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32534-81-9

Basic Information
CAS No.: 32534-81-9
Name: Pentabromodiphenyl ether
Molecular Structure:
Molecular Structure of 32534-81-9 (Pentabromodiphenyl ether)
Formula: C12H5Br5O
Molecular Weight: 564.72
Synonyms: Bromkal G1;DE 60FTM;Pentabromodiphenyl ether;Pentabromodiphenyl oxide;Planelon PB501;Saytex 125;
EINECS: 251-084-2
Density: 2.344g/cm3
Melting Point: -4oC
Boiling Point: 430.768°C at 760 mmHg
Flash Point: 178.529°C
Solubility: Insoluble (
Appearance: AMBER VISCOUS LIQUID
Hazard Symbols: Xn,N
Risk Codes: 48/21/22-50/53-64
Safety: 36/37-45-60-61
PSA: 9.23000
LogP: 7.29140
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Chemistry

PENTABROMODIPHENYL ETHER(32534-81-9) is the chemical compound with the formula C12H5Br5O.Its molar weight is 564.69g/mol.
PENTABROMODIPHENYL ETHER(32534-81-9) is also named diphenyl ether, pentabromo derivative;Benzene, 1,1-oxybis-, pentabromo deriv.;pentabromodiphenylether (technical mixture);PENTABROMOBIPHENYLETHER;PBDECONGENER99;PENTA-BROMINATEDDIPHENYLETHER.
Index of Refraction: 1.68
Molar Refractivity: 91.14 cm
Molar Volume: 240.9 cm3
Polarizability: 36.13 10-24cm3 
Surface Tension: 53.2 dyne/cm 
Density: 2.343 g/cm3 
Flash Point: 180 o
Enthalpy of Vaporization: 66.36 kJ/mol 
Boiling Point: 434.2 oC  at 760 mmHg 
Vapour Pressure: 2.46E-07 mmHg at 25 o
Water Solubility: Insoluble (<0.1 g/100 mLat 20.5 oC )
Stability: Incompatible with strong oxidizing agents.
The chemical structure of PENTABROMODIPHENYL ETHER(32534-81-9) is
.

Uses

PENTABROMODIPHENYL ETHER(32534-81-9) is most commonly used as a flame retardant in flexible polyurethane foam; it was also used in printed circuit boards in Asia, and in other applications.

Toxicity Data With Reference

1.   

skn-rbt 500 µL/24H MLD

   NTIS**    National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) OTS0522196 .
2.   

skn-rbt 100 µL/24H MOD

   NTIS**    National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) OTS0522196 .
3.   

orl-rat LD50:5 g/kg

   NTIS**    National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) OTS0522287 .
4.   

skn-rat LDLo:5500 mg/kg

   NTIS**    National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) OTS0522196 .
5.   

orl-mus TDLo:0.8 mg/kg

   TXCYAC    Toxicology. 86 (1994),49.
6.   

ihl-rat LC :>200 g/m3/1H

   NTIS**    National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) OTS0540414 .
7.   

skn-rbt LD :>2 g/kg

   NTIS**    National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) OTS0540414 .

Consensus Reports

PENTABROMODIPHENYL ETHER(32534-81-9) has no proven health effects in humans; however, based on animal experiments, it may have effects on "the liver, thyroid, and neurobehavioral development".

Safety Profile

A poison by ingestion. Moderately toxic by inhalation. Low toxicity by skin contact. A moderate skin irritant. When heated to decomposition it emits toxic vapors of Br.
Hazard Codes: Xn,N
Risk Statements: 48/21/22-50/53-64
48/21/22:  Harmful: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed 
50/53:  Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment 
64:  May cause harm to breast-fed babies 
Safety Statements: 36/37-45-60-61
36/37:  Wear suitable protective clothing and gloves 
45:  In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) 
60:  This material and/or its container must be disposed of as hazardous waste 
61:  Avoid release to the environment. Refer to special instructions safety data sheet 
RIDADR: 3152
HazardClass: 9
PackingGroup: II
Hazardous Substances Data: 32534-81-9(Hazardous Substances Data).