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CAS No.: | 3424-93-9 |
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Name: | 4-Methoxybenzamide |
Article Data: | 403 |
Molecular Structure: | |
Formula: | C8H9NO2 |
Molecular Weight: | 151.165 |
Synonyms: | p-Anisamide(6CI,7CI,8CI);Anisamide;NSC 11139;p-Methoxybenzamide; |
EINECS: | 222-319-6 |
Density: | 1.144 g/cm3 |
Melting Point: | 164-167 °C(lit.) |
Boiling Point: | 295.803 °C at 760 mmHg |
Flash Point: | 161.563 °C |
Appearance: | White crystalline powder |
Hazard Symbols: | Xn |
Risk Codes: | 36/37/38 |
Safety: | 22-24/25 |
PSA: | 52.32000 |
LogP: | 1.49440 |
Conditions | Yield |
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With C18H57O3P6Ru2(1+)*C6H5O(1-)*C6H6O; water In 1,4-dioxane for 6h; Time; Sealed tube; Inert atmosphere; Schlenk technique; | 100% |
With [bis(2-methylallyl)cycloocta-1,5-diene]ruthenium(II); water; 2-(diphenylphosphino)-N,N-dimethylpyridine-4-amine In 1,2-dimethoxyethane at 80℃; for 5h; | 99% |
With C12H24O16Ru3*2H2O In water at 110℃; for 13h; Catalytic behavior; Schlenk technique; Inert atmosphere; | 99% |
Conditions | Yield |
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With hydroxylamine; C33H28F3N5O3Ru(1+)*Cl(1-) In water at 60℃; for 0.5h; Catalytic behavior; Sonication; | 99% |
Stage #1: 4-methoxy-benzaldehyde With hydroxylamine hydrochloride; caesium carbonate In water; dimethyl sulfoxide at 100℃; Stage #2: With palladium diacetate In water; dimethyl sulfoxide at 125℃; chemoselective reaction; | 97% |
With copper(ll) sulfate pentahydrate; hydroxylamine hydrochloride; sodium acetate at 110℃; for 2h; Neat (no solvent); | 97% |
Conditions | Yield |
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Stage #1: 4-methoxybenzoic acid With 1,3,5-trichloro-2,4,6-triazine; potassium carbonate In tetrahydrofuran for 0.0166667h; Milling; Stage #2: With ammonium thiocyanate In tetrahydrofuran for 0.0833333h; Milling; | 99% |
With pyridine; urea for 0.00833333h; microwave irradiation; | 90% |
Stage #1: 4-methoxybenzoic acid With thionyl chloride In tetrahydrofuran at 50℃; for 1h; Stage #2: With ammonium hydroxide In tetrahydrofuran at 0℃; for 0.0833333h; | 84% |
N-tert-butyl-4-methoxybenzamide
4-methoxyphenylacetamide
Conditions | Yield |
---|---|
scandium tris(trifluoromethanesulfonate) In nitromethane at 170℃; for 1h; Irradiation; | 99% |
With t-butyldimethylsiyl triflate In toluene at 100℃; for 8h; | 74% |
Conditions | Yield |
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With dmap at 135℃; under 3000.3 Torr; for 7h; Pressure; Temperature; Reagent/catalyst; | 99% |
Conditions | Yield |
---|---|
With ammonia Inert atmosphere; | 98% |
With ammonia at -10 - 20℃; for 1h; Temperature; | 96.3% |
With ammonia In water at 20℃; for 1h; | 79% |
Conditions | Yield |
---|---|
With tert.-butylhydroperoxide; ammonia; oxygen In water; N,N-dimethyl-formamide at 80℃; under 1520.1 Torr; for 5h; Green chemistry; | 98% |
Stage #1: 4-Methoxybenzyl alcohol With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; ammonia; oxygen; copper(II) nitrate In water; dimethyl sulfoxide at 80℃; under 760.051 Torr; for 5h; Stage #2: With Acetaldehyde oxime In water; dimethyl sulfoxide at 110℃; for 24h; Inert atmosphere; | 97% |
With ammonia; oxygen In water at 150℃; under 22502.3 Torr; for 3h; | 96.5% |
Conditions | Yield |
---|---|
With manganese(IV) oxide at 130℃; under 4560.31 Torr; for 3h; | 98% |
With dihydrogen peroxide at 80℃; for 10h; Inert atmosphere; | 96% |
With (carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II); potassium tert-butylate In tert-butyl alcohol at 70℃; for 12h; | 95% |
Conditions | Yield |
---|---|
With (1,4-diazabicyclo{2.2.2}-octane)zinc(II) tetrahydoborate In tetrahydrofuran for 48h; Ambient temperature; | 97% |
With 1,3-diadamantane-4,5-dihydroimidazole chloride; potassium tert-butylate; bis(pinacol)diborane; copper(l) chloride In toluene at 25℃; for 4h; Schlenk technique; Inert atmosphere; | 94% |
With sodium tetrahydroborate; copper(II) sulfate In methanol at 0 - 5℃; for 1h; | 92% |
Conditions | Yield |
---|---|
With hydroxylamine In ethanol for 3h; Reagent/catalyst; Reflux; | A 97% B n/a |
With hydroxylamine hydrochloride; sodium hydroxide In ethanol; water Reflux; |
Product Name: 4-Methoxybenzamide
The MF of 4-Methoxybenzamide (3424-93-9) is C8H9NO2.
The MW of 4-Methoxybenzamide (3424-93-9) is 151.16.
Synonyms of 4-Methoxybenzamide (3424-93-9): p-Anisamide ; p-Methoxybenzamide
Product Categories: Aromatic Carboxylic Acids,Anilides, Anhydrides & Salts
Form: white crystalline powder
Index of Refraction: 1.546
EINECS: 222-319-6
Density: 1.143 g/ml
Flash Point: 161.5 °C
Boiling Point: 295.8 °C
Melting Point: 164-167 °C
BRN: 1862847
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
mammal (species unspecified) | LD50 | unreported | 1gm/kg (1000mg/kg) | Pharmaceutical Chemistry Journal Vol. 28, Pg. 335, 1994. |
Safety information of 4-Methoxybenzamide (3424-93-9):
Risk Statements
36/37/38 Irritating to eyes, respiratory system and skin
Safety Statements
22 Do not breathe dust
24/25 Avoid contact with skin and eyes
WGK Germany 3
RTECS CV5466666