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CAS No.: | 32970-45-9 |
---|---|
Name: | 2-(tert-butoxy)butane |
Article Data: | 12 |
Molecular Structure: | |
Formula: | C8H18 O |
Molecular Weight: | 130.23 |
Synonyms: | Ether,sec-butyl tert-butyl (6CI); 2-Butyl tert-butyl ether; sec-Butyl tert-butylether |
Density: | 0.778g/cm3 |
Boiling Point: | 117°Cat760mmHg |
Flash Point: | 13.7°C |
PSA: | 9.23000 |
LogP: | 2.60000 |
Conditions | Yield |
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With erbium(III) triflate at 20 - 40℃; for 6h; Inert atmosphere; neat (no solvent); | 97% |
Conditions | Yield |
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With sulfocationite KU-23 at 66.4℃; Thermodynamic data; var. temp., var. times; ΔrHmo, ΔrSmo; | |
With sulfuric acid at 75℃; | |
With sulfuric acid at 75℃; |
Conditions | Yield |
---|---|
With pyridine |
tert-Butyl peroxybenzoate
sec-butylmagnesium bromide
2-(tert-butoxy)butane
Conditions | Yield |
---|---|
In diethyl ether |
Conditions | Yield |
---|---|
With activated clay In cyclohexane at 74 - 78℃; for 6h; | 13.6 %Chromat. |
2-(tert-butoxy)butane
boron trichloride
A
s-butyl chloride
B
tri-sec-butylborate
C
tertiary butyl chloride
Conditions | Yield |
---|---|
at -80℃; |
2-(tert-butoxy)butane
iso-butanol
Conditions | Yield |
---|---|
With erbium(III) triflate In methanol at 100℃; for 0.75h; Microwave irradiation; |