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39562-22-6

Basic Information
CAS No.: 39562-22-6
Name: 2-Methoxyethyl 2-[(3-nitrophenyl)methylene]acetoacetate
Article Data: 8
Molecular Structure:
Molecular Structure of 39562-22-6 (2-Methoxyethyl 2-[(3-nitrophenyl)methylene]acetoacetate)
Formula: C14H15NO6
Molecular Weight: 293.276
Synonyms: 2-Methoxyethyl2-(3-nitrobenzylidene)acetoacetate;2-Methoxyethyl 2-(m-nitrobenzylidene)acetoacetate;Methoxyethyl 3 -Nitrobenzylidenacetoacetate;
EINECS: 254-511-0
Density: 1.266 g/cm3
Melting Point: 72-74 °C
Boiling Point: 433.4 °C at 760 mmHg
Flash Point: 182 °C
Appearance: a white crystalline
PSA: 98.42000
LogP: 2.28000
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66085-59-4
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  • Methoxyethyl 3-nitrobenzylidenacetoacetate

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  • 2-methoxyethyl 2-[(3-nitrophenyl)methylene]acetoacetate

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    2-methoxyethyl 2-[(3-nitrophenyl)methylene]acetoacetate

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    2-methoxyethyl 2-[(3-nitrophenyl)methylene]acetoacetate

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Chemistry

Molecular Structure of Methoxyethyl 3-nitrobenzylidenacetoacetate (CAS NO.24549-06-2):

IUPAC Name: 2-Methoxyethyl 2-[(3-nitrophenyl)methylene]acetoacetate 
Empirical Formula: C14H15NO6
Molecular Weight: 293.272
H bond acceptors: 7
H bond donors: 0
Freely Rotating Bonds: 8
Index of Refraction: 1.563
Molar Refractivity: 75.24 cm3
Molar Volume: 231.5 cm3
Surface Tension: 48.2 dyne/cm
Density: 1.266 g/cm3
Flash Point: 182 °C
Enthalpy of Vaporization: 68.93 kJ/mol
EINECS: 254-511-0
Melting Point: 72-74 °C
Boiling Point: 433.4 °C at 760 mmHg
Vapour Pressure: 1.03E-07 mmHg at 25°C
Smiles
C(\C(C(=O)C)=C\c1cc(ccc1)[N+](=O)[O-])(=O)OCCOC

Toxicity Data With Reference

1.    

eye-rbt 100 µL/24H MOD

    IJTOFN    International Journal of Toxicology. 19 (2000),332.
2.    

orl-rat LD50:5 g/kg

    IJTOFN    International Journal of Toxicology. 19 (2000),332.
3.    

ihl-rat LC50:>1401 mg/m3/4H

    IJTOFN    International Journal of Toxicology. 19 (2000),332.

Safety Profile

Low toxicity by ingestion and inhalation. A moderate eye irritant. When heated to decomposition it emits toxic vapors of NOx.

Specification

 Methoxyethyl 3-nitrobenzylidenacetoacetate , with CAS number of 24549-06-2, can be called 2-Methoxyethyl 2-((3-nitrophenyl)methylene)acetoacetate ; 2-Methoxyethyl 2-acetyl-3-(3-nitrophenyl)acrylate ; Methoxyrthyl-3-nitrobenzylidenacetoacetate ; 3-Nitrobenzylideneacetoacetate-2-methoxyethylester . It is a a white crystalline.