Products Categories
CAS No.: | 4245-37-8 |
---|---|
Name: | VINYL METHACRYLATE |
Molecular Structure: | |
Formula: | C6H8O2 |
Molecular Weight: | 112.128 |
Synonyms: | ethenyl 2-methylprop-2-enoate;Vinyl Methacrylate;2-Propenoic acid, 2-methyl-, ethenyl ester;Methacrylic Acid Vinyl Ester; |
Density: | 0.926g/cm3 |
Boiling Point: | 123.3°Cat760mmHg |
Flash Point: | 28.8°C |
Hazard Symbols: | 1743336 |
Risk Codes: | R11; R36/37/38 |
Safety: | 1743336 |
PSA: | 26.30000 |
LogP: | 1.24920 |
Conditions | Yield |
---|---|
With sulfuric acid; mercury(II) diacetate | |
poly(methacrylic acid)
acetic anhydride
acetylene
A
vinyl methacrylate
B
1,1-bis-methacryloyloxy-ethane
Conditions | Yield |
---|---|
With mercury(II) orthophosphate |
Conditions | Yield |
---|---|
With Cp*2Sm(THF)2 In toluene Ambient temperature; further reagent: SmI2; | 99% |
Conditions | Yield |
---|---|
pseudomonas fluorescens lipase at 60℃; for 72h; Polymerization; acylation; | 98% |
4-Hydroxy-dihydro-furan-2-on
vinyl methacrylate
β-methacryloyloxy-γ-butyrolactone
Conditions | Yield |
---|---|
With Novozym 435 In (E)-2-methyl-2-butenoate at 50℃; for 24h; Conversion of starting material; | 98% |
With Lipase P In tert-butyl alcohol at 30℃; for 24h; Conversion of starting material; | 84.53% |
With Lipase PL In tert-butyl alcohol at 30℃; for 24h; Conversion of starting material; | 61.32% |
vinyl methacrylate
bis(pinacol)diborane
vinyl 2-methyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)propanoate
Conditions | Yield |
---|---|
Stage #1: bis(pinacol)diborane With copper(II) carbonate; triphenylphosphine In water at 20℃; for 0.5h; Inert atmosphere; Stage #2: vinyl methacrylate In water at 30℃; for 20h; Inert atmosphere; | 94% |
Stage #1: bis(pinacol)diborane With copper carbonate hydroxide; triphenylphosphine In water at 20℃; for 0.5h; Inert atmosphere; Stage #2: vinyl methacrylate In water at 30℃; for 20h; Inert atmosphere; | 94% |
Stage #1: bis(pinacol)diborane With copper(II) carbonate; triphenylphosphine In water at 20℃; for 0.833333h; Inert atmosphere; Stage #2: vinyl methacrylate In water at 30℃; for 20h; | 94% |
Stage #1: bis(pinacol)diborane With copper(II) carbonate; triphenylphosphine In water at 20℃; for 0.5h; Inert atmosphere; Stage #2: vinyl methacrylate In water at 30℃; for 20h; Inert atmosphere; | 94% |
Conditions | Yield |
---|---|
With Rhizomucor miehei lipase Enzymatic reaction; regioselective reaction; | 93% |
With Lipozyme RM IM In tert-butyl methyl ether at 20℃; for 60h; Enzymatic reaction; | 87.3% |
Conditions | Yield |
---|---|
pseudomonas fluorescens lipase at 60℃; for 72h; Polymerization; acylation; | 92% |
1-Bromo-11-hydroxyundecane
vinyl methacrylate
2-methylacrylic acid 11-bromoundecyl ester
Conditions | Yield |
---|---|
1,3-dicyclohexyl-imidazol-2-ylidene In tetrahydrofuran at 20℃; for 0.25h; | 90% |
vinyl methacrylate
Conditions | Yield |
---|---|
With Novozym 435 In tetrahydrofuran at 50℃; for 80h; | 90% |