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3566-10-7

Basic Information
CAS No.: 3566-10-7
Name: AMOBAM
Molecular Structure:
Molecular Structure of 3566-10-7 (AMOBAM)
Formula: C4H8 N2 S4 . 2 H3 N
Molecular Weight: 246.44
Synonyms: Carbamicacid, ethylenebis[dithio-, diammonium salt (8CI); Carbamodithioic acid, 1,2-ethanediylbis-,diammonium salt (9CI); Ambis; Ammonium 1,2-ethanebis(dithiocarbamate); Ammoniumethylenebis(dithiocarbamate); Amobam; Diammonium ethylenebis[dithiocarbamate];Dithane stainless; Ethylene-1,2-bis(ammonium dithiocarbamate)
Melting Point: 72.5-72.8oC
Safety: Poison by ingestion. When heated to decomposition it emits very toxic fumes of SOx and NOx.
PSA: 172.32000
LogP: 2.02460
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Chemistry

Molecular Formula: C4H14N4S4
Molar mass: 246.44 g/mol
EINECS: 222-651-1
Flash Point: 140.2 °C
Boiling Point: 308.2 °C at 760 mmHg
Vapour Pressure: 0.000692 mmHg at 25°C
Appearance: White colorless crystal
Solubility: Soluble in water, slightly soluble in ethanol, acetone, insoluble in benzene
Stable: Unstable in the air, chemical properties of aqueous solution more stable, but the temperature is higher than 40 ºC, easy to decompose the event of acidic substances
Product categories of Amobam (3566-10-7): Fertilizer and pesticides;Pesticides fungicides
Structure of Amobam (3566-10-7):

H-Bond Donor: 4
H-Bond Acceptor: 2
Systematic Name: Ammonia; [2-(dithiocarboxyamino)ethylamino]methanedithioic acid 
SMILES: S=C(S)NCCNC(=S)S.N.N 
InChI: InChI=1/C4H8N2S4.2H3N/c7-3(8)5-1-2-6-4(9)10;;/h1-2H2,(H2,5,7,8)(H2,6,9,10);2*1H3 
InChIKey: FROZIYRKKUFAOC-UHFFFAOYAC 
Std. InChI: InChI=1S/C4H8N2S4.2H3N/c7-3(8)5-1-2-6-4(9)10;;/h1-2H2,(H2,5,7,8)(H2,6,9,10);2*1H3 
Std. InChIKey: FROZIYRKKUFAOC-UHFFFAOYSA-N

Uses

 Amobam (3566-10-7) has been used on a variety of fungal diseases of crops, and it is valid for seed treatment, foliar spray and soil sterilization purposes.

Production

Adding Carbon disulfide into the mixture of Ethylenediamine and Ammonia for the reaction at 30 ºC, and then by filter press to get:  Amobam (3566-10-7). Consumption of raw materials fixed: ethylene diamine (98%) 130kg / t, carbon disulfide (98%) 340kg / t, ammonia (20%) 500kg / t.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 oral 540mg/kg (540mg/kg)   Yakkyoku. Pharmacy. Vol. 37, Pg. 187, 1986.
rat LD50 oral 395mg/kg (395mg/kg)   "Pesticide Index," Frear, E.H., ed., State College, PA, College Science Pub., 1969Vol. 5, Pg. 11, 1976.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Poison by ingestion. When heated to decomposition it emits very toxic fumes of SOx and NOx.

Specification

 Amobam (3566-10-7) also can be called Nabam ; Acide 1,2-éthanediyldicarbamodithioïque diammoniate ; 1,2-Ethanediyldicarbamodithioic acid diammoniate ; Diammonium 1,2-ethanediyldicarbamodithioate and 1,2-Ethandiyldicarbamindithiosäurediammoniat .