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CAS No.: | 4986-89-4 |
---|---|
Name: | Pentaerythritol tetraacrylate |
Article Data: | 12 |
Molecular Structure: | |
Formula: | C17H20 O8 |
Molecular Weight: | 352.341 |
Synonyms: | 2-Propenoicacid, 2,2-bis[[(1-oxo-2-propenyl)oxy]methyl]-1,3-propanediyl ester (9CI);Acrylic acid, neopentanetetrayl ester (7CI); Acrylic acid, tetraester withpentaerythritol (8CI); A-TMMT; Aronix M 450; BS 710; Beam Set 710; KayaradA-TMMT; Kayarad PET 40; Kayarad SR 295; Light Acrylate PE 4A; M 450; NK EsterA-TMMT; NK Ester A-YMMT; Pentaerythritol tetraacrylate; Pentaerythritoltetracrylate; SR 295; SR 295 (acrylate); Saret SR 295; Sartomer 295; SartomerSR 295; Tetramethylolmethane tetraacrylate; Tetramethylolmethane tetracrylate;Viscoat 400 |
EINECS: | 225-644-1 |
Density: | 1.16 g/cm3 |
Melting Point: | 18ºC |
Boiling Point: | 450.3 ºC at 760 mmHg |
Flash Point: | 196 ºC |
Hazard Symbols: | Xi |
Risk Codes: | 36/38-43 |
Safety: | 26-39 |
PSA: | 105.20000 |
LogP: | 0.88960 |
Conditions | Yield |
---|---|
With triethylamine In dichloromethane at 0 - 20℃; for 2.5h; | 96.6% |
With triethylamine In dichloromethane at 0℃; Inert atmosphere; |
(E)-but-2-enol
Pentaerythritol
4-methoxy-phenol
acrylic acid
pentaerythritol tetraacrylate
Conditions | Yield |
---|---|
In Petroleum ether |
Pentaerythritol
2-methoxyethyl acrylate
B
pentaerythritol tetraacrylate
C
pentaerythritol triacrylate
Conditions | Yield |
---|---|
With zinc diacetate; oxygen; 4-methoxy-phenol; 1,8-diazabicyclo[5.4.0]undec-7-ene at 105 - 120℃; for 5h; Reagent/catalyst; Inert atmosphere; Overall yield = 48 %; |
Pentaerythritol
2-methoxyethyl acrylate
A
pentaerythritol tetraacrylate
B
pentaerythritol triacrylate
Conditions | Yield |
---|---|
With 1,4-diaza-bicyclo[2.2.2]octane; zinc diacetate; oxygen; 4-methoxy-phenol at 105 - 120℃; under 130 - 760 Torr; for 30h; Inert atmosphere; Overall yield = 96 %; | |
With 1,4-diaza-bicyclo[2.2.2]octane; zinc diacetate; oxygen; 4-methoxy-phenol at 105 - 120℃; under 130 - 760 Torr; for 30h; Catalytic behavior; Reagent/catalyst; Inert atmosphere; Overall yield = 88 %; | |
With 1,4-diaza-bicyclo[2.2.2]octane; zinc diacetate; oxygen; 4-methoxy-phenol at 105 - 120℃; under 130 - 760 Torr; for 30h; Catalytic behavior; Reagent/catalyst; Inert atmosphere; Overall yield = 88 %; |
Conditions | Yield |
---|---|
With 2CF3O3S(1-)*(x)C7H8*C26H42Hf(2+) In acetonitrile at 20℃; for 12h; Green chemistry; |
carbonic acid dimethyl ester
pentaerythritol triacrylate
D
pentaerythritol tetraacrylate
Conditions | Yield |
---|---|
With potassium carbonate In N,N-dimethyl-formamide at 80℃; for 0.5h; Inert atmosphere; Overall yield = 3.8 g; |
Conditions | Yield |
---|---|
