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| CAS No.: | 37443-42-8 |
|---|---|
| Name: | Methyl 2-tetrahydrofuroate |
| Article Data: | 31 |
| Molecular Structure: | |
|
|
|
| Formula: | C6H10O3 |
| Molecular Weight: | 130.144 |
| Synonyms: | 2-Furoicacid, tetrahydro-, methyl ester (6CI);Methyl tetrahydro-2-furancarboxylate;Tetrahydro-2-furancarboxylic acid methyl ester;Tetrahydro-2-furoic acid methylester; |
| EINECS: | 420-670-1 |
| Density: | 1.108 g/cm3 |
| Boiling Point: | 158.8 °C at 760 mmHg |
| Flash Point: | 55.2 °C |
| Appearance: | Colourless clear and volatile liquid |
| Hazard Symbols: |
 Xi
|
| Risk Codes: | 41 |
| Safety: | 26-39 |
| PSA: | 35.53000 |
| LogP: | 0.33840 |
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- 16874-33-2
tetrahydro-2-furancarboxylic acid
- 67-56-1
methanol
- 37443-42-8
methyl tetrahydrofuran-2-carboxylate
| Conditions | Yield |
|---|---|
| With dimesitylammonium pentafluorobenzenesulfonate at 20℃; for 24h; | 92% |
| With dimesitylammonium pentafluorobenzenesulfonate at 22℃; for 11h; | 91% |
| dimesitylammonium pentafluorobenzenesulfonate at 20℃; for 11h; Product distribution / selectivity; | 91% |
- 611-13-2
2-furoic acid methyl ester
- 37443-42-8
methyl tetrahydrofuran-2-carboxylate
| Conditions | Yield |
|---|---|
| With methanol; nickel at 120℃; Hydrogenation.Unter Druck; | |
| at 160℃; Leiten ueber Palladium/Asbest im Wasserstoff-Strom; | |
| With palladium/alumina; hydrogen; Cinchonidin In isopropyl alcohol at 20℃; under 22501.8 Torr; | |
| With hydrogen In methanol at 99.84℃; under 30003 Torr; for 1h; Autoclave; | 12 %Chromat. |
| With hydrogen In methanol at 30℃; under 75007.5 Torr; for 72h; Reagent/catalyst; Temperature; Pressure; Autoclave; |
- 52449-98-6
tetrahydrofuran-2-carbonyl chloride
- 67-56-1
methanol
- 37443-42-8
methyl tetrahydrofuran-2-carboxylate
- 16874-33-2
tetrahydro-2-furancarboxylic acid
- 37443-42-8
methyl tetrahydrofuran-2-carboxylate
| Conditions | Yield |
|---|---|
| Multi-step reaction with 2 steps 1: SOCl2 View Scheme |
| Conditions | Yield |
|---|---|
| palladium-carbon In methanol | |
| palladium-carbon In methanol | |
| palladium-carbon In methanol |
- 611-13-2
2-furoic acid methyl ester
A
- 37443-42-8
methyl tetrahydrofuran-2-carboxylate
B
- 14273-92-8
methyl 5-hydroxypentanoate
| Conditions | Yield |
|---|---|
| With hydrogen In methanol at 99.84℃; under 30003 Torr; for 1h; Autoclave; | A 30 %Chromat. B 41 %Chromat. |
- 67-56-1
methanol
- 88-14-2
2-furanoic acid
A
- 542-28-9
3,4,5,6-tetrahydro-2H-pyran-2-one
B
- 16874-33-2
tetrahydro-2-furancarboxylic acid
C
- 37443-42-8
methyl tetrahydrofuran-2-carboxylate
D
- 14273-92-8
methyl 5-hydroxypentanoate
| Conditions | Yield |
|---|---|
| With hydrogen at 99.84℃; under 30003 Torr; for 1h; Catalytic behavior; Reagent/catalyst; Temperature; Pressure; Concentration; Autoclave; | A 6 %Chromat. B 9 %Chromat. C 11 %Chromat. D 47 %Chromat. |
