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CAS No.: | 40851-62-5 | ||
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Name: | METHYL O-TOLYLACETATE | ||
Article Data: | 47 | ||
Molecular Structure: | |||
Formula: | C10H12 O2 | ||
Molecular Weight: | 164.204 | ||
Synonyms: | 2-Methylphenylaceticacid methyl ester; Methyl 2-methylphenylacetate; Methyl o-tolylacetate | ||
Density: | 1.035g/cm3 | ||
Boiling Point: | 229.8°Cat760mmHg | ||
Flash Point: | 101.9°C | ||
Safety: |
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PSA: | 26.30000 | ||
LogP: | 1.71050 |
Conditions | Yield |
---|---|
With sulfuric acid at 0℃; for 8h; Reflux; Inert atmosphere; | 100% |
With sulfuric acid for 6.5h; Inert atmosphere; Reflux; | 99% |
With sulfuric acid at 28℃; for 12h; | 98% |
o-methylphenylacetic acid
methyl o-tolylacetate
Conditions | Yield |
---|---|
With sulfuric acid In methanol | 98% |
With sulfuric acid In methanol | 98% |
With sulfuric acid In formic acid for 6h; Reflux; |
1-chloromethyl-2-methylbenzene
methyl o-tolylacetate
Conditions | Yield |
---|---|
94% |
Conditions | Yield |
---|---|
With sulfuric acid; trimethyl orthoformate at 20℃; for 0.333333h; | 91% |
methanol
2-Methylacetophenone
trimethyl orthoformate
methyl o-tolylacetate
Conditions | Yield |
---|---|
With iodine; silver nitrate for 5h; Heating; | 90% |
1-methoxycarbonylmethyl-2-methyl-2,5-cyclohexadiene-1-carboxylic acid
methyl o-tolylacetate
Conditions | Yield |
---|---|
With chlorosulfonic acid In dichloromethane at 0℃; for 0.166667h; | 87% |
methanol
carbon monoxide
2-methyl-benzyl alcohol
carbonic acid dimethyl ester
methyl o-tolylacetate
Conditions | Yield |
---|---|
With palladium(II) trifluoroacetate; 1,3-bis-(diphenylphosphino)propane at 135℃; under 15001.5 Torr; for 24h; Autoclave; Green chemistry; | 81% |
methanol
2-Methylacetophenone
A
methyl o-tolylacetate
B
2-methoxy-1-(2-methylphenyl)ethanone
Conditions | Yield |
---|---|
With [bis(acetoxy)iodo]benzene at 60℃; for 1h; | A 62% B 13% |
diazomethane
o-methylphenylacetic acid
methyl o-tolylacetate
Conditions | Yield |
---|---|
In diethyl ether |
o-(methoxycarbonylmethyl)benzoic acid
methyl o-tolylacetate
Conditions | Yield |
---|---|
(i) furan-2-carbonyl chloride, Et3N, (ii) H2, Pd(OH)2-BaSO4; Multistep reaction; |