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32767-18-3

Basic Information
CAS No.: 32767-18-3
Name: OXYGEN-18O2, 97 ATOM % 18O
Article Data: 86
Molecular Structure:
Molecular Structure of 32767-18-3 (OXYGEN-18O2, 97 ATOM % 18O)
Formula: O2
Molecular Weight: 38.0159
Synonyms: 18O2;Dioxygen-18; Oxygen (18O2); Oxygen, molecule (18O2); Oxygen-18 molecule (18O2);Oxygen-18O2
Density: 1.11 (vs air)
Melting Point: −218 °C(lit.)
Boiling Point: −183 °C(lit.)
Hazard Symbols:
Risk Codes: 8
Safety:
Hazard Codes O
Risk Statements 8
Safety Statements 17
RIDADR UN 1072 2.2
WGK Germany 3
PSA: 34.14000
LogP: 0.06700
Synthetic route
13709-36-9

xenon difluoride

14797-71-8

18O-labeled water

32767-18-3

oxygen-18

Conditions
ConditionsYield
In neat (no solvent, gas phase) byproducts: Xe, HF; at 50°C for 3 h; fractional distn. at low temp.;99%

cobalt(III)

14797-71-8

18O-labeled water

A

oxygen

B

cobalt(II)

C

80937-33-3

oxygen

D

hydrogen cation

E

32767-18-3

oxygen-18

Conditions
ConditionsYield
In sulfuric acid React. at 23°C.;A 27%
B n/a
C <1
D n/a
E 73%
In sulfuric acid React. at 23°C.;

Ti((18)O2)(meso-tetra-m-tolyl-porphinato)

Ti(18)O(meso-tetra-m-tolyl-porphinato)

B

32767-18-3

oxygen-18

Conditions
ConditionsYield
In benzene byproducts: C(18)O2, C(18)O; Irradiation (UV/VIS); high-pressure Hg lamp, 30 min; not isolated, (18)O2 detd. by mass spectroscopy;A n/a
B 26%

cobalt(III)

A

oxygen

B

cobalt(II)

C

80937-33-3

oxygen

D

hydrogen cation

E

32767-18-3

oxygen-18

Conditions
ConditionsYield
In sulfuric acid React. at 23°C in aq. CF3CO2H.;A 9%
B n/a
C >90
D n/a
E <1

H(18)O(1-)

32767-18-3

oxygen-18

Conditions
ConditionsYield
With sodium hydroxide In water Kinetics; byproducts: HO(1-); evacuation of ampoule with frozen ozone, water labelled with (18)O and NaOH (0.1-2 M) (addn. of natural O2 to some ampoules), ampoules sealing,leaving at 20+/-1°C for 5-20 h; determination of isotopic compn. of liberated oxygen, detection of short living radicals using different acceptors;
14797-71-8

18O-labeled water

A

oxygen

B

1333-74-0

hydrogen

C

80937-33-3

oxygen

D

32767-18-3

oxygen-18

Conditions
ConditionsYield
titanium disilicide In water Irradiation (UV/VIS); suspn. of TiSi2 in either tridistilled or tap water with 10% H2(18)O at pH 7 was irradiated at 50 to 85°C with stirring under N2 or Ar; gas chromy., mass-spectrometry;

ice

14797-71-8

18O-labeled water

A

oxygen

B

1173018-52-4

dioxygen-(16)O

C

1333-74-0

hydrogen

D

32767-18-3

oxygen-18

Conditions
ConditionsYield
copper(I) oxide In neat (no solvent) Irradiation (UV/VIS); at room temp. with irradiation by visible light;

ice

14797-71-8

18O-labeled water

A

oxygen

B

1173018-52-4

dioxygen-(16)O

C

32767-18-3

oxygen-18

Conditions
ConditionsYield
With ammonium cerium(IV) nitrate In water pH=1.0, 25 °C; monitored by MS;
With sulfuric acid pH=0.0; Catalytic behavior; Electrochemical reaction;
With sodium persulfate; tris(2,2'-bipyridine)ruthenium(II) perchlorate; 27Na(1+)*103H2O*Fe11(H2O)14(OH)2(W3O10)2(SbW9O33)6(27-) at 25℃; pH=10; Irradiation;

ice

silver sulfate

14797-71-8

18O-labeled water

A

oxygen

B

1173018-52-4

dioxygen-(16)O

C

7440-22-4

silver

D

32767-18-3

oxygen-18

Conditions
ConditionsYield
With titanium(IV) oxide In water Kinetics; byproducts: H(1+); Irradiation (UV/VIS); irradiated under Ar for 5 h;
14797-71-8

18O-labeled water

A

hydrogen cation

B

32767-18-3

oxygen-18

Conditions
ConditionsYield
With manganese(II) sulfate In water Kinetics; Irradiation (UV/VIS); catalytic oxidn. of H2(18)O in a three-chamber glass vessel while shaking deaerated aq. solns. of reagents (Ru- and Mn-compds., vesicles and a buffer soln.), photocatalytic liberation of (18)O2; detn. of (18)O2 by gas chromy.;
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