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| CAS No.: | 3536-96-7 |
|---|---|
| Name: | Vinylmagnesium chloride |
| Article Data: | 8 |
| Molecular Structure: | |
|
|
|
| Formula: | C2H3ClMg |
| Molecular Weight: | 86.8038 |
| Synonyms: | Magnesium,chlorovinyl- (7CI,8CI);Vinylmagnesium chloride (6CI);Chloroethenylmagnesium;Ethenylmagnesium chloride; |
| EINECS: | 222-575-9 |
| Density: | 0.980g/mLat 20°C |
| Boiling Point: | 66 °C |
| Flash Point: | ?1°F |
| Solubility: | vigorous reaction |
| Appearance: | dark brown solution |
| Hazard Symbols: |
 F, C
|
| Risk Codes: | 11-14/15-19-22-34 |
| Safety: | 16-26-36/37/39-43-45-7/8 |
| PSA: | 0.00000 |
| LogP: | 1.36870 |
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| Conditions | Yield |
|---|---|
| With magnesium In tetrahydrofuran | |
| With magnesium In tetrahydrofuran at 50℃; for 0.75h; | |
| With magnesium; ethylene dibromide In tetrahydrofuran at 25 - 60℃; | |
| With magnesium In tert-butyl methyl ether at 50℃; for 8h; Inert atmosphere; |
| Conditions | Yield |
|---|---|
| In tetrahydrofuran | |
| Stage #1: magnesium With iodine; ethylene dibromide In tetrahydrofuran at 60 - 64℃; Stage #2: chloroethylene In tetrahydrofuran at 60 - 64℃; |
| Conditions | Yield |
|---|---|
| In tetrahydrofuran at 0℃; for 2h; Inert atmosphere; | 100% |
| In tetrahydrofuran at -10 - 20℃; Schlenk technique; | 95% |
| In tetrahydrofuran at -10℃; for 2h; Inert atmosphere; | 93% |
| Conditions | Yield |
|---|---|
| In tetrahydrofuran at -20℃; for 0.333333h; | 100% |
- 3536-96-7
vinylmagnesium chloride
| Conditions | Yield |
|---|---|
| In tetrahydrofuran at 0℃; | 100% |
- 457948-95-7
2-(4-fluorophenyl)-N-methoxy-N-methylacetamide
- 3536-96-7
vinylmagnesium chloride
A
- 860642-35-9
1-(4-fluorophenyl)but-3-en-2-one
B
- 119114-45-3
2-(4-fluorophenyl)-N-methoxyacetamide
D
- 78191-00-1
N-Methoxy-N-methylacetamide
| Conditions | Yield |
|---|---|
| Stage #1: 2-(4-fluorophenyl)-N-methoxy-N-methylacetamide; vinylmagnesium chloride In tetrahydrofuran; toluene at -30℃; for 2h; Stage #2: With acetic anhydride In tetrahydrofuran; toluene at -30℃; for 0.5h; Stage #3: With ammonium chloride In tetrahydrofuran; water; toluene at -30 - 10℃; | A 100% B n/a C n/a D n/a |
- 98632-84-9
(R,R)-2,3-butanediol (dichloromethyl)boronate
- 18680-27-8
pinanediol
- 3536-96-7
vinylmagnesium chloride
| Conditions | Yield |
|---|---|
| With zinc(II) chloride In tetrahydrofuran; Petroleum ether to borolane (THF, -78°C) added vinylmagnesium chloride (THF), after 15 min ZnCl2 (THF) added, warmed (0°C), stirred (4h), filtered without moisture, concd. in vac., treated with petroleum ether, filtered, diol added, stirred; after 15 h aq. phase separated, extracted with ether, combined extracts dried over Na2SO4, concd., (1)H-NMR; | 100% |
- 154675-56-6
bis[(μ-dimethylsilyl)(η5-cyclopentadienyl)]dichlorozirconium
- 3536-96-7
vinylmagnesium chloride
- 260786-65-0
[Zr(C5H3(CH3)4Si2C5H3)(CHCH2)2]
| Conditions | Yield |
|---|---|
| In tetrahydrofuran; tetrahydrofuran-d8 dichlorozirconocene in THF and soln. of MgCl(CHCH2) in THF-d8 was sealed in vac. (-78°C); heated (5 min, -50°C); not isolated; detected by NMR; | 100% |
| Conditions | Yield |
|---|---|
| In tetrahydrofuran; diethyl ether at -40℃; for 1.5h; Inert atmosphere; | 100% |
- 3536-96-7
vinylmagnesium chloride
- 14618-80-5
(R)-benzyl glycidol
- 814-68-6
acryloyl chloride
- 640298-47-1
Acrylic acid (R)-1-benzyloxymethyl-but-3-enyl ester
| Conditions | Yield |
|---|---|
| Stage #1: vinylmagnesium chloride; (R)-benzyl glycidol With copper(l) iodide In tetrahydrofuran at 0℃; for 1h; Stage #2: acryloyl chloride With ethylmagnesium bromide In tetrahydrofuran at 20℃; for 1.5h; | 100% |
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Chemistry
IUPAC Name: Magnesium ethene chloride
Molecular Formula: C2H3ClMg
Molecular Weight: 86.80g/mol
Density: 0.975g/cm3
Boiling Point: 66 °C at 760 mmHg
Flash Point: -17 ºC
Freely Rotating Bonds: 1
The Cas Register Number of Vinylmagnesium chloride is 3536-96-7 .The chemical synonyms of Vinylmagnesium chloride (CAS No.3536-96-7) are Vinylmagnesium chloride ; Vinylmagnesium chloride solution ; Chlorovinylmagnesium ; Vinylmagnesium ; Vinylmagnesium chloride, 1.6m solution in tetrahydrofuran ; Vinylmagnesium chloride solution, ~1.7 m in tetrahydrofuran ; Vinylmagnesium chloride, 15 wt% solution in tetrahydrofuran ; Vinylmagnesiumchloride,15%(w/w)solutionintetrahydrofuran .Product categories of Vinylmagnesium chloride (CAS No.3536-96-7) are Alkenyl ; Grignard reagents ; Organometallic reagents .The molecular structure of Vinylmagnesium chloride (CAS No.3536-96-7) is
.
Uses
It can be used in organic synthesis.
Safety Profile
Hazard Codes: 
F 
C
Risk Statements: 11-14/15-19-22-34
R11:Highly flammable.
R19:May form explosive peroxides.
R22:Harmful if swallowed.
R34:Causes burns.
Safety Statements: 16-26-36/37/39-43-45-7/8-43B-30
S16: Keep away from sources of ignition.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
S43: In case of fire use ... (there follows the type of fire-fighting equipment to be used.)
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S30: Never add water to this product.
RIDADR: UN 3399 4.3/PG 1
WGK Germany: 1
F: 1-3-10