CAS No.3143-02-0,3-Methyl-3-oxetanemethanol Suppliers,MSDS download

Products Categories

Pharmaceutical (172)
Organic Chemicals (31)
Others (10)
Reagent (8)
Materials (2)

Basic Information

Molecular Structure:
CAS No.:	3143-02-0
Name:	3-Methyl-3-oxetanemethanol
Article Data:	16
Cas Database

Formula:	C₅H₁₀O₂
Molecular Weight:	102.133
Synonyms:	(3-Methyloxetan-3-yl)methanol;3-(Hydroxymethyl)-3-methyloxetane;3-Methyl-3-(hydroxymethyl)oxacyclobutane;3-Methyl-3-(hydroxymethyl)oxetane;3-Methyl-3-oxetanylmethyl alcohol;MOXA(monomer);3-Hydroxymethyl-3-methyloxetane;
EINECS:	-0
Density:	1.031 g/cm³
Boiling Point:	152.2 °C at 760 mmHg
Flash Point:	98.9 °C
Appearance:	clear colorless to pale yellow liquid
Hazard Symbols:	Xi
Risk Codes:	43
Safety:	23-24/25-36/37
PSA:	29.46000
LogP:	0.01520

Synthetic route

: 1620017-21-1
tert-butyl[(3-methyloxetan-3-yl)methoxy]diphenylsilane

: 3143-02-0
3-hydroxymethyl-3-methyloxethane

Conditions

Conditions	Yield
With tetrabutyl ammonium fluoride In tetrahydrofuran at 20℃; for 2h;	84%
With tetrabutyl ammonium fluoride In tetrahydrofuran at 20℃; for 2h;	84%

: 77-85-0
2-(hydroxymethyl)-2-methylpropane-1,3-diol

: 3143-02-0
3-hydroxymethyl-3-methyloxethane

Conditions

Conditions	Yield
With potassium hydroxide; Diethyl carbonate at 115℃; for 1h;	83.7%
With potassium hydroxide; Diethyl carbonate In ethanol for 2h; Heating;	81%
Stage #1: 2-(hydroxymethyl)-2-methylpropane-1,3-diol With potassium hydroxide; carbonic acid dimethyl ester In methanol under 760.051 Torr; Heating; Stage #2: at 130 - 140℃; under 110 - 120 Torr;	77%

: 84051-79-6
1,1,1-Trimethylolethane dinitrate

A: 3143-02-0
3-hydroxymethyl-3-methyloxethane

B: 77-85-0
2-(hydroxymethyl)-2-methylpropane-1,3-diol

C: 625-58-1
ethyl nitrate

D: 84051-80-9
1,1,1-Trimethylolethane mononitrate

E: 84051-81-0
3-methyl-3-(nitroxymethyl)oxetane

F NO2- (5.2percent), NO3-: NO2- (5.2percent), NO3-

Conditions

Conditions	Yield
With sodium hydroxide In ethanol; water at 55℃; for 3.10833h; Product distribution; Rate constant; var. NaOH conc.;	A 13% B 0.7% C n/a D 24% E 66% F n/a

...Expand

: 3032-55-1
trimethylolethane trinitrate

A: 3143-02-0
3-hydroxymethyl-3-methyloxethane

B: 77-85-0
2-(hydroxymethyl)-2-methylpropane-1,3-diol

C: 84051-80-9
1,1,1-Trimethylolethane mononitrate

D: 84051-79-6
1,1,1-Trimethylolethane dinitrate

E: 84051-81-0
3-methyl-3-(nitroxymethyl)oxetane

Conditions

Conditions	Yield
With sodium hydroxide In methanol; water at 55℃; for 86.1667h; Product distribution; Rate constant; Thermodynamic data; var. NaOH conc., var. solv., solv. effect, ΔH(excit.), ΔF(excit.), ΔS(excit.);	A 45.5% B 2.3% C 31.8% D 1.5% E 16.5%

...Expand

: 2210-03-9
2-(bromomethyl)-2-methylpropane-1,3-diol

: 3143-02-0
3-hydroxymethyl-3-methyloxethane

Conditions

Conditions	Yield
With Ph4SbOMe In 1,2-dichloro-ethane at 60℃; for 24h; sealed ampule;	82 % Chromat.

