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CAS No.: | 456-42-8 |
---|---|
Name: | 3-Fluorobenzyl chloride |
Article Data: | 27 |
Molecular Structure: | |
Formula: | C7H6ClF |
Molecular Weight: | 144.576 |
Synonyms: | a-Chloro-m-fluorotoluene;Toluene,a-chloro-m-fluoro- (6CI,7CI,8CI);1-(Chloromethyl)-3-fluorobenzene;3-Fluorophenylmethylchloride;NSC 60720;m-Fluorobenzyl chloride;a-Chloro-3-fluorotoluene; |
EINECS: | 207-264-8 |
Density: | 1.191 g/cm3 |
Melting Point: | 34.5-36 °C |
Boiling Point: | 173.3 °C at 760 mmHg |
Flash Point: | 58.9 °C |
Solubility: | 40 g/L (20 °C) in water |
Appearance: | Colorless to light yellow liquid |
Hazard Symbols: | C |
Risk Codes: | 34-37 |
Safety: | 26-36/37/39-45 |
PSA: | 0.00000 |
LogP: | 2.56450 |
Conditions | Yield |
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With methanol; tetrachloromethane; iron(II) chloride tetrahydrate; formamide at 180℃; for 6h; Reagent/catalyst; Inert atmosphere; Sealed tube; Autoclave; chemoselective reaction; | 35% |
at 147℃; Irradiation.Einleiten von Chlor; | |
at 147℃; Einleiten von Chlor; |
Conditions | Yield |
---|---|
Chlorierung; |
Conditions | Yield |
---|---|
With pyridine; thionyl chloride |
1-fluoro-3-(iodomethyl)benzene
m-fluorobenzyl chloride
Conditions | Yield |
---|---|
With pyridine; tributyltin chloride at 50℃; Thermodynamic data; Equilibrium constant; Δ G; | 28 % Spectr. |
m-fluorobenzyl ion
m-fluorobenzyl chloride
Conditions | Yield |
---|---|
With tertiary butyl chloride In gaseous matrix at 600℃; chloride affinity; |
Conditions | Yield |
---|---|
With pyridine; tributyltin chloride at 50℃; Thermodynamic data; Equilibrium constant; Δ G; | 65 % Spectr. |
Conditions | Yield |
---|---|
With pyridine; tributyltin chloride at 50℃; Thermodynamic data; Equilibrium constant; Δ G; | 65 % Spectr. |
1-(1-chloro-2,2,2-trifluoroethyl)-4-chlorobenzene
m-fluorobenzyl ion
A
C8H5ClF3(1+)
B
m-fluorobenzyl chloride
Conditions | Yield |
---|---|
at 69.85℃; Thermodynamic data; chloride-transfer; |
1-(1-Chloro-2,2,2-trifluoro-ethyl)-3-methyl-benzene
m-fluorobenzyl ion
A
C9H8F3(1+)
B
m-fluorobenzyl chloride
Conditions | Yield |
---|---|
at 69.85℃; Thermodynamic data; chloride-transfer; |
1-(1-Chloro-2,2,2-trifluoro-ethyl)-4-fluoro-benzene
m-fluorobenzyl ion
A
C8H5F4(1+)
B
m-fluorobenzyl chloride
Conditions | Yield |
---|---|
at 69.85℃; Thermodynamic data; chloride-transfer; |
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