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420-90-6

Basic Information
CAS No.: 420-90-6
Name: 3-Bromo-3,3-difluoropropene
Article Data: 8
Molecular Structure:
Molecular Structure of 420-90-6 (3-Bromo-3,3-difluoropropene)
Formula: C3H3BrF2
Molecular Weight: 156.958
Synonyms: Propene,3-bromo-3,3-difluoro- (6CI,7CI,8CI);1,1-Difluoroallyl bromide;3-Bromo-3,3-difluoro-1-propene;
EINECS: 810-594-0
Density: 1.614 g/cm3
Melting Point: 53-54 °C
Boiling Point: 41.999 °C at 760 mmHg
Flash Point: -4.642 °C
Hazard Symbols: IrritantXi
Risk Codes: 36/37/38
Safety: 26-36/37/39
PSA: 0.00000
LogP: 2.16010
Synthetic route
460-25-3

1,1-difluoro-1,3-dibromopropane

420-90-6

3-bromo-3,3-difluropropene

Conditions
ConditionsYield
With potassium hydroxide
460-25-3

1,1-difluoro-1,3-dibromopropane

A

420-90-6

3-bromo-3,3-difluropropene

B

60917-29-5

1,1-difluoro-3-bromo-1-propene

Conditions
ConditionsYield
With potassium hydroxide at 115 - 130℃; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
With potassium hydroxide In water at 120 - 160℃; Yield given. Yields of byproduct given;
With potassium hydroxide In water at 90 - 110℃; for 3h;
460-25-3

1,1-difluoro-1,3-dibromopropane

aqueous KOH-solution

aqueous KOH-solution

420-90-6

3-bromo-3,3-difluropropene

Conditions
ConditionsYield
at 80℃;
74-85-1

ethene

75-61-6

dibromodifluoromethane

420-90-6

3-bromo-3,3-difluropropene

420-90-6

3-bromo-3,3-difluropropene

100-52-7

benzaldehyde

85864-61-5

2,2-difluoro-1-phenyl-3-buten-1-ol

Conditions
ConditionsYield
With indium In water at 20℃; for 3h; Addition;100%
With indium In N,N-dimethyl-formamide for 3h; Ambient temperature;99%
With ammonium chloride; zinc In tetrahydrofuran allylation;84%
420-90-6

3-bromo-3,3-difluropropene

66-25-1

hexanal

131437-07-5

3,3-difluoro-1-nonen-4-ol

Conditions
ConditionsYield
With indium In water for 3h;100%
With zinc In tetrahydrofuran47%
With indium In N,N-dimethyl-formamide
420-90-6

3-bromo-3,3-difluropropene

104-55-2

3-phenyl-propenal

88257-89-0

4,4-difluoro-1-phenylhexa-1,5-dien-3-ol

Conditions
ConditionsYield
With indium In water at 20℃; for 3h; Addition;100%
With zinc In tetrahydrofuran 1.) 0 deg C to RT, 4.5 h; 2.) RT, overnight;74%
124-19-6

nonan-1-al

420-90-6

3-bromo-3,3-difluropropene

3,3-difluorododec-1-en-4-ol

Conditions
ConditionsYield
With indium In water at 20℃; for 3h; Addition;100%
With indium In N,N-dimethyl-formamide for 3h; Ambient temperature;93%
420-90-6

3-bromo-3,3-difluropropene

105-07-7

4-cyanobenzaldehyde

4-(2,2-difluoro-1-hydroxybut-3-en-1-yl)benzonitrile

Conditions
ConditionsYield
With indium In N,N-dimethyl-formamide at 20℃;100%
50-00-0

formaldehyd

420-90-6

3-bromo-3,3-difluropropene

2,2-difluoro-3-butene-1-ol

Conditions
ConditionsYield
With indium; lithium iodide In N,N-dimethyl-formamide100%
With lithium iodide In N,N-dimethyl-formamide at 22℃; for 12h;
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Chemistry

Molecular structure of 3-Bromo-3,3-difluoropropene (CAS NO.420-90-6) is:

Product Name: 3-Bromo-3,3-difluoropropene
CAS Registry Number: 420-90-6
Empirical Formula: C3H3BrF2
Molecular Weight: 156.9567
Melting Point: 53-54 °C
Storage temp.: Keep Cold
Surface Tension: 20.4 dyne/cm
Density: 1.613 g/cm3 
Enthalpy of Vaporization: 27.44 kJ/mol
Boiling Point: 42 °C at 760 mmHg
Vapour Pressure: 411 mmHg at 25°C

Safety Profile

Safty information about 3-Bromo-3,3-difluoropropene (CAS NO.420-90-6) is:
Hazard Codes: IrritantXi
Risk Statements: 36/37/38 
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 26-36/37/39 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
Hazard Note: Irritant
HazardClass: IRRITANT, KEEP COLD

Specification

 3-Bromo-3,3-difluoropropene , its cas register number is 420-90-6. It also can be called 3-Bromo-3,3-difluoro-1-propene ; 1,1-Difluoroallyl bromide ; Propene,3-bromo-3,3-difluoro- (6CI,7CI,8CI) .