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333-18-6

Basic Information
CAS No.: 333-18-6
Name: Ethylenediamine dihydrochloride
Article Data: 27
Molecular Structure:
Molecular Structure of 333-18-6 (Ethylenediamine dihydrochloride)
Formula: C2H8N2.2(HCl)
Molecular Weight: 133.021
Synonyms: 1,2-Ethanediamine,dihydrochloride (9CI);Ethylenediamine, dihydrochloride (8CI);1,2-Diaminoethane dihydrochloride;Chlor-ethamine;Dimethylenediaminedihydrochloride;Ethylenediamine hydrochloride;Ethylenediammonium dichloride;
EINECS: 206-369-6
Density: 1.159g/cm3
Melting Point: >300 °C(lit.)
Boiling Point: 119.7 °C at 760 mmHg
Flash Point: 33.9 °C
Solubility: 300 g/L (20 °C) in water
Appearance: white crystalline powder
Hazard Symbols: HarmfulXn
Risk Codes: 22-36/37/38-42/43
Safety: 22-26-36/37-45
PSA: 52.04000
LogP: 1.90840
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Chemistry

IUPAC Name: Ethane-1,2-diamine dihydrochloride
Synonyms of Ethylenediamine hydrochloride (CAS NO.542-90-5) : 1,2-Diaminoethane dihydrochloride ; 1,2-Ethanediamine, dihydrochloride ; Chlor-ethamine ; Dimethylenediamine dihydrochloride ; Ethylenediamine dihydrochloride ; 1,2-Ethanediamine, hydrochloride (1:2)
Product Categories: Pharmaceutical Intermediates;Sulphur Derivatives
CAS NO:542-90-5
Molecular Formula:C2H10Cl2N2
Molecular Weight :133.020200 g/mol
Molecular Structure :
EINECS: 206-369-6 
Flash Point: 33.9 °C
Enthalpy of Vaporization: 37.98 kJ/mol
Boiling Point: 119.7 °C at 760 mmHg
Vapour Pressure: 15.8 mmHg at 25°C
Melting Point: >300 °C(lit.)
Water Solubility : 300 g/L (20 ºC)
Sensitive: Hygroscopic
Stability: Stable. Incompatible with strong oxidizing agents.
Appearance: Ethylenediamine hydrochloride (CAS NO.542-90-5) is white crystalline powder.

Uses

 Ethylenediamine hydrochloride (CAS NO.542-90-5) is used as analytical reagents and curing agent, which is also used in dye synthesis.

Production

Raw materials: Hydrochloric acid-->Ethylenediamine

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intraperitoneal 1064mg/kg (1064mg/kg)   Yakugaku Zasshi. Journal of Pharmacy. Vol. 97, Pg. 1117, 1977.
mouse LD50 oral 1620mg/kg (1620mg/kg)   Fundamental and Applied Toxicology. Vol. 3, Pg. 512, 1983.
mouse LD50 subcutaneous 940mg/kg (940mg/kg)   Arzneimittel-Forschung. Drug Research. Vol. 4, Pg. 649, 1954.
rabbit LD50 skin > 6400mg/kg (6400mg/kg)   Kiso to Rinsho. Clinical Report. Vol. 3, Pg. 512, 1983.
rat LD50 intramuscular 150mg/kg (150mg/kg)   Experimental Medicine and Surgery. Vol. 4, Pg. 223, 1946.
rat LDLo oral 500mg/kg (500mg/kg)   Journal of Pharmacology and Experimental Therapeutics. Vol. 90, Pg. 260, 1947.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Poison by intramuscular route. Moderately toxic by ingestion. Experimental teratogenic and reproductive effects. When heated to decomposition it emits very toxic fumes of HCl and NOx.

Hazard Codes HarmfulXn
Risk Statements 22-36/37/38-42/43
R22:Harmful if swallowed. 
R42/43:May cause sensitization by inhalation and skin contact. 
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements 22-26-36/37-45
S22:Do not breathe dust. 
S26: When Ethylenediamine hydrochloride (CAS NO.542-90-5) is used,in case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36/37:Wear suitable protective clothing and gloves. 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
WGK Germany 2
RTECS KV3850000
HS Code 29212100