Products Categories
CAS No.: | 36309-88-3 | ||||||||||||
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Name: | TRIS(4,7-DIPHENYL-1,10-PHENANTHROLINE)RUTHENIUM (II) DICHLORIDE | ||||||||||||
Article Data: | 4 | ||||||||||||
Molecular Structure: | |||||||||||||
Formula: | C72H48 N6 Ru . 2 Cl | ||||||||||||
Molecular Weight: | 1169.19 | ||||||||||||
Synonyms: | Ruthenium(2+),tris(4,7-diphenyl-1,10-phenanthroline-N1,N10)-, dichloride, (OC-6-11)-;Ruthenium(2+), tris(4,7-diphenyl-1,10-phenanthroline-kN1,kN10)-, dichloride, (OC-6-11)- (9CI);1,10-Phenanthroline, 4,7-diphenyl-, ruthenium complex; Ruthenium (II)tris(4,7-diphenyl-1,10-phenanthroline) dichloride; Ruthenium(II)tris(4,7-diphenyl-1,10-phenanthrolin) chloride;Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium dichloride;Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium(2+) dichloride;Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium(II) chloride;Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium(II) dichloride | ||||||||||||
Density: | g/cm3 | ||||||||||||
Melting Point: | 275-279°C (dec.) | ||||||||||||
Boiling Point: | 543.1°Cat760mmHg | ||||||||||||
Flash Point: | 242.1°C | ||||||||||||
Solubility: | Soluble in alcohol and dimethylformamide. Insoluble in water. | ||||||||||||
Risk Codes: | 34 | ||||||||||||
Safety: |
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PSA: | 77.34000 | ||||||||||||
LogP: | 19.73000 |
tetrabutyl-ammonium chloride
ruthenium(II)-tris-4,7-diphenyl-1,10-phenanthroline dichloride
Conditions | Yield |
---|---|
In acetone | 95% |
[ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2
bathophenanthroline
ruthenium(II)-tris-4,7-diphenyl-1,10-phenanthroline dichloride
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide other Radiation; subjected to 300-W microwave irradn. at 250°C for 5 min; cooled, pptd. (CH2Cl2/Et2O), recrystd.; | 89% |
bathophenanthroline
ruthenium(II)-tris-4,7-diphenyl-1,10-phenanthroline dichloride
Conditions | Yield |
---|---|
In 1,2-dimethoxyethane for 72h; Inert atmosphere; Reflux; | 85% |
bathophenanthroline
ruthenium(II)-tris-4,7-diphenyl-1,10-phenanthroline dichloride
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 120℃; for 36h; Inert atmosphere; | 50% |
ruthenium(II)-tris-4,7-diphenyl-1,10-phenanthroline dichloride
Conditions | Yield |
---|---|
methatesis reaction of tris(4,7-diphenyl-1,10-phenanthroline)ruthenium(II) chloride with excess of NH4PF6; elem. anal.; | 40% |
ruthenium(II)-tris-4,7-diphenyl-1,10-phenanthroline dichloride
Conditions | Yield |
---|---|
With perchloric acid; oxygen for 0.333333h; Photolysis; |