Products Categories
| CAS No.: | 3972-65-4 |
|---|---|
| Name: | 1-Bromo-4-tert-butylbenzene |
| Article Data: | 61 |
| Molecular Structure: | |
|
|
|
| Formula: | C10H13Br |
| Molecular Weight: | 213.117 |
| Synonyms: | Benzene,1-bromo-4-tert-butyl- (6CI,7CI,8CI);1-Bromo-4-(1,1-dimethylethyl)benzene;1-Bromo-4-t-butylbenzene;1-tert-Butyl-4-bromobenzene;4-Bromo-tert-butylbenzene;4-tert-Butyl-1-bromobenzene;4-tert-Butylbromobenzene;4-tert-Butylphenylbromide;B 1727;NSC 43038;p-Bromo-tert-butylbenzene;p-tert-Butylbromobenzene; |
| EINECS: | 223-599-2 |
| Density: | 1.236 g/cm3 |
| Melting Point: | 13-16 °C(lit.) |
| Boiling Point: | 232 °C at 760 mmHg |
| Flash Point: | 97.2 °C |
| Solubility: | Insoluble in water. |
| Appearance: | clear colorless to slightly yellow liquid |
| Hazard Symbols: |
 Xi
|
| Risk Codes: | 36/37/38 |
| Safety: | 23-24/25-37/39-26 |
| PSA: | 0.00000 |
| LogP: | 3.74660 |
- 483366-12-7(2S,4R)-1-Boc-2-cyano-4-hydroxypyrrolidine
- 5156-58-1N-(1-Benzyl-4-pipperidinyl)-N-phenylpropanamide HCl
- 81281-59-67-Benzylideneaminotheophylline
- 50288-62-5threo-Phenyl-2-piperidyl acetamide
- 82993-81-5D-threo-Ritalinic acid hydrochloride
- 47087-37-6Z-D-Glu-OMe
- 73441-42-6METHYL-5-CHLORO-2,2-DIMETHYLVALERATE
- 68439-39-4Poly(oxy-1,2-ethanediyl), alpha-(2-ethylhexyl)-omega-hydroxy-,
- 852475-26-4MC1568
- 43224-75-52,2,6,6-Tetramethyl-4-(2-propyleneoxy) Piperidine
- 253185-03-4, 253185-04-5
tert-butylbenzene
- 3972-65-4
1-bromo-4-tert-butylbenzene
| Conditions | Yield |
|---|---|
| With bromine; iodine at 0℃; | 100% |
| With carbon dioxide; bromine at 40℃; under 187519 Torr; for 2h; Supercritical conditions; Green chemistry; | 100% |
| With benzyltrimethylazanium tribroman-2-uide; zinc(II) chloride In acetic acid at 70℃; for 2h; | 95% |
| Conditions | Yield |
|---|---|
| 97% |
- 214360-66-4
2-(4-tert-butylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
- 3972-65-4
1-bromo-4-tert-butylbenzene
| Conditions | Yield |
|---|---|
| With copper(ll) bromide In methanol Heating; | 96% |
| Conditions | Yield |
|---|---|
| With sulfuric acid | 90% |
| Conditions | Yield |
|---|---|
| In hexane; 1,2-dichloro-ethane at 25 - 50℃; Inert atmosphere; | 89% |
- 108-86-1
bromobenzene
- 3282-30-2
pivaloyl chloride
A
- 3972-65-4
1-bromo-4-tert-butylbenzene
B
- 30314-45-5
1-(4-bromophenyl)-2,2-dimethylpropan-1-one
| Conditions | Yield |
|---|---|
| With iodine for 0.166667h; Ambient temperature; Irradiation; | A 8% B 87% |
| With iron(III) sulfate In hexane at 20℃; for 0.75h; Friedel-Crafts acylation; Sonication; | A 8% B 72% |
| With aluminium trichloride In hexane for 0.166667h; Ambient temperature; Irradiation; | A 25% B 50% |
- 154318-75-9
4-tert-butylphenyl triflate
- 3972-65-4
1-bromo-4-tert-butylbenzene
| Conditions | Yield |
|---|---|
| With [Cp*Ru(CH3CN)3]OTf; lithium bromide at 120℃; for 48h; Inert atmosphere; | 87% |
| Multi-step reaction with 2 steps 1: 86 percent / Et3N / PdCl2(dppf) / dioxane / Heating 2: 96 percent / aq. CuBr2 / methanol / Heating View Scheme |
- 3972-65-4
1-bromo-4-tert-butylbenzene
| Conditions | Yield |
|---|---|
