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CAS No.: | 3162-58-1 | ||||||||||||||||||
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Name: | SULFUR TRIOXIDE TRIMETHYLAMINE COMPLEX | ||||||||||||||||||
Molecular Structure: | |||||||||||||||||||
Formula: | C3H9NO3S | ||||||||||||||||||
Molecular Weight: | 139.175 | ||||||||||||||||||
Synonyms: | SULPHUR TRIOXIDE-TRIMETHYLAMINE COMPLEX;SULFUR TRIOXIDE TRIMETHYLAMINE;SULFUR TRIOXIDE TRIMETHYLAMINE COMPLEX;SULFUR TRIOXIDE TRIMETHYLAMINEOMPLEX;TRIMETHYLAMINE SULFUR TRIOXIDE;TRIMETHYLAMINE SULFUR TRIOXIDE COMPLEX;TRLIMETHYLAMINE SULPHUR TRIOXIDE COMPLEX;Trimethylamine-sulphur trioxide complex | ||||||||||||||||||
Density: | g/cm3 | ||||||||||||||||||
Melting Point: |
232 °C (dec.)(lit.) |
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Boiling Point: | 2.8°Cat760mmHg | ||||||||||||||||||
Flash Point: | °C | ||||||||||||||||||
Solubility: | Soluble in hot water and ethanol. Slightly soluble in dimethyl sulfoxide and methanol. Insoluble in water. | ||||||||||||||||||
Hazard Symbols: | |||||||||||||||||||
Risk Codes: | 34 | ||||||||||||||||||
Safety: |
|
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PSA: | 86.54000 | ||||||||||||||||||
LogP: | 0.46960 |
Conditions | Yield |
---|---|
With trimethylsilyl N,N-dimesylamidosulfonate In dichloromethane at 0℃; | 95% |
With chlorosulphuric acid; chloroform |
trimethylsilyl N,N-dimesylamidosulfonate
trimethylamine
A
trimethylsilyldimesylamine
B
sulfur trioxide trimethylamine complex
Conditions | Yield |
---|---|
In dichloromethane at 0℃; Product distribution; other Lewis bases; | A n/a B 95% |
Conditions | Yield |
---|---|
In neat (no solvent) react. of SO3-vapor (dild. with N2 as carrier gas) with dry (CH3)3N-vapor;; crystn.;; | |
In neat (no solvent) react. of SO3-vapor (dild. with N2 as carrier gas) with dry (CH3)3N-vapor;; crystn.;; |
sulfur trioxide trimethylamine complex
2,3,4,6-tetra-O-benzyl-α-D-mannopyranoside
Conditions | Yield |
---|---|
In acetonitrile for 48h; Heating; | 100% |
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 50℃; for 72h; | 100% |
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 50℃; for 72h; | 100% |
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 60℃; | 100% |
sulfur trioxide trimethylamine complex
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 60℃; Inert atmosphere; | 100% |
Conditions | Yield |
---|---|
With N,N-dimethyl-formamide In 1,2-dichloro-ethane at 80℃; for 0.5h; Inert atmosphere; | 98.1% |
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 50℃; for 72h; | 96% |
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IUPAC Name: N,N-Dimethylmethanamine; sulfur trioxide
Empirical Formula: C3H9NO3S
Molecular Weight: 139.1735
Einecs: 221-614-7
Melting point: 232 °C
Polar Surface Area: 3.24 Å2
Enthalpy of Vaporization: 22.94 kJ/mol
Boiling Point: 2.8 °C at 760 mmHg
Vapour Pressure: 1720 mmHg at 25°C
The Cas Register Number of Sulfur trioxide trimethylamine complex is 3162-58-1.The chemical synonyms of Sulfur trioxide trimethylamine complex (CAS NO.3162-58-1) are Sulphur trioxide trimethylamine (1:1) .The molecular structure of Sulfur trioxide trimethylamine complex (CAS NO.3162-58-1) is
.
Sulfur trioxide trimethylamine complex (CAS NO.3162-58-1) is used in organic synthesis.
Hazard Codes: C
Risk Statements: 34
R34: Causes burns.
Safety Statements: 26-36/37/39-45
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
RIDADR: UN 3261 8/PG 2
WGK Germany: 3
F: 3-9-21
Hazard Note: Corrosive/Moisture Sensitive
HazardClass: 8
PackingGroup: II