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470-08-6

Basic Information
CAS No.: 470-08-6
Name: (1S,2R,4R)-1,3,3-Trimethyl-bicyclo[2.2.1]heptan-2-ol
Article Data: 40
Molecular Structure:
Molecular Structure of 470-08-6 ((1S,2R,4R)-1,3,3-Trimethyl-bicyclo[2.2.1]heptan-2-ol)
Formula: C10H18 O
Molecular Weight: 154.252
Synonyms: 2-Norbornanol,1,3,3-trimethyl-, (1S,2R,4R)-(-)- (8CI); Bicyclo[2.2.1]heptan-2-ol,1,3,3-trimethyl-, (1S-exo)-; (-)-(1S,2R,4R)-b-Fenchol; (-)-b-Fenchol; (-)-b-Fenchyl alcohol; b-Fenchol, (-)-
Density: 0.992g/cm3
Boiling Point: 202.9°Cat760mmHg
Flash Point: 73.9°C
PSA: 20.23000
LogP: 2.19350
Synthetic route
4695-62-9

fenchone

555-31-7

aluminum isopropoxide

A

512-13-0

(-)-α-fenchol

B

470-08-6

(-)-β-fenchol

Conditions
ConditionsYield
With isopropyl alcohol
4695-62-9

fenchone

A

512-13-0

(-)-α-fenchol

B

470-08-6

(-)-β-fenchol

Conditions
ConditionsYield
With copper chromite; ethanol at 110℃; under 73550.8 Torr; Hydrogenation;
With nickel at 110℃; Hydrogenation;
With methanol; nickel Hydrogenation;
With aluminum isopropoxide In isopropyl alcohol for 420h; Heating;A n/a
B 1.52 g
124118-33-8

oxalic acid bis-((1S)-1,3,3-trimethyl-norbornan-2-yl ester)

A

512-13-0

(-)-α-fenchol

B

470-08-6

(-)-β-fenchol

Conditions
ConditionsYield
Hydrolysis;
4695-62-9

fenchone

555-31-7

aluminum isopropoxide

67-63-0

isopropyl alcohol

470-08-6

(-)-β-fenchol

486-25-9

9-fluorenone

1689-64-1

9-Fluorenol

512-13-0

(-)-α-fenchol

75-65-0

tert-butyl alcohol

sodium tert.-butylate

sodium tert.-butylate

470-08-6

(-)-β-fenchol

Conditions
ConditionsYield
at 160 - 180℃; Epimerisierung;
4695-62-9

fenchone

Raney nickel

Raney nickel

A

512-13-0

(-)-α-fenchol

B

470-08-6

(-)-β-fenchol

Conditions
ConditionsYield
at 110℃; unter Druck.Hydrogenation;
67-56-1

methanol

4695-62-9

fenchone

Raney nickel

Raney nickel

A

512-13-0

(-)-α-fenchol

B

470-08-6

(-)-β-fenchol

Conditions
ConditionsYield
at 110℃; unter Druck.Hydrogenation;
64-17-5

ethanol

4695-62-9

fenchone

sodium

sodium

A

512-13-0

(-)-α-fenchol

B

470-08-6

(-)-β-fenchol

4695-62-9

fenchone

sodium

sodium

LiAlH4

LiAlH4

A

512-13-0

(-)-α-fenchol

B

470-08-6

(-)-β-fenchol

4695-62-9

fenchone

A

470-08-6

(-)-β-fenchol

B

l-α-fenchol

l-α-fenchol

Conditions
ConditionsYield
With ethanol; sodium
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