| With tetra-N-butylammonium tribromide In tetrahydrofuran; water at 20℃; for 0.333333h; chemoselective reaction; | 86% |
| With tetra-N-butylammonium tribromide In tetrahydrofuran; water at 20℃; for 0.333333h; chemoselective reaction; | 86% |
- 176780-03-3, 164927-39-3
(P(o-tol)3)2Pd2(C6H4tBu-4)2Br2
- 13716-12-6
tri-tert-butyl phosphine
A
- 53199-31-8
bis(tri-t-butylphosphine)palladium(0)
B
- 3972-65-4
1-bromo-4-tert-butylbenzene
| Conditions | Yield |
|---|---|
| In benzene-d6 byproducts: P(o-tol)3, biaryl, arene; in C6D6 soln. at 70°C; K(eq) = 3.3(6)E-4; | A n/a B 75% |
- 108-86-1
bromobenzene
- 3282-30-2
pivaloyl chloride
A
- 3972-65-4
1-bromo-4-tert-butylbenzene
B
- 61593-14-4
1-(2-bromophenyl)-2,2-dimethyl-propan-1-one
C
- 30314-45-5
1-(4-bromophenyl)-2,2-dimethylpropan-1-one
| Conditions | Yield |
|---|---|
| With iodine for 6h; Ambient temperature; | A 64% B 6% C 17% |
| With aluminium trichloride In hexane for 5h; Ambient temperature; | A 42% B 5% C 12% |
- 3973-18-0Propynol ethoxylate
- 397843-71-9(3-Phenylaminocarbonylphenyl)boronic acid
- 39806-16-1(2E,4E)-5-PHENYL-PENTA-2,4-DIENOIC ACID ETHYL ESTER
- 39831-55-5Amikacin disulfate salt
- 39833-65-31-(chloromethyl)-3-vinylbenzene
- 398-36-74-(TRIFLUOROMETHYL)-BIPHENYL
- 398487-31-56-Quinolinecarbonitrile, 4-chloro-7-methoxy-
- 39979-46-91,1'-(2,2,4-trimethylhexane-1,6-diyl)bis-1H-pyrrole-2,5-dione
- 104987-11-3Tacrolimus
- 141-53-7Sodium formate
- 8001-54-5Quaternary ammonium compounds, alkylbenzyldimethyl, chlorides
- 9003-39-8Povidone
- 10161-34-9Trenbolone acetate
- 402957-28-2Telaprevir
- 68-19-9Cyanocobalamin
What can I do for you?
Get Best Price
Chemistry
IUPAC Name:1-bromo-4-tert-butylbenzene
Molecular Formula:C10H13Br
Molecular Weight:213.114220 g/mol
Appearance:Colorless liquid
Melting Point:13-16 °C(lit.)
Boiling Point:80-81 °C2 mm Hg(lit.)
Flash Point:97 °C
Solubility:benzene, xylene, chlorobenzene and other solvents.
Insolubility:water
density:1.229 g/mL at 25 °C(lit.)
refractive index n20/D 1.533(lit.)
BRN:1859117
CAS DataBase Reference:3972-65-4(CAS DataBase Reference)
NIST Chemistry Reference:3972-65-4(NIST)
Synonyms of 1-Bromo-4-tert-butylbenzene(3972-65-4):
P-BROMO-T-BUTYLBENZENE;4-BROMO-TERT-BUTYLBENZENE;2-(4'-BROMOPHENYL)-2-METHYLPROPANE;1-BROMO-P-T-BUTYLBENZENE;1-BROMO-4-T-BUTYLBENZENE;1-BROMO-4-TERT-BUTYLBENZENE;P-BROMO-TERT-BUTYLBENZENE;4-TERT-BUTYLBROMOBENZENE
Categories of 1-Bromo-4-tert-butylbenzene(3972-65-4):
Halides;Phenyls & Phenyl-Het;Phenyls & Phenyl-Het;Aryl;C9 to C12;Halogenated Hydrocarbons;Bromine Compounds
Uses
1-Bromo-4-tert-butylbenzene(3972-65-4) is used as a intermediate for the synthesis of Miticide Fenazaquin.
Safety Profile
Safety Information of 1-Bromo-4-tert-butylbenzene(3972-65-4):
Hazard Codes : Xi 
Risk Statements:36/37/38
36/37/38:Irritating to eyes, respiratory system and skin
Safety Statements:23-24/25-37/39-26
23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer)
24/25:Avoid contact with skin and eyes
37/39:Wear suitable gloves and eye/face protection
26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
WGK Germany:3
Hazard Note:Irritant
HS Code:29036990