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CAS No.: | 4538-50-5 |
---|---|
Name: | Glycidic acid methyl ester |
Article Data: | 37 |
Molecular Structure: | |
Formula: | C4H6O3 |
Molecular Weight: | 102.09 |
Synonyms: | Racemic methyl glycidate;Glycidic acid methyl ester;Methyl 2-oxiranecarboxylate;Methyl oxirane-2-carboxylate;Oxirane-2-carboxylic acid, methyl ester; |
Density: | 1.246g/cm3 |
Boiling Point: | 97.4 °C at 760 mmHg |
Flash Point: | 26.2 °C |
PSA: | 38.83000 |
LogP: | -0.44180 |
acrylic acid methyl ester
methyl glycidate
Conditions | Yield |
---|---|
With Mn-trimethyltriazacyclononane; dihydrogen peroxide; sodium L-ascorbate In water; acetonitrile at 0℃; Epoxidation; | 97% |
With sodium hypochlorite; tetrabutyl-ammonium chloride; sodium hydrogencarbonate In water at 40℃; for 1h; Reagent/catalyst; Green chemistry; | 82% |
With sodium hypochlorite In water at 0 - 70℃; Product distribution / selectivity; | 80% |
Conditions | Yield |
---|---|
With sodium hypochlorite; carbon dioxide; sodium carbonate In water at 10℃; for 1h; | 50% |
Conditions | Yield |
---|---|
With trimethylbenzylammonium bromide at 70℃; under 33753.4 - 37503.8 Torr; for 15h; Product distribution / selectivity; | 100% |
With tert-butyl methyl ether; tetrabutylammomium bromide at 40℃; under 15001.5 Torr; for 96h; Product distribution / selectivity; | 94% |
With tetrabutylammomium bromide In tert-butyl methyl ether at 40℃; under 15001.5 Torr; for 96h; Reagent/catalyst; Sealed tube; | 94% |
methyl glycidate
4-methoxy-benzylamine
2-hydroxy-N-(4-methoxybenzyl)-3-(4-methoxybenzylamino)propionamide
Conditions | Yield |
---|---|
at 60℃; for 6h; Inert atmosphere; | 99% |
methyl glycidate
phenol
(R)-2-Hydroxy-3-phenoxy-propionic acid methyl ester
Conditions | Yield |
---|---|
With (R,R)-(salen)Co(H2O); 3 A molecular sieve In various solvent(s) at -20℃; | 98% |
chiral Co-complex |
Conditions | Yield |
---|---|
In isopropyl alcohol at 20℃; for 3h; | 95% |
methyl glycidate
o-bromobenzyl alcohol
(2R)-3-(2-bromobenzyloxy)-2-hydroxypropionic acid methyl ester
Conditions | Yield |
---|---|
In acetonitrile at 4℃; for 24h; enantioselective reaction; | 94% |
Conditions | Yield |
---|---|
With 1,1,1,3',3',3'-hexafluoro-propanol; palladium diacetate; acetic acid at 25℃; for 24h; Inert atmosphere; | 92% |
Conditions | Yield |
---|---|
In toluene at 0℃; | 90% |
methyl glycidate
acrylic acid methyl ester
Conditions | Yield |
---|---|
With sodium iodide; tin(ll) chloride In ethanol for 0.05h; Reflux; Green chemistry; | 85% |
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Molecular Structure of Oxiranecarboxylic acid, methyl ester (CAS NO.4538-50-5):
IUPAC Name: methyl oxirane-2-carboxylate
Empirical Formula: C4H6O3
Molecular Weight: 102.0886
CAS: 4538-50-5
H bond acceptors: 3
H bond donors: 0
Freely Rotating Bonds: 2
Polar Surface Area: 38.83Å2
Index of Refraction: 1.444
Molar Refractivity: 21.77 cm3
Molar Volume: 81.8 cm3
Surface Tension: 38.7 dyne/cm
Density: 1.246 g/cm3
Flash Point: 26.2 °C
Enthalpy of Vaporization: 33.69 kJ/mol
Boiling Point: 97.4 °C at 760 mmHg
Vapour Pressure: 41.7 mmHg at 25°C
InChI
InChI=1/C4H6O3/c1-6-4(5)3-2-7-3/h3H,2H2,1H3
Smiles
O1[C@@H](C1)C(=O)OC
Oxiranecarboxylic acid, methyl ester , with CAS number of 4538-50-5, can be called Racemic methyl glycidate ; Glycidic acid methyl ester ; Methyl 2-oxiranecarboxylate ; Methyl oxirane-2-carboxylate ; Oxirane-2-carboxylic acid, methyl ester .