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4551-15-9

Basic Information
CAS No.: 4551-15-9
Name: PHENYLTHIOTRIMETHYLSILANE
Article Data: 39
Molecular Structure:
Molecular Structure of 4551-15-9 (PHENYLTHIOTRIMETHYLSILANE)
Formula: C9H14SSi
Molecular Weight: 182.362
Synonyms: Silane,trimethyl(phenylthio)- (7CI,8CI,9CI);Phenyl trimethylsilyl sulfide;Phenylthiotrimethylsilane;Trimethyl(phenylthio)silane;Trimethyl(phenylthiolato)silicon;Trimethylsilyl phenyl sulfide;
EINECS: 224-916-7
Density: 0.96 g/cm3
Boiling Point: 200.3 °C at 760 mmHg
Flash Point: 87.4 °C
Solubility: Hydrolyzes in water.
Appearance: clear colorless to light yellow liquid
Hazard Symbols: HarmfulXn
Risk Codes: 10-20-38
Safety: 23-28
PSA: 25.30000
LogP: 3.61360
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Specification

The Benzene,[(trimethylsilyl)thio]-, with the CAS registry number 4551-15-9, is also known as Phenylthiotrimethylsilane. It belongs to the product categories of Monoalkoxysilanes; Protection & Derivatization Reagents (for Synthesis); Si (Classes of Silicon Compounds); Si-O Compounds; Synthetic Organic Chemistry. Its EINECS number is 224-916-7. This chemical's molecular formula is C9H14SSi and molecular weight is 182.36. What's more, its systematic name is trimethyl(phenylsulfanyl)silane. It is stable at common pressure and temperature, and it should be sealed and stored in a cool and dry place. Moreover, it should be protected from light.

Physical properties of Benzene,[(trimethylsilyl)thio]- are: (1)ACD/LogP: 3.95; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 3.95; (4)ACD/LogD (pH 7.4): 3.95; (5)ACD/BCF (pH 5.5): 593.04; (6)ACD/BCF (pH 7.4): 593.04; (7)ACD/KOC (pH 5.5): 3361.81; (8)ACD/KOC (pH 7.4): 3361.81; (9)#H bond acceptors: 0; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 2; (12)Polar Surface Area: 25.3 Å2; (13)Index of Refraction: 1.519; (14)Molar Refractivity: 57.4 cm3; (15)Molar Volume: 189.1 cm3; (16)Polarizability: 22.75×10-24cm3; (17)Surface Tension: 28.3 dyne/cm; (18)Density: 0.96 g/cm3; (19)Flash Point: 87.4 °C; (20)Enthalpy of Vaporization: 41.87 kJ/mol; (21)Boiling Point: 200.3 °C at 760 mmHg; (22)Vapour Pressure: 0.462 mmHg at 25°C.

Preparation of Benzene,[(trimethylsilyl)thio]-: this chemical can be prepared by benzenethiol and chloro-trimethyl-silane. This reaction will need reagent triethylamine and solvent diethyl ether with the reaction time of 12 hours. The yield is about 85%.

Benzene,[(trimethylsilyl)thio]- can be prepared by benzenethiol and chloro-trimethyl-silane

Uses of Benzene,[(trimethylsilyl)thio]-: it can be used to produce 1-phenyl-1,2-bis-phenylsulfanyl-ethane at the temperature of 40 °C. It will need reagent ZnI2 and solvent 1,2-dichloro-ethane. The yield is about 85%.

Benzene,[(trimethylsilyl)thio]- can be used to produce 1-phenyl-1,2-bis-phenylsulfanyl-ethane at the temperature of 40 °C

When you are using this chemical, please be cautious about it as the following:
This chemical is harmful by inhalation. It is flammable. It is irritating to skin. You should not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer). After contact with skin, you must wash immediately with plenty of ... (to be specified by the manufacturer).

You can still convert the following datas into molecular structure:
(1)SMILES: S(c1ccccc1)[Si](C)(C)C
(2)InChI: InChI=1S/C9H14SSi/c1-11(2,3)10-9-7-5-4-6-8-9/h4-8H,1-3H3
(3)InChIKey: VJMQFIRIMMSSRW-UHFFFAOYSA-N