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4497-92-1

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Basic Information
CAS No.: 4497-92-1
Name: (+)-2-CARENE
Article Data: 20
Molecular Structure:
Molecular Structure of 4497-92-1 ((+)-2-CARENE)
Formula: C10H16
Molecular Weight: 136.237
Synonyms: 2-Carene,(1S,6R)-(+)- (8CI); Bicyclo[4.1.0]hept-2-ene, 3,7,7-trimethyl-, (1S)-;(+)-2-Carene; Pinonene
Density: 0.879g/cm3
Melting Point: 25°C (estimate)
Boiling Point: 167.5°Cat760mmHg
Flash Point: 38.3°C
Hazard Symbols:
Risk Codes: 10
Safety:
Hazard Codes Xi
Risk Statements 10
Safety Statements 16-26-36/37/39-45
RIDADR UN 3295 3/PG 3
WGK Germany 3
PSA: 0.00000
LogP: 2.99870
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Synthetic route

C30H45BO

A

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(R)-1-Phenylbut-3-en-1-ol

B

4497-92-1

2-carene

Conditions
ConditionsYield
With boron trifluoride diethyl etherate; isobutyraldehyde at 65℃; for 48h;A 76%
B 83%
498-15-7

(+)-Δ3-carene

4497-92-1

2-carene

Conditions
ConditionsYield
With potassium tert-butylate In dimethyl sulfoxide at 100℃; for 4h;15%
With titanic acid at 140℃;
With sulfuric acid at 110℃;
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((1S,6R)-7,7-Dimethyl-bicyclo[4.1.0]hept-2-en-3-yl)-methanol

4497-92-1

2-carene

Conditions
ConditionsYield
(i) Py*SO3, THF, (ii) LiAlH4; Multistep reaction;
15372-79-9, 15372-81-3, 18767-55-0

(-)-trans-Caran-2-on-tosylhydrazon

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2-carene

Conditions
ConditionsYield
With methyllithium In diethyl ether

(+)(1R:4R:6S)-Caran-trans-4-ol-benzoat

A

498-15-7

(+)-Δ3-carene

B

4497-92-1

2-carene

Conditions
ConditionsYield
at 320℃;

(+)(1R:4R:6S)-Caran-trans-4-ol-acetat

4497-92-1

2-carene

Conditions
ConditionsYield
at 180℃;
498-15-7

(+)-Δ3-carene

A

99-87-6

4-methylisopropylbenzene

B

4497-92-1

2-carene

C

97763-43-4

(-)-(1S)-3,8,8-trimethylbicyclo<4.1.1.>oct-3-ene-7-one

Conditions
ConditionsYield
With iron pentacarbonyl In dibutyl ether for 72h; Heating; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
With iron pentacarbonyl In dibutyl ether for 72h; Heating; Yield given. Yields of byproduct given;
...Expand
82470-87-9

α-terpinylphenylsulphide

A

61585-35-1

p-menth-1-ene

B

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(+)-Δ3-carene

C

99-87-6

4-methylisopropylbenzene

D

4497-92-1

2-carene

Conditions
ConditionsYield
With lithium diethylamide In N,N,N,N,N,N-hexamethylphosphoric triamide; diethyl ether at 20℃; for 3h; Product distribution; Various reagents/solvents was used for the cyclisation (n-BuLi/TMEDA, K-t-butoxide/DMSO).;
...Expand
498-15-7

(+)-Δ3-carene

A

99-87-6

4-methylisopropylbenzene

B

4497-92-1

2-carene

C

97763-43-4

(-)-(1S)-3,8,8-trimethylbicyclo<4.1.1.>oct-3-ene-7-one

D

iron-carbonyl-complexes

iron-carbonyl-complexes

Conditions
ConditionsYield
With iron pentacarbonyl 1) 150 deg C, 18 h, 2) 160 deg C, 24 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
...Expand
4017-79-2

3,7,7-trimethylbicyclo[4.1.0]heptan-3-ol

4497-92-1

2-carene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: PhNMe2 / acetic anhydride
2: 180 °C
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    China (Mainland)  |  Contact Details

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     China (Mainland)  |  Contact Details

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    China (Mainland)  |  Contact Details

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    China (Mainland)  |  Contact Details

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     China (Mainland)  |  Contact Details

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     China (Mainland)  |  Contact Details

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