8-Dimethanonaphthalene, 1,2,3,4,10,10-hexachloro-1,4,4a,5,8,8a-hexahydro-, (1alpha,4alpha,4abeta,5alpha,8alpha,8abeta)- ; Aldrin, liquid ; Aldrin, liquid [NA2762] [Poison] ; Aldrin, solid ; Aldrin, solid [NA2761] [Poison] ; NA2761 ; NA2762 ; RCRA waste no. P004
CAS NO: 309-00-2
Classification Code: Agricultural Chemical ; Human Data ; Insecticide ; Insecticides ; Mutation data ; Out-dated pesticide ; Pesticides ; Reproductive Effect ; Tumor data 
Index of Refraction: 1.659
Molar Refractivity: 77.741 cm3
Molar Volume: 210.723 cm3
Surface Tension: 55.317 dyne/cm
Density: 1.732 g/cm3
Flash Point: 186.068 °C
Enthalpy of Vaporization: 60.886 kJ/mol
Boiling Point: 384.92 °C at 760 mmHg

History

  Aldrin (CAS NO.309-00-2) is named after the German chemist Kurt Alder, one of the coinventors of this kind of reaction. An estimated 270 million kilograms of aldrin and related cyclodiene pesticides were produced between 1946 and 1976.

Uses

  Aldrin (CAS NO.309-00-2) is an organochlorine insecticide that was widely used until the 1970's when it was banned in most countries.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
bird - wild LD50 oral 7200ug/kg (7.2mg/kg)   Toxicology and Applied Pharmacology. Vol. 21, Pg. 315, 1972.
cat LDLo oral 15mg/kg (15mg/kg) LUNGS, THORAX, OR RESPIRATION: CHRONIC PULMONARY EDEMA

LIVER: FATTY LIVER DEGERATION

KIDNEY, URETER, AND BLADDER: OTHER CHANGES
Communicationes Veterinariae. Vol. 2, Pg. 71, 1958.
cat LDLo skin 75mg/kg (75mg/kg) LUNGS, THORAX, OR RESPIRATION: CHRONIC PULMONARY EDEMA

KIDNEY, URETER, AND BLADDER: OTHER CHANGES

LIVER: FATTY LIVER DEGERATION
Communicationes Veterinariae. Vol. 2, Pg. 71, 1958.
chicken LD50 oral 10mg/kg (10mg/kg) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

BEHAVIORAL: EXCITEMENT

BEHAVIORAL: CHANGES IN MOTOR ACTIVITY (SPECIFIC ASSAY)
Journal of Economic Entomology. Vol. 45, Pg. 121, 1952.
child LDLo oral 1250ug/kg (1.25mg/kg)   "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969Vol. -, Pg. 82, 1969.
dog LD50 intraperitoneal 1999mg/kg (1999mg/kg) LIVER: LIVER FUNCTION TESTS IMPAIRED Toxicology and Applied Pharmacology. Vol. 10, Pg. 119, 1967.
dog LD50 oral 65mg/kg (65mg/kg)   Pesticide Chemicals Official Compendium, Association of the American Pesticide Control Officials, Inc., 1966. Vol. -, Pg. 7, 1966.
dog LDLo unreported 95mg/kg (95mg/kg)   AMA Archives of Industrial Hygiene and Occupational Medicine. Vol. 3, Pg. 64, 1951.
duck LD50 oral 520mg/kg (520mg/kg)   Down to Earth. Vol. 35, Pg. 25, 1979.
guinea pig LD50 oral 33mg/kg (33mg/kg)   Pesticide Chemicals Official Compendium, Association of the American Pesticide Control Officials, Inc., 1966. Vol. -, Pg. 7, 1966.
hamster LD50 oral 100mg/kg (100mg/kg)   Teratology, The International Journal of Abnormal Development. Vol. 9, Pg. 11, 1974.
human TDLo oral 14mg/kg (14mg/kg) BEHAVIORAL: TREMOR