: 77-85-0
2-(hydroxymethyl)-2-methylpropane-1,3-diol

: 105-58-8
Diethyl carbonate

ethanolic KOH-solution: ethanolic KOH-solution

: 3143-02-0
3-hydroxymethyl-3-methyloxethane

Conditions

Conditions	Yield
Erhitzen des Reaktionsprodukts unter vermindertem Druck bis auf 200grad;

...Expand

: 84051-80-9
1,1,1-Trimethylolethane mononitrate

A: 3143-02-0
3-hydroxymethyl-3-methyloxethane

B: 625-58-1
ethyl nitrate

C NO2-, NO3-: NO2-, NO3-

Conditions

Conditions	Yield
With sodium hydroxide In ethanol; water at 55℃; for 21.9033h; Product distribution; Rate constant; var. NaOH conc.;

...Expand

: 84051-81-0
3-methyl-3-(nitroxymethyl)oxetane

A: 3143-02-0
3-hydroxymethyl-3-methyloxethane

B: 625-58-1
ethyl nitrate

C NO2-, NO3-: NO2-, NO3-

Conditions

Conditions	Yield
With sodium hydroxide In ethanol; water at 55℃; for 11.38h; Product distribution; Rate constant; var. NaOH conc.;

...Expand

: 77-85-0
2-(hydroxymethyl)-2-methylpropane-1,3-diol

: 105-58-8
Diethyl carbonate

: 3143-02-0
3-hydroxymethyl-3-methyloxethane

Conditions

Conditions	Yield
With potassium hydroxide In ethanol

: 1256651-65-6
N-hexyl-3-methyloxetane-3-carboxamide

A: 3143-02-0
3-hydroxymethyl-3-methyloxethane

B: 111-26-2
hexan-1-amine

Conditions

Conditions	Yield
With [RuH(CO)(BPy-tPNN*)]; hydrogen In tetrahydrofuran at 110℃; under 7600.51 Torr; for 48h; Fischer-Porter tube;	A 74 %Chromat. B 74 %Chromat.

Total:164 Page 1 of 5 1 2 3 4 5 Next>>

Post a RFQ

Cas No.:

Product Name:

Quantity:

Email:

Company name:

Valid Period:

Detailed Requirements:

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

What can I do for you?
Get Best Price

Get Best Price for 3143-02-0

Specification

The 3-Methyl-3-oxetanemethanol, with the CAS registry number 3143-02-0, is also known as 3-Hydroxymethyl-3-methyloxetane. It belongs to the product categories of Oxetanes; Simple 4-Membered Ring Compounds. This chemical's molecular formula is C₅H₁₀O₂ and molecular weight is 102.13. Its IUPAC name is called (3-methyloxetan-3-yl)methanol. The product should be sealed at temperature of 2-8 °C.

Physical properties of 3-Methyl-3-oxetanemethanol: (1)ACD/LogP: -0.61; (2)ACD/LogD (pH 5.5): -0.61; (3)ACD/LogD (pH 7.4): -0.61; (4)ACD/BCF (pH 5.5): 1; (5)ACD/BCF (pH 7.4): 1; (6)ACD/KOC (pH 5.5): 11.04; (7)ACD/KOC (pH 7.4): 11.04; (8)#H bond acceptors: 2; (9)#H bond donors: 1; (10)#Freely Rotating Bonds: 2; (11)Index of Refraction: 1.443; (12)Molar Refractivity: 26.28 cm³; (13)Molar Volume: 99 cm³; (14)Surface Tension: 40.3 dyne/cm; (15)Density: 1.031 g/cm³; (16)Flash Point: 98.9 °C; (17)Enthalpy of Vaporization: 45.31 kJ/mol; (18)Boiling Point: 152.2 °C at 760 mmHg; (19)Vapour Pressure: 1.32 mmHg at 25°C.

Preparation: this chemical can be prepared by 2-hydroxymethyl-2-methyl-propane-1,3-diol. This reaction will need reagent diethyl carbonate, ethanolic KOH-solution. The reaction temperature is 180 °C.

Uses of 3-Methyl-3-oxetanemethanol: it can be used to produce 2-(dimethylamino-methyl)-2-methyl-propane-1,3-diol at temperature of 180 °C. This reaction will need solvent H₂O.

When you are using this chemical, please be cautious about it as the following:
This chemical may cause inflammation to the skin or other mucous membranes. It also may cause sensitisation by skin contact. You must avoid contacting it with skin and eyes. Whenever you will contact it, please wear suitable protective clothing and gloves.

You can still convert the following datas into molecular structure:
(1)Canonical SMILES: CC1(COC1)CO
(2)InChI: InChI=1S/C5H10O2/c1-5(2-6)3-7-4-5/h6H,2-4H2,1H3
(3)InChIKey: NLQMSBJFLQPLIJ-UHFFFAOYSA-N