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CAS No.: | 485-91-6 |
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Name: | ALLOCRYPTOPINE |
Article Data: | 10 |
Molecular Structure: | |
Formula: | C21H23 N O5 |
Molecular Weight: | 369.417 |
Synonyms: | a-Fagarine (6CI,7CI);Allocryptopine; Thalictrimine; Thalictrimine (C21 alkaloid); a-Allocryptopine; a-allo-Cryptopine; b-Homochelidonine |
Density: | 1.216g/cm3 |
Melting Point: | 160~161℃ |
Boiling Point: | 552.7°Cat760mmHg |
Flash Point: | 288.1°C |
PSA: | 57.23000 |
LogP: | 2.78370 |
dihydroallocryptopine
allocryptopine
Conditions | Yield |
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With sodium acetate; pyridinium chlorochromate In dichloromethane at 20℃; for 2h; | 63% |
With sodium acetate; pyridinium chlorochromate In dichloromethane for 2h; |
Conditions | Yield |
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In water at 24℃; for 144h; incorporation experiment on Macleaya cordata in Murashige and Skoog's medium; | A 0.4% B 12.1% C 1.7% |
(+/-)-cis-N-methyl-7,8,13,13a-tetrahydroberberinium chloride
A
12,13-dihydrochelerythrine
B
allocryptopine
Conditions | Yield |
---|---|
In water at 24℃; for 192h; incorporation experiment on Macleaya cordata in Murashige and Skoog's medium; | A 1.4% B 6.2% |
Conditions | Yield |
---|---|
In diethyl ether |
(14Z)-3,4-dimethoxy-6-methyl-5,6,7,8-tetrahydro-benzo[c][1,3]dioxolo[4',5':4,5]benzo[1,2-g]azecine 6-oxide
allocryptopine
Conditions | Yield |
---|---|
With hydrogenchloride In acetic acid |
9,10,13a-trimethoxy-5,8,13,13a-tetrahydro-6H-[1,3]dioxolo[4,5-g]isoquino[3,2-a]isoquinoline
methyl iodide
allocryptopine
Conditions | Yield |
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In methanol |
(S)-N-methylcanadine
allocryptopine
Conditions | Yield |
---|---|
With oxygen; NADPH at 30℃; for 0.333333h; tricine buffer, pH 8.5; Yield given; |
14-boranyl-3,4-dimethoxy-6-methyl-5,6,7,8,14,15-hexahydro-benzo[c][1,3]dioxolo[4',5':4,5]benzo[1,2-g]azecine
allocryptopine
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 137 mg / H2O2; NaOH / tetrahydrofuran; H2O / Heating 2: 63 percent / pyridinium chlorochromate; NaOAc; 3A MS / CH2Cl2 / 2 h / 20 °C View Scheme |
(-)-N-methylcanadine iodide
allocryptopine
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1: NaH / dimethylsulfoxide; benzene / 5 h / 20 °C 2: BH3*THF / tetrahydrofuran / 0.5 h / 20 °C 3: 137 mg / H2O2; NaOH / tetrahydrofuran; H2O / Heating 4: 63 percent / pyridinium chlorochromate; NaOAc; 3A MS / CH2Cl2 / 2 h / 20 °C View Scheme |
(+/-)-trans-N-methyl-7,8,13,13a-tetrahydroberberinium iodide
allocryptopine
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1: NaH / dimethylsulfoxide; benzene / 5 h / 20 °C 2: BH3*THF / tetrahydrofuran / 0.5 h / 20 °C 3: 137 mg / H2O2; NaOH / tetrahydrofuran; H2O / Heating 4: 63 percent / pyridinium chlorochromate; NaOAc; 3A MS / CH2Cl2 / 2 h / 20 °C View Scheme |