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CAS No.: | 4698-11-7 |
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Name: | 10-Methoxyiminostilbene |
Article Data: | 19 |
Molecular Structure: | |
Formula: | C15H13NO |
Molecular Weight: | 223.274 |
Synonyms: | 10-Oxo-10,11-dihydro-5H-dibenzo[b,f]azepine-5-carboxamide;10-Methoxy-5H-dibenz(b,f)azepine; |
EINECS: | 225-172-6 |
Density: | 1.19 g/cm3 |
Melting Point: | 122-128 °C |
Boiling Point: | 410.8 °C at 760 mmHg |
Flash Point: | 162.5 °C |
Appearance: | Yellowish foam |
PSA: | 21.26000 |
LogP: | 4.02610 |
10-methoxy-5H-dibenz[b,f]azepine-5-carboxylic acid methyl ester
10-methoxy-5H-dibenzo[b,f]azepine
Conditions | Yield |
---|---|
With sodium hydroxide In various solvent(s) at 100℃; for 4h; | 98% |
With sodium hydroxide In water | 98% |
With sodium hydroxide In methanol; water at 105 - 110℃; for 2.5h; | 97% |
10-methoxy-dibenzo[b,f]azepine-5-carboxylic acid phenyl ester
10-methoxy-5H-dibenzo[b,f]azepine
Conditions | Yield |
---|---|
With sodium hydroxide In various solvent(s) at 100℃; for 4h; | 96% |
5-benzyl-10-methoxyiminostilbene
10-methoxy-5H-dibenzo[b,f]azepine
Conditions | Yield |
---|---|
With 5%-palladium/activated carbon; hydrogen at 35 - 40℃; under 1500.15 - 2250.23 Torr; for 5h; Autoclave; | 93.5% |
5-acetyl-10-methoxy-5H-dibenzazepine
10-methoxy-5H-dibenzo[b,f]azepine
Conditions | Yield |
---|---|
With potassium hydroxide In ethylene glycol for 5h; Heating; | 80% |
With triethyl borane; sodium hydroxide In tert-butyl methyl ether at 80℃; for 6h; Inert atmosphere; Sealed tube; | 67% |
Stage #1: 5-acetyl-10-methoxy-5H-dibenzazepine With Triethoxysilane; sodium triethylborohydride In tert-butyl methyl ether at 80℃; for 6h; Stage #2: With hydrogenchloride In tert-butyl methyl ether; water at 20℃; for 1h; chemoselective reaction; | 59% |
10-methoxy-5H-dibenzo[b,f]azepine
Conditions | Yield |
---|---|
With potassium tert-butylate In dimethyl sulfoxide |
10-methoxy-5H-dibenzo[b,f]azepine
Conditions | Yield |
---|---|
Stage #1: 5-formyl-10-bromo-11-methoxy-10,11-dihydro-5H-dibenzo[b,f]azepine With 1,8-diazabicyclo[5.4.0]undec-7-ene In toluene for 0.5h; Heating / reflux; Stage #2: With Deloxan ASP I/7; potassium hydroxide In toluene Product distribution / selectivity; Heating / reflux; |
(2-phenylamino-phenyl)-acetic acid methyl ester
10-methoxy-5H-dibenzo[b,f]azepine
Conditions | Yield |
---|---|
Multi-step reaction with 5 steps 1.1: pyridine / toluene / 24 h / 50 °C 1.2: pyridine / 22 h / 100 °C 2.1: 90 percent / aq. NaOH / methanol / 24 h / 25 °C 3.1: 70 percent / polyphosphoric acid / 3 h / 95 °C 4.1: 81 percent / p-TsOH / methanol / 5 h / Heating 5.1: 98 percent / aq. NaOH / various solvent(s) / 4 h / 100 °C View Scheme | |
Multi-step reaction with 6 steps 1: pyridine / toluene / 24 h / 50 °C 2: pyridine / 22 h / 100 °C 3: sodium hydroxide / water; methanol / 24 h / 20 °C 4: polyphosphoric acid / 3 h / 90 - 95 °C 5: water / 0 - 98 °C 6: sodium hydroxide / water; methanol / 2.5 h / 105 - 110 °C View Scheme |
10,11-dihydro-10-oxo-5H-dibenz[b,f]azepine-5-carboxylic acid methyl ester
10-methoxy-5H-dibenzo[b,f]azepine
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 81 percent / p-TsOH / methanol / 5 h / Heating 2: 98 percent / aq. NaOH / various solvent(s) / 4 h / 100 °C View Scheme | |
Multi-step reaction with 2 steps 1: water / 0 - 98 °C 2: sodium hydroxide / water; methanol / 2.5 h / 105 - 110 °C View Scheme |
[2-(methoxycarbonyl-phenyl-amino)-phenyl]-acetic acid methyl ester
10-methoxy-5H-dibenzo[b,f]azepine
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1: 90 percent / aq. NaOH / methanol / 24 h / 25 °C 2: 70 percent / polyphosphoric acid / 3 h / 95 °C 3: 81 percent / p-TsOH / methanol / 5 h / Heating 4: 98 percent / aq. NaOH / various solvent(s) / 4 h / 100 °C View Scheme | |
Multi-step reaction with 4 steps 1: sodium hydroxide / water; methanol / 24 h / 20 °C 2: polyphosphoric acid / 3 h / 90 - 95 °C 3: water / 0 - 98 °C 4: sodium hydroxide / water; methanol / 2.5 h / 105 - 110 °C View Scheme |
2-[(methoxycarbonyl)phenylamino]benzeneacetic acid
10-methoxy-5H-dibenzo[b,f]azepine
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: 70 percent / polyphosphoric acid / 3 h / 95 °C 2: 81 percent / p-TsOH / methanol / 5 h / Heating 3: 98 percent / aq. NaOH / various solvent(s) / 4 h / 100 °C View Scheme | |
Multi-step reaction with 3 steps 1: polyphosphoric acid / 3 h / 90 - 95 °C 2: water / 0 - 98 °C 3: sodium hydroxide / water; methanol / 2.5 h / 105 - 110 °C View Scheme |
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Molecular Structure of 10-Methoxy-5H-dibenz(b,f)azepine (CAS NO.4698-11-7):
Molecular Formula: C15H13NO
Molecular Weight: 223.2698
IUPAC Name: 6-Methoxy-11H-benzo[b][1]benzazepine
Synonyms of 10-Methoxy-5H-dibenz(b,f)azepine (CAS NO.4698-11-7): EINECS 225-172-6 ; 10-Methoxyiminostilbene ; 10-Methoxy-2,2'-iminostilbene
CAS NO: 4698-11-7
Product Categories: Stilbenes (substituted) ; Aromatics Compounds ; Aromatics ; Heterocycles
Melting point: 122-128°C
Index of Refraction: 1.651
Molar Refractivity: 68.37 cm3
Molar Volume: 187 cm3
Surface Tension: 49.8 dyne/cm
Density: 1.19 g/cm3
Flash Point: 162.5 °C
Enthalpy of Vaporization: 66.32 kJ/mol
Boiling Point: 410.8 °C at 760 mmHg
Vapour Pressure of 10-Methoxy-5H-dibenz(b,f)azepine (CAS NO.4698-11-7): 5.86E-07 mmHg at 25°C
10-Methoxy-5H-dibenz(b,f)azepine (CAS NO.4698-11-7) is used as Drug Oxcarbazepine.