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351-36-0

Basic Information
CAS No.: 351-36-0
Name: 3-(TRIFLUOROMETHYL)ACETANILIDE
Article Data: 43
Molecular Structure:
Molecular Structure of 351-36-0 (3-(TRIFLUOROMETHYL)ACETANILIDE)
Formula: C9H8F3NO
Molecular Weight: 203.164
Synonyms: m-Acetotoluidide,α,α,α-trifluoro- (6CI,7CI,8CI);N-(3-Trifluoromethylphenyl)acetamide;N-Acetyl-α,α,α-trifluoro-m-toluidine;m-(Trifluoromethyl)acetanilide;α,α,α-Trifluoro-m-acetotoluidide;
EINECS: 206-512-2
Density: 1.302 g/cm3
Melting Point: 103-106 °C(lit.)
Boiling Point: 292.006 °C at 760 mmHg
Flash Point: 130.401 °C
Appearance: white to off-white crystals or crystalline powder
Hazard Symbols: HarmfulXn,IrritantXi
Risk Codes: 22-36/37/38
Safety: 26-36
PSA: 29.10000
LogP: 2.73680
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  • N-[3-(trifluoromethyl)phenyl]acetamide

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    N-[3-(trifluoromethyl)phenyl]acetamide

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Specification

The Acetamide, N-[3-(trifluoromethyl)phenyl]-, with the CAS registry number of 351-36-0, is also known as 3-(Trifluoromethyl)acetanilide and Acetanilide, 3-(trifluoromethyl)-. It belongs to the product categories of Anilines, Amides & Amines; Fluorine Compounds. Its EINECS registry number is 206-512-2. This chemical's molecular formula is C9H8F3NO and molecular weight is 203.16. What's more, its IUPAC name is N-[3-(Trifluoromethyl)phenyl]acetamide. Besides, it can be stored at room temperature.

Physical properties about Acetamide, N-[3-(trifluoromethyl)phenyl]- are: (1)ACD/LogP: 2.20; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 2.2; (4)ACD/LogD (pH 7.4): 2.2; (5)ACD/BCF (pH 5.5): 27.67; (6)ACD/BCF (pH 7.4): 27.67; (7)ACD/KOC (pH 5.5): 374.8; (8)ACD/KOC (pH 7.4): 374.8; (9)#H bond acceptors: 2; (10)#H bond donors: 1; (11)#Freely Rotating Bonds: 1; (12)Polar Surface Area: 20.31 Å2; (13)Index of Refraction: 1.495; (14)Molar Refractivity: 45.5 cm3; (15)Molar Volume: 156 cm3; (16)Polarizability: 18.03×10-24 cm3; (17)Surface Tension: 31 dyne/cm; (18)Density: 1.302 g/cm3; (19)Flash Point: 130.4 °C; (20)Enthalpy of Vaporization: 53.15 kJ/mol; (21)Boiling Point: 292 °C at 760 mmHg; (22)Vapour Pressure: 0.00188 mmHg at 25 °C; (23)Melting Point: 103-106 °C(lit. ).

Uses: it is used to produce other chemicals. For example, it is used to produce N-(2-Fluoro-3-trifluoromethyl-phenyl)-acetamide. This reaction needs reagent CH3COOF. Meanwhile, it needs solvents CH2Cl2 and CCl3F. The reaction temperature is -75 ℃. The yield is about 34 %.

When you are using this chemical, please be cautious about it as the following:
As a chemical, it is irritating to eyes, respiratory system and skin. In addition, this chemical may harmful if swallowed. During using it, wear suitable protective clothing. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
(1) SMILES: O=C(Nc1cc(ccc1)C(F)(F)F)C
(2) InChI: InChI=1/C9H8F3NO/c1-6(14)13-8-4-2-3-7(5-8)9(10,11)12/h2-5H,1H3,(H,13,14)
(3) InChIKey: HNIPNANLYHXYDE-UHFFFAOYAI

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intraperitoneal 250mg/kg (250mg/kg)   National Technical Information Service. Vol. AD277-689,
mouse LD50 oral 550mg/kg (550mg/kg)   Toxicology and Applied Pharmacology. Vol. 19, Pg. 20, 1971.