BEHAVIORAL: EXCITEMENT

GASTROINTESTINAL: NAUSEA OR VOMITING
"Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969Vol. -, Pg. 82, 1969.
mammal (species unspecified) LD50 unreported 40mg/kg (40mg/kg)   "Chemistry of Pesticides," Melnikov, N.N., New York, Springer-Verlag New York, Inc., 1971Vol. -, Pg. 62, 1971.
mouse LD50 intracrebral 4mg/kg (4mg/kg) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD Toxicology Letters. Vol. 60, Pg. 289, 1992.
mouse LD50 intraperitoneal 50mg/kg (50mg/kg)   Soviet Genetics. English translation of GNKAA5. Vol. 2, Pg. 80, 1966.
mouse LD50 intravenous 21mg/kg (21mg/kg)   "Aldrin Dieldrin Endrin and Telodrin: An Epidemiological and Toxicological Study of Long-Ter Occupational Exposure," Jager, K.W., New York, Elsevier Science Pub. Co., 1970Vol. -, Pg. 52, 1970.
mouse LD50 oral 44mg/kg (44mg/kg)   Special Publication of the Entomological Society of America. Vol. 78-1, Pg. 12, 1978.
pigeon LD50 oral 56200ug/kg (56.2mg/kg)   ASTM Special Technical Publication. Vol. (680), Pg. 157, 1979.
quail LD50 oral 42100ug/kg (42.1mg/kg)   ASTM Special Technical Publication. Vol. (680), Pg. 157, 1979.
rabbit LD50 oral 50mg/kg (50mg/kg)   Pesticide Chemicals Official Compendium, Association of the American Pesticide Control Officials, Inc., 1966. Vol. -, Pg. 7, 1966.
rabbit LD50 skin 15mg/kg (15mg/kg) SENSE ORGANS AND SPECIAL SENSES: OTHER CHANGES: OLFACTION

BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

BEHAVIORAL: EXCITEMENT
Journal of Economic Entomology. Vol. 46, Pg. 702, 1953.
rabbit LDLo subcutaneous 100mg/kg (100mg/kg)   "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 73, 1982.
rat LCLo inhalation 5800ug/m3/4H (5.8mg/m3)   "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 73, 1982.
rat LD50 intraperitoneal 150mg/kg (150mg/kg)   Toxicology and Applied Pharmacology. Vol. 11, Pg. 302, 1967.
rat LD50 oral 39mg/kg (39mg/kg)   Special Publication of the Entomological Society of America. Vol. 78-1, Pg. 12, 1978.
rat LD50 skin 98mg/kg (98mg/kg)   Toxicology and Applied Pharmacology. Vol. 14, Pg. 515, 1969.
rat LD50 subcutaneous 62mg/kg (62mg/kg)   "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 73, 1982.

Safety Profile

Hazard Codes of Aldrin (CAS NO.309-00-2): ToxicT,DangerousN,HarmfulXn,FlammableF,IrritantXi
Risk Statements: 40-48-50/53-67-65-11-20/21/22-36/37/38-39-23/24/25 
R40: Limited evidence of a carcinogenic effect. 
R48: Danger of serious damage to health by prolonged exposure. 
R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 
R67: Vapours may cause drowsiness and dizziness. 
R65: Harmful: may cause lung damage if swallowed. 
R11: Highly flammable. 
R20/21/22: Harmful by inhalation, in contact with skin and if swallowed. 
R36/37/38: Irritating to eyes, respiratory system and skin. 
R39: Danger of very serious irreversible effects. 
R23/24/25: Toxic by inhalation, in contact with skin and if swallowed.
Safety Statements: 22-36/37-45-60-61-62-26-16-33-7 
S22:Do not breathe dust. 
S36/37:Wear suitable protective clothing and gloves. 
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S60: This material and its container must be disposed of as hazardous waste. 
S61: Avoid release to the environment. Refer to special instructions / safety data sheets. 
S62: If swallowed, do not induce vomitting; seek medical advice immediately and show this container or label. 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S16: Keep away from sources of ignition. 
S33: Take precautionary measures against static discharges. 
S7: Keep container tightly closed.
RIDADR: 2761
RTECS: IO2100000
HazardClass: 6.1(a)
PackingGroup: II

Specification

  Aldrin (CAS NO.309-00-2) has rat LD50 of 39 to 60 mg/kg (oral in rats).
This colourless solid was heavily used as a pesticide to treat seed and soil. Aldrin and related "cyclodiene" pesticides became notorious as persistent organic pollutants.