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3162-58-1

Basic Information
CAS No.: 3162-58-1
Name: SULFUR TRIOXIDE TRIMETHYLAMINE COMPLEX
Molecular Structure:
Molecular Structure of 3162-58-1 (SULFUR TRIOXIDE TRIMETHYLAMINE COMPLEX)
Formula: C3H9NO3S
Molecular Weight: 139.175
Synonyms: SULPHUR TRIOXIDE-TRIMETHYLAMINE COMPLEX;SULFUR TRIOXIDE TRIMETHYLAMINE;SULFUR TRIOXIDE TRIMETHYLAMINE COMPLEX;SULFUR TRIOXIDE TRIMETHYLAMINEOMPLEX;TRIMETHYLAMINE SULFUR TRIOXIDE;TRIMETHYLAMINE SULFUR TRIOXIDE COMPLEX;TRLIMETHYLAMINE SULPHUR TRIOXIDE COMPLEX;Trimethylamine-sulphur trioxide complex
Density: g/cm3
Melting Point: 232 °C (dec.)(lit.)
Boiling Point: 2.8°Cat760mmHg
Flash Point: °C
Solubility: Soluble in hot water and ethanol. Slightly soluble in dimethyl sulfoxide and methanol. Insoluble in water.
Hazard Symbols:
Risk Codes: 34
Safety:
Hazard Codes C
Risk Statements 34
Safety Statements 26-36/37/39-45
RIDADR UN 3261 8/PG 2
WGK Germany 3
3-9-21
Hazard Note Corrosive/Moisture Sensitive
HazardClass 8
PackingGroup II
PSA: 86.54000
LogP: 0.46960
Synthetic route
75-50-3

trimethylamine

3162-58-1

sulfur trioxide trimethylamine complex

Conditions
ConditionsYield
With trimethylsilyl N,N-dimesylamidosulfonate In dichloromethane at 0℃;95%
With chlorosulphuric acid; chloroform
176759-56-1

trimethylsilyl N,N-dimesylamidosulfonate

75-50-3

trimethylamine

A

30488-04-1

trimethylsilyldimesylamine

B

3162-58-1

sulfur trioxide trimethylamine complex

Conditions
ConditionsYield
In dichloromethane at 0℃; Product distribution; other Lewis bases;A n/a
B 95%
7446-11-9

sulfur trioxide

75-50-3

trimethylamine

3162-58-1

sulfur trioxide trimethylamine complex

Conditions
ConditionsYield
In neat (no solvent) react. of SO3-vapor (dild. with N2 as carrier gas) with dry (CH3)3N-vapor;; crystn.;;
In neat (no solvent) react. of SO3-vapor (dild. with N2 as carrier gas) with dry (CH3)3N-vapor;; crystn.;;
3162-58-1

sulfur trioxide trimethylamine complex

2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl sulfate

Conditions
ConditionsYield
In acetonitrile for 48h; Heating;100%
3162-58-1

sulfur trioxide trimethylamine complex

C64H72N6O21

C64H72N6O30S3*3C3H9N

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 50℃; for 72h;100%
3162-58-1

sulfur trioxide trimethylamine complex

C64H74N6O21

C64H74N6O33S4*4C3H9N

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 50℃; for 72h;100%

C47H55N3O15

3162-58-1

sulfur trioxide trimethylamine complex

C47H51N3O27S4(4-)*4Na(1+)

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 60℃;100%

2-(N-benzyloxycarbonyl)aminoethyl 2,3,4-tri-O-(4-methyl)benzoyl-6-O-(2-naphthylmethyl)-β-D-galactopyranosyl-(1→4)-3-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranoside

3162-58-1

sulfur trioxide trimethylamine complex

2-(N-benzyloxycarbonyl)aminoethyl 2,3,4-tri-O-(4-methyl)benzoyl-6-O-(2-naphthylmethyl)-β-D-galactopyranosyl-(1→4)-3-O-benzyl-2-deoxy-2-phthalimido-6-O-sulfo-β-D-glucopyranoside trimethylamine salt

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 60℃; Inert atmosphere;100%

C148H152N12O45

3162-58-1

sulfur trioxide trimethylamine complex

C148H152N12O57S4*4C3H9N

Conditions
ConditionsYield
With N,N-dimethyl-formamide In 1,2-dichloro-ethane at 80℃; for 0.5h; Inert atmosphere;98.1%
3162-58-1

sulfur trioxide trimethylamine complex

C71H78N6O21

C71H78N6O27S2*2C3H9N

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 50℃; for 72h;96%
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Chemistry

IUPAC   Name: N,N-Dimethylmethanamine; sulfur trioxide    
Empirical Formula: C3H9NO3S
Molecular Weight: 139.1735 
Einecs: 221-614-7 
Melting point: 232 °C
Polar Surface Area: 3.24 Å2 
Enthalpy of Vaporization: 22.94 kJ/mol
Boiling Point: 2.8 °C at 760 mmHg
Vapour Pressure: 1720 mmHg at 25°C 
The Cas Register Number of  Sulfur trioxide trimethylamine complex is 3162-58-1.The chemical synonyms of  Sulfur trioxide trimethylamine complex (CAS NO.3162-58-1) are Sulphur trioxide trimethylamine (1:1) .The molecular structure of  Sulfur trioxide trimethylamine complex (CAS NO.3162-58-1) is
.

Uses

  Sulfur trioxide trimethylamine complex (CAS NO.3162-58-1) is used in organic synthesis.

Safety Profile

Hazard Codes: CorrosiveC
Risk Statements: 34 
R34: Causes burns.
Safety Statements: 26-36/37/39-45 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection. 
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
RIDADR: UN 3261 8/PG 2
WGK Germany: 3
F: 3-9-21
Hazard Note: Corrosive/Moisture Sensitive
HazardClass: 8
PackingGroup: II