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497-04-1

Basic Information
CAS No.: 497-04-1
Name: 2-chloropropane-1,3-diol
Article Data: 46
Molecular Structure:
Molecular Structure of 497-04-1 (2-chloropropane-1,3-diol)
Formula: C3H7 Cl O2
Molecular Weight: 110.54
Synonyms: 2-Chloro-1,3-dihydroxypropane;2-Chloro-1,3-propanediol; Glycerol b-chlorohydrin
Density: 1.303g/cm3
Boiling Point: 248.5°Cat760mmHg
Flash Point: 104.1°C
PSA: 40.46000
LogP: -0.42160
Synthetic route
56-81-5

glycerol

A

616-23-9

2,3-Dichloro-1-propanol

B

497-04-1

2-chloro-propane-1,3-diol

C

96-23-1

1,3-Dichloro-2-propanol

D

96-24-2

3-monochloro-1,2-propanediol

Conditions
ConditionsYield
With hydrogenchloride; hexahydro-2H-oxepin-2-one In water at 110℃; under 6448.83 Torr; for 4h; Product distribution / selectivity;A 1.9197%
B 3.7294%
C 93.414%
D 0.5545%
With hydrogenchloride; malonic acid at 100 - 110℃; for 3 - 5h; Kinetics;A ~ 0.5 %Chromat.
B ~ 6 %Chromat.
C 37 %Chromat.
D 54 %Chromat.
With hydrogenchloride; succinic acid at 100℃; for 2.5h; Kinetics;A 0.37 %Chromat.
B 6.84 %Chromat.
C 30.05 %Chromat.
D 60.88 %Chromat.
64-19-7

acetic acid

56-81-5

glycerol

A

616-23-9

2,3-Dichloro-1-propanol

B

497-04-1

2-chloro-propane-1,3-diol

C

96-23-1

1,3-Dichloro-2-propanol

D

24573-30-6

3-chloro-2-hydroxy-1-propyl acetate

E

3674-10-0

1,3-dichloro-2-acetoxypropane

F

96-24-2

3-monochloro-1,2-propanediol

Conditions
ConditionsYield
With hydrogenchloride at 100℃; for 23.75h; Product distribution / selectivity;A 1.11%
B 4.03%
C 57.78%
D 0.42%
E 0.34%
F 9.98%
64-19-7

acetic acid

56-81-5

glycerol

A

616-23-9

2,3-Dichloro-1-propanol

B

497-04-1

2-chloro-propane-1,3-diol

C

96-23-1

1,3-Dichloro-2-propanol

D

589-96-8

(+/-)-1-Acetoxy-2,3-dichloropropane

E

3674-10-0

1,3-dichloro-2-acetoxypropane

Conditions
ConditionsYield
With hydrogenchloride at 90 - 123℃; under 5414.51 - 5724.8 Torr; for 1.5 - 2h; Product distribution / selectivity;A 1%
B 1.88%
C 53.74%
D 0.43%
E 4.75%
51483-40-0

1,3-dibromo-2-chloro-propane

563-63-3

silver(I) acetate

A

497-04-1

2-chloro-propane-1,3-diol

B

96-24-2

3-monochloro-1,2-propanediol

Conditions
ConditionsYield
at 170℃; und nachfolgendes Verseifen mit ueberschuessigem Alkali bei 100grad;
556-52-5

oxiranyl-methanol

497-04-1

2-chloro-propane-1,3-diol

Conditions
ConditionsYield
With hydrogenchloride
556-52-5

oxiranyl-methanol

A

497-04-1

2-chloro-propane-1,3-diol

B

96-24-2

3-monochloro-1,2-propanediol

Conditions
ConditionsYield
With hydrogenchloride
107-18-6

allyl alcohol

A

616-23-9

2,3-Dichloro-1-propanol

B

497-04-1

2-chloro-propane-1,3-diol

Conditions
ConditionsYield
With water; chlorine im diffusen Tageslicht;
With air; water; chlorine im diffusen Tagenlicht;
107-18-6

allyl alcohol

497-04-1

2-chloro-propane-1,3-diol

Conditions
ConditionsYield
With hypochloric acid
107-18-6

allyl alcohol

A

497-04-1

2-chloro-propane-1,3-diol

B

96-24-2

3-monochloro-1,2-propanediol

Conditions
ConditionsYield
With hypochloric acid
56-81-5

glycerol

497-04-1

2-chloro-propane-1,3-diol

Conditions
ConditionsYield
With hydrogenchloride
With hydrogenchloride
With disulfur dichloride
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    2-Chloro-1,3-propanediol CAS NO.497-04-1

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