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3279-26-3

Basic Information
CAS No.: 3279-26-3
Name: METHYL PHOSPHORODICHLORIDITE
Article Data: 26
Molecular Structure:
Molecular Structure of 3279-26-3 (METHYL PHOSPHORODICHLORIDITE)
Formula: CH3Cl2OP
Molecular Weight: 132.914
Synonyms: Methylphosphorodichloridite (6CI,7CI);Dichloro methyl phosphite;Dichloromethoxyphosphine;Methoxydichlorophosphine;Methoxyphosphonousdichloride;Methyl dichlorophosphinite;Methyl dichlorophosphite;O-Methylphosphorodichloridite;
EINECS: 221-915-3
Density: 1.376 g/mL at 20 °C(lit.)
Melting Point: -91 °C(lit.)
Boiling Point: 89.4 °C at 760 mmHg
Flash Point: 7.9 °C
Solubility: Reacts with water. Soluble in chloroform, dichloromethane and ethyl acetate.
Appearance: colourless liquid
Hazard Symbols: CorrosiveC
Risk Codes: 10-14-34-37
Safety: 26-36/37/39-45
Transport Information: UN 2920 8/PG 2
PSA: 22.82000
LogP: 2.33730
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Specification

The CAS register number of Methyl phosphorodichloridite is 3279-26-3. It also can be called as Phosphorodichloridous acid, methyl ester and the IUPAC name about this chemical is dichloro(methoxy)phosphane. The molecular formula about this chemical is CH3Cl2OP and the molecular weight is 132.91. It belongs to the following product categories which include Pyridine; All Aliphatics; Biochemistry; Nucleosides, Nucleotides & Related Reagents; Phosphorylating and Phosphorothioating Agents; Phosphorylation; Protecting Agents, Phosphorylating Agents & Condensing Agents; Synthetic Organic Chemistry; Aliphatics; Phosphorylating and Phosphitylating Agents and so on.

Physical properties about Methyl phosphorodichloridite are: (1)ACD/LogP: 3.29; (2)ACD/LogD (pH 5.5): 3.29; (3)ACD/LogD (pH 7.4): 3.29; (4)ACD/BCF (pH 5.5): 184.79; (5)ACD/BCF (pH 7.4): 184.79; (6)ACD/KOC (pH 5.5): 1459.16; (7)ACD/KOC (pH 7.4): 1459.16; (8)#H bond acceptors: 1; (9)#Freely Rotating Bonds: 1; (10)Polar Surface Area: 22.82Å2; (11)Flash Point: 7.9 °C; (12)Enthalpy of Vaporization: 31.58 kJ/mol; (13)Boiling Point: 89.4 °C at 760 mmHg; (14)Vapour Pressure: 66.3 mmHg at 25°C.

Preparation: this chemical can be prepared by methanol. This reaction will need reagent PCl3, Py and solvent diethyl ether.

Uses of Methyl phosphorodichloridite: it can be used to produce phosphorous acid tetramethyldiamide methylester with dimethylamine. It will need solvent diethyl ether.

When you are using this chemical, please be cautious about it as the following:
This chemical is flammable and it is irritating to respiratory system. It can react violently with water. It also can cause burns. When you are using it, wear suitable protective clothing, gloves and eye/face protection. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)

You can still convert the following datas into molecular structure:
(1)SMILES: ClP(Cl)OC
(2)InChI: InChI=1/CH3Cl2OP/c1-4-5(2)3/h1H3
(3)InChIKey: HCSDJECSMANTCX-UHFFFAOYAJ
(4)Std. InChI: InChI=1S/CH3Cl2OP/c1-4-5(2)3/h1H3
(5)Std. InChIKey: HCSDJECSMANTCX-UHFFFAOYSA-N