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CAS No.: | 4984-22-9 |
---|---|
Name: | (R)-(-)-1-METHOXY-2-PROPANOL |
Article Data: | 14 |
Molecular Structure: | |
Formula: | C4H10O2 |
Molecular Weight: | 90.1222 |
Synonyms: | 2-Propanol,1-methoxy-, (R)-;2-Propanol, 1-methoxy-, D-(-)- (8CI);(-)-1-Methoxy-2-propanol;(R)-(-)-1-Methoxy-2-propanol; |
EINECS: | 628-460-3 |
Density: | 0.912 g/cm3 |
Melting Point: | -97 °C |
Boiling Point: | 118.5 °C at 760 mmHg |
Flash Point: | 33.9 °C |
Appearance: | Colorless to light yellow liquid |
Hazard Symbols: | F, Xn |
Risk Codes: | 10-15 |
Safety: | 24-43-7/8 |
Transport Information: | UN 3092 3/PG 3 |
PSA: | 29.46000 |
LogP: | 0.01360 |
Conditions | Yield |
---|---|
In methanol for 13.5h; Reflux; | 86.51% |
Conditions | Yield |
---|---|
With sodium hydroxide at 35 - 65℃; for 16h; | 86.51% |
methanol
(R)-propylene oxide
A
(R)-1-methoxy-2-propanol
B
2-methoxypropanol
Conditions | Yield |
---|---|
With sodium hydroxide for 5h; Reflux; | A 79% B n/a |
methanol
(S)-Propylene oxide
A
(R)-1-methoxy-2-propanol
B
(2R)-2-methoxypropan-1-ol
C
(R)-(-)-1-chloro-2-propanol
Conditions | Yield |
---|---|
With Cu(L-Asp)(1,2-bis(4-pyridyl)ethylene)0.5(H2O)0.5(MeOH)0.5 at 25℃; | A 52% B 42% C 6% |
Conditions | Yield |
---|---|
With methanol |
A
(S)-1-Methoxy-propan-2-ol
B
(R)-1-methoxy-2-propanol
Conditions | Yield |
---|---|
With hydrogenchloride In tetrahydrofuran for 24h; Ambient temperature; Yield given. Yields of byproduct given. Title compound not separated from byproducts; |
methanol
(R)-propylene oxide
A
(S)-1-Methoxy-propan-2-ol
B
(R)-1-methoxy-2-propanol
C
(S)-(+)-2-methoxypropanol
D
(2R)-2-methoxypropan-1-ol
E
(S)-(+)-1,2-dimethoxypropane
F
(R)-(-)-1,2-dimethoxypropane
Conditions | Yield |
---|---|
With Methyl fluoride at 25℃; under 720 Torr; Product distribution; Mechanism; Irradiation; also in the presence of H2O or CH4; |
methanol
(S)-Propylene oxide
A
(S)-1-Methoxy-propan-2-ol
B
(R)-1-methoxy-2-propanol
C
(S)-(+)-2-methoxypropanol
D
(2R)-2-methoxypropan-1-ol
E
(S)-(+)-1,2-dimethoxypropane
F
(R)-(-)-1,2-dimethoxypropane
Conditions | Yield |
---|---|
With Methyl fluoride at 25℃; under 720 Torr; Product distribution; Mechanism; Irradiation; also in the presence of H2O or CH4; |
Conditions | Yield |
---|---|
With potassium isopropoxide; isopropyl alcohol; dichloro(benzene)ruthenium(II) dimer; (1S,2R)-N-benzylnorephedrine at 20℃; for 0.33h; Title compound not separated from byproducts; | |
With dichloro(benzene)ruthenium(II) dimer; 2-benzylamino-1-phenyl-propan-1-ol; potassium isopropoxide In isopropyl alcohol at 20℃; for 0.33h; Title compound not separated from byproducts; |
Conditions | Yield |
---|---|
With vinyl acetate; Candida antarctica B lipase on carrier C3 In hexane at 37℃; for 20h; Title compound not separated from byproducts; | |
With pentyl cage-coated capillary column Resolution of racemate; | |
With homochiral metal-organic cage [Zn3(deprotonated [3+3] macrocyclic Schiff base of trans-1,2-diaminocyclohexane and 4-tert-butyl-2,6-diformylphenol)2] coated capillary column In dichloromethane at 115℃; Resolution of racemate; enantioselective reaction; |
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