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CAS No.: | 32767-18-3 | ||||||||||
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Name: | OXYGEN-18O2, 97 ATOM % 18O | ||||||||||
Article Data: | 86 | ||||||||||
Molecular Structure: | |||||||||||
Formula: | O2 | ||||||||||
Molecular Weight: | 38.0159 | ||||||||||
Synonyms: | 18O2;Dioxygen-18; Oxygen (18O2); Oxygen, molecule (18O2); Oxygen-18 molecule (18O2);Oxygen-18O2 | ||||||||||
Density: | 1.11 (vs air) | ||||||||||
Melting Point: |
−218 °C(lit.) |
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Boiling Point: |
−183 °C(lit.) |
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Hazard Symbols: | |||||||||||
Risk Codes: | 8 | ||||||||||
Safety: |
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PSA: | 34.14000 | ||||||||||
LogP: | 0.06700 |
Conditions | Yield |
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In neat (no solvent, gas phase) byproducts: Xe, HF; at 50°C for 3 h; fractional distn. at low temp.; | 99% |
Conditions | Yield |
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In sulfuric acid React. at 23°C.; | A 27% B n/a C <1 D n/a E 73% |
In sulfuric acid React. at 23°C.; |
Conditions | Yield |
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In benzene byproducts: C(18)O2, C(18)O; Irradiation (UV/VIS); high-pressure Hg lamp, 30 min; not isolated, (18)O2 detd. by mass spectroscopy; | A n/a B 26% |
Conditions | Yield |
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In sulfuric acid React. at 23°C in aq. CF3CO2H.; | A 9% B n/a C >90 D n/a E <1 |
Conditions | Yield |
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With sodium hydroxide In water Kinetics; byproducts: HO(1-); evacuation of ampoule with frozen ozone, water labelled with (18)O and NaOH (0.1-2 M) (addn. of natural O2 to some ampoules), ampoules sealing,leaving at 20+/-1°C for 5-20 h; determination of isotopic compn. of liberated oxygen, detection of short living radicals using different acceptors; |
Conditions | Yield |
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titanium disilicide In water Irradiation (UV/VIS); suspn. of TiSi2 in either tridistilled or tap water with 10% H2(18)O at pH 7 was irradiated at 50 to 85°C with stirring under N2 or Ar; gas chromy., mass-spectrometry; |
Conditions | Yield |
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copper(I) oxide In neat (no solvent) Irradiation (UV/VIS); at room temp. with irradiation by visible light; |
Conditions | Yield |
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With ammonium cerium(IV) nitrate In water pH=1.0, 25 °C; monitored by MS; | |
With sulfuric acid pH=0.0; Catalytic behavior; Electrochemical reaction; | |
With sodium persulfate; tris(2,2'-bipyridine)ruthenium(II) perchlorate; 27Na(1+)*103H2O*Fe11(H2O)14(OH)2(W3O10)2(SbW9O33)6(27-) at 25℃; pH=10; Irradiation; |
Conditions | Yield |
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With titanium(IV) oxide In water Kinetics; byproducts: H(1+); Irradiation (UV/VIS); irradiated under Ar for 5 h; |
Conditions | Yield |
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With manganese(II) sulfate In water Kinetics; Irradiation (UV/VIS); catalytic oxidn. of H2(18)O in a three-chamber glass vessel while shaking deaerated aq. solns. of reagents (Ru- and Mn-compds., vesicles and a buffer soln.), photocatalytic liberation of (18)O2; detn. of (18)O2 by gas chromy.; |