With methanesulfonic acid; hypophosphorous acid; copper(l) chloride In toluene at 70℃; Inert atmosphere; | |
With hypophosphorous acid; toluene-4-sulfonic acid; 4-methoxy-phenol In toluene at 82℃; under 225.023 Torr; |
Pentaerythritol
acetic anhydride
acrylic acid
A
Pentaerithrit-triacetat-acrylat
D
pentaerythritol tetraacrylate
Conditions | Yield |
---|---|
Stage #1: Pentaerythritol; acrylic acid With methanesulfonic acid; 4-methoxy-phenol; copper(l) chloride In water; toluene at 75℃; under 1125.11 Torr; for 15h; Inert atmosphere; Stage #2: acetic anhydride With methanesulfonic acid; 4-methoxy-phenol In toluene at 35 - 40℃; for 1h; Inert atmosphere; |
acetic anhydride
pentaerythritol triacrylate
A
Pentaerithrit-triacetat-acrylat
D
pentaerythritol tetraacrylate
Conditions | Yield |
---|---|
With triethylamine In dichloromethane at 20℃; for 2.5h; Inert atmosphere; |
Conditions | Yield |
---|---|
With methanesulfonic acid at 20℃; for 0.5h; Inert atmosphere; |
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Molecular structure of Pentaerythritol tetraacrylate (CAS NO.4986-89-4) is:
Product Name: Pentaerythritol tetraacrylate
CAS Registry Number: 4986-89-4
IUPAC Name: [3-Prop-2-enoyloxy-2,2-bis(prop-2-enoyloxymethyl)propyl] prop-2-enoate
Molecular Weight: 352.3359 [g/mol]
Molecular Formula: C17H20O8
XLogP3-AA: 2.3
H-Bond Donor: 0
H-Bond Acceptor: 8
EINECS: 225-644-1
Melting Point: 18°C
Refractive index: n20/D 1.487(lit.)
Index of Refraction: 1.483
Molar Refractivity: 86.77 cm3
Molar Volume: 303.5 cm3
Surface Tension: 39 dyne/cm
Density: 1.16 g/cm3
Flash Point: 196 °C
Enthalpy of Vaporization: 70.92 kJ/mol
Boiling Point: 450.3 °C at 760 mmHg
Vapour Pressure: 2.66E-08 mmHg at 25°C
Other Registry Number: 113674-04-7 ;124538-16-5 ;150315-46-1 ;152992-37-5 ;154303-16-9 ;255831-13-1
;93218-05-4
Product Categories: Functional Monomer;Acrylic Monomers;C12 to C63Monomers;Carbonyl Compounds;Esters;Polyfunctional Acrylics
Canonical SMILES: C=CC(=O)OCC(COC(=O)C=C)(COC(=O)C=C)COC(=O)C=C
InChI: InChI=1S/C17H20O8/c1-5-13(18)22-9-17(10-23-14(19)6-2,11-24-15(20)7-3)12-25-16(21)8-4/h5-8H,1-4,9-12H2
InChIKey: KNSXNCFKSZZHEA-UHFFFAOYSA-N
Safty information about Pentaerythritol tetraacrylate (CAS NO.4986-89-4) is:
Hazard Codes: Xi
Risk Statements: 36/38-43
R36/38:Irritating to eyes and skin.
R43:May cause sensitization by skin contact.
Safety Statements: 26-39
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S39:Wear eye / face protection.
WGK Germany: 1
Pentaerythritol tetraacrylate , its cas register number is 4986-89-4. It also can be called 2,2-Bis(((1-oxoallyl)oxy)methyl)-1,3-propanediyl diacrylate ; 2-Propenoic acid, 1,1'-(2,2-bis(((1-oxo-2-propen-1-yl)oxy)methyl)-1,3-propanediyl) ester ; 2-Propenoic acid, 2,2-bis(((1-oxo-2-propenyl)oxy)methyl)-1,3-propanediyl ester .