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3233-32-7

Basic Information
CAS No.: 3233-32-7
Name: 4-hydroxyphenyl acetate
Article Data: 61
Molecular Structure:
Molecular Structure of 3233-32-7 (4-hydroxyphenyl acetate)
Formula: C8H8 O3
Molecular Weight: 152.15
Synonyms: 1,4-Benzenediol,monoacetate (9CI); Hydroquinone, acetate (6CI,7CI); Hydroquinone, monoacetate(8CI); 4-(Acetyloxy)phenol; 4-Acetoxyphenol; 4-Hydroxyphenyl acetate; NSC47899; p-Hydroxyphenyl acetate
Density: 1.212g/cm3
Melting Point: 62-63 °C
Boiling Point: 269.3°C at 760 mmHg
Flash Point: 118.6°C
PSA: 46.53000
LogP: 1.31750
Synthetic route
1205-91-0

benzene-1,4-diyl diacetate

123-31-9

hydroquinone

3233-32-7

hydroquinone monoacetate

Conditions
ConditionsYield
With potassium carbonate In dimethyl sulfoxide at 25℃; Green chemistry; regioselective reaction;99%
177490-82-3

(4-acetoxyphenyl)boronic acid

3233-32-7

hydroquinone monoacetate

Conditions
ConditionsYield
With menadione; sodium hydrogencarbonate; sodium L-ascorbate In ethanol; water at 20℃; under 760.051 Torr; for 24h; pH=8.5; Darkness; Green chemistry;98%
With oxygen; N-ethyl-N,N-diisopropylamine; [5,6]fullerene-C70 In chloroform; toluene at 20℃; for 12h; Irradiation;98%
64-19-7

acetic acid

123-31-9

hydroquinone

3233-32-7

hydroquinone monoacetate

Conditions
ConditionsYield
With 50wtpercent Cs2.5H0.5PW12O40 supported on MCM-41 In acetonitrile at 50℃; for 0.5h;97%

4-[(t-butyldimethylsilyl)oxy]phenyl acetate

3233-32-7

hydroquinone monoacetate

Conditions
ConditionsYield
With potassium hydrogen difluoride In methanol at 20℃; for 1h;97%
108-24-7

acetic anhydride

123-31-9

hydroquinone

3233-32-7

hydroquinone monoacetate

Conditions
ConditionsYield
With silica-sulfuric acid nanoparticles In neat (no solvent) at 20℃; for 0.166667h;95%
With acetic acid at 110℃; for 2h;94%
With acetic acid at 110℃; Inert atmosphere;86%
225529-40-8

4-benzoyloxy phenyl acetate

3233-32-7

hydroquinone monoacetate

Conditions
ConditionsYield
With phosphate buffer; Lipase PS-C In tetrahydrofuran for 4h; Ambient temperature; pH=7;93%

acetic acid 4-methoxymethoxy-phenyl ester

3233-32-7

hydroquinone monoacetate

Conditions
ConditionsYield
sodium hydrogen sulfate; silica gel In dichloromethane at 20℃; for 1.5h;91%
82969-01-5

4-acetoxyphenyl tosylate

3233-32-7

hydroquinone monoacetate

Conditions
ConditionsYield
With cerium(III) chloride; sodium iodide In acetonitrile for 4h; tosylate cleavage; Heating;90%
108-24-7

acetic anhydride

123-31-9

hydroquinone

A

1205-91-0

benzene-1,4-diyl diacetate

B

3233-32-7

hydroquinone monoacetate

Conditions
ConditionsYield
With pyridine hydrogenfluoride In dichloromethane at 20℃; for 1.5h;A 13%
B 74%
With pyridine for 1h;
With sodium carbonate anfangs unter Kuehlung;
53135-65-2

4-(prop-2-yn-1-yloxy)phenyl acetate

3233-32-7

hydroquinone monoacetate

Conditions
ConditionsYield
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride In benzene at 100℃; for 24h; Product distribution; Further Variations:; Solvents; Temperatures; reaction times;61%
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