- 67-56-1
methanol
- 88-14-2
2-furanoic acid
A
- 16874-33-2
tetrahydro-2-furancarboxylic acid
B
- 37443-42-8
methyl tetrahydrofuran-2-carboxylate
C
- 14273-92-8
methyl 5-hydroxypentanoate
| Conditions | Yield |
|---|---|
| With hydrogen at 99.84℃; under 30003 Torr; for 1h; Catalytic behavior; Reagent/catalyst; Autoclave; |
- 67-56-1
methanol
- 88-14-2
2-furanoic acid
A
- 16874-33-2
tetrahydro-2-furancarboxylic acid
B
- 37443-42-8
methyl tetrahydrofuran-2-carboxylate
| Conditions | Yield |
|---|---|
| With 5%-palladium/activated carbon; hydrogen at 99.84℃; under 30003 Torr; for 1h; Autoclave; |
- 88-14-2
2-furanoic acid
- 37443-42-8
methyl tetrahydrofuran-2-carboxylate
| Conditions | Yield |
|---|---|
| Multi-step reaction with 2 steps 1: hydrogen / 1 h / 99.84 °C / 30003 Torr / Autoclave 2: hydrogen / 1 h / 99.84 °C / 30003 Torr / Autoclave View Scheme | |
| Multi-step reaction with 2 steps 1: hydrogen / 1 h / 99.84 °C / 30003 Torr / Autoclave 2: hydrogen / 1 h / 99.84 °C / 30003 Torr / Autoclave View Scheme | |
| Multi-step reaction with 2 steps 1: hydrogen / 4 h / 99.84 °C / 30003 Torr / Autoclave 2: hydrogen / 1 h / 99.84 °C / 30003 Torr / Autoclave View Scheme | |
| Multi-step reaction with 2 steps 1: hydrogen; 5%-palladium/activated carbon / 1 h / 99.84 °C / 30003 Torr / Autoclave 2: hydrogen / 1 h / 99.84 °C / 30003 Torr / Autoclave View Scheme | |
| Multi-step reaction with 2 steps 1: hydrogen / isopropyl alcohol / 1 h / 99.84 °C / 30003 Torr / Autoclave 2: hydrogen / 1 h / 99.84 °C / 30003 Torr / Autoclave View Scheme |
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Chemistry
Molecular Formula: C6H10O3
Density: 1.108 g/cm3
EINECS: 420-670-1
Flash Point: 55.2 °C
Index of Refraction: 1.441
Molecular Weight: 130.141800 g/mol
IUPAC Name: methyl oxolane-2-carboxylate
Product Name: Methyl 2-tetrahydrofuroate
Enthalpy of Vaporization: 39.54 kJ/mol
Boiling Point: 158.8 °C at 760 mmHg
Vapour Pressure: 2.59 mmHg at 25°C
Appearance:Colorless, transparent volatile liquid
synonyms: 2-Tetrahydrofuroic acid methyl ester ; Methyl tetrahydrofuran-2-carboxylate ; Methyltetrahydrofuroate ; Methyl tetrahydro-2-furoate ; Methyl 2-tetrahydrofuroate ; Methfat ; Tetrahydrofuran-2-carboxylic acid methyl ester ; Tetra hydro-2-methyl furoate
Following is the molecular structure of Methyl 2-tetrahydrofuroate (37443-42-8):
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Uses
Methyl 2-tetrahydrofuroate (37443-42-8) used as pharmaceutical intermediates and solvents.
Safety Profile
Safety Information of Methyl 2-tetrahydrofuroate (37443-42-8):
Hazard Codes: Xi
Xi: Irritant .gif){kind=small}
Risk Statements: 41
41: Risk of serious damage to eyes
Safety Statements: 26-39
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
39: Wear eye/face protectio