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4986-89-4

Basic Information
CAS No.: 4986-89-4
Name: Pentaerythritol tetraacrylate
Article Data: 12
Molecular Structure:
Molecular Structure of 4986-89-4 (Pentaerythritol tetraacrylate)
Formula: C17H20 O8
Molecular Weight: 352.341
Synonyms: 2-Propenoicacid, 2,2-bis[[(1-oxo-2-propenyl)oxy]methyl]-1,3-propanediyl ester (9CI);Acrylic acid, neopentanetetrayl ester (7CI); Acrylic acid, tetraester withpentaerythritol (8CI); A-TMMT; Aronix M 450; BS 710; Beam Set 710; KayaradA-TMMT; Kayarad PET 40; Kayarad SR 295; Light Acrylate PE 4A; M 450; NK EsterA-TMMT; NK Ester A-YMMT; Pentaerythritol tetraacrylate; Pentaerythritoltetracrylate; SR 295; SR 295 (acrylate); Saret SR 295; Sartomer 295; SartomerSR 295; Tetramethylolmethane tetraacrylate; Tetramethylolmethane tetracrylate;Viscoat 400
EINECS: 225-644-1
Density: 1.16 g/cm3
Melting Point: 18ºC
Boiling Point: 450.3 ºC at 760 mmHg
Flash Point: 196 ºC
Hazard Symbols: IrritantXi
Risk Codes: 36/38-43
Safety: 26-39
PSA: 105.20000
LogP: 0.88960
Synthetic route
115-77-5

Pentaerythritol

814-68-6

acryloyl chloride

4986-89-4

pentaerythritol tetraacrylate

Conditions
ConditionsYield
With triethylamine In dichloromethane at 0 - 20℃; for 2.5h;96.6%
With triethylamine In dichloromethane at 0℃; Inert atmosphere;
504-61-0

(E)-but-2-enol

115-77-5

Pentaerythritol

150-76-5

4-methoxy-phenol

79-10-7

acrylic acid

4986-89-4

pentaerythritol tetraacrylate

Conditions
ConditionsYield
In Petroleum ether
115-77-5

Pentaerythritol

3121-61-7

2-methoxyethyl acrylate

A

2,2-bis(hydroxymethyl)-1,3-propanediyl diacrylate

B

4986-89-4

pentaerythritol tetraacrylate

C

3524-68-3

pentaerythritol triacrylate

Conditions
ConditionsYield
With zinc diacetate; oxygen; 4-methoxy-phenol; 1,8-diazabicyclo[5.4.0]undec-7-ene at 105 - 120℃; for 5h; Reagent/catalyst; Inert atmosphere; Overall yield = 48 %;
115-77-5

Pentaerythritol

3121-61-7

2-methoxyethyl acrylate

A

4986-89-4

pentaerythritol tetraacrylate

B

3524-68-3

pentaerythritol triacrylate

Conditions
ConditionsYield
With 1,4-diaza-bicyclo[2.2.2]octane; zinc diacetate; oxygen; 4-methoxy-phenol at 105 - 120℃; under 130 - 760 Torr; for 30h; Inert atmosphere; Overall yield = 96 %;
With 1,4-diaza-bicyclo[2.2.2]octane; zinc diacetate; oxygen; 4-methoxy-phenol at 105 - 120℃; under 130 - 760 Torr; for 30h; Catalytic behavior; Reagent/catalyst; Inert atmosphere; Overall yield = 88 %;
With 1,4-diaza-bicyclo[2.2.2]octane; zinc diacetate; oxygen; 4-methoxy-phenol at 105 - 120℃; under 130 - 760 Torr; for 30h; Catalytic behavior; Reagent/catalyst; Inert atmosphere; Overall yield = 88 %;
115-77-5

Pentaerythritol

140-88-5

ethyl acrylate

4986-89-4

pentaerythritol tetraacrylate

Conditions
ConditionsYield
With 2CF3O3S(1-)*(x)C7H8*C26H42Hf(2+) In acetonitrile at 20℃; for 12h; Green chemistry;
616-38-6

carbonic acid dimethyl ester

3524-68-3

pentaerythritol triacrylate

A

C14H20O11

B

C16H20O9

C

C15H20O10

D

4986-89-4

pentaerythritol tetraacrylate

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 80℃; for 0.5h; Inert atmosphere; Overall yield = 3.8 g;
115-77-5

Pentaerythritol

79-10-7

acrylic acid

4986-89-4

pentaerythritol tetraacrylate

Conditions
ConditionsYield
With methanesulfonic acid; hypophosphorous acid; copper(l) chloride In toluene at 70℃; Inert atmosphere;
With hypophosphorous acid; toluene-4-sulfonic acid; 4-methoxy-phenol In toluene at 82℃; under 225.023 Torr;
115-77-5

Pentaerythritol

108-24-7

acetic anhydride

79-10-7

acrylic acid

A

51690-75-6

Pentaerithrit-triacetat-acrylat

B

C15H20O8

C

C16H20O8

D

4986-89-4

pentaerythritol tetraacrylate

Conditions
ConditionsYield
Stage #1: Pentaerythritol; acrylic acid With methanesulfonic acid; 4-methoxy-phenol; copper(l) chloride In water; toluene at 75℃; under 1125.11 Torr; for 15h; Inert atmosphere;
Stage #2: acetic anhydride With methanesulfonic acid; 4-methoxy-phenol In toluene at 35 - 40℃; for 1h; Inert atmosphere;
108-24-7

acetic anhydride

3524-68-3

pentaerythritol triacrylate

A

51690-75-6

Pentaerithrit-triacetat-acrylat

B

C15H20O8

C

C16H20O8

D

4986-89-4

pentaerythritol tetraacrylate

Conditions
ConditionsYield
With triethylamine In dichloromethane at 20℃; for 2.5h; Inert atmosphere;
108-24-7

acetic anhydride

3524-68-3

pentaerythritol triacrylate

A

C15H20O8

B

C16H20O8

C

4986-89-4

pentaerythritol tetraacrylate

Conditions
ConditionsYield
With methanesulfonic acid at 20℃; for 0.5h; Inert atmosphere;
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7357-67-7
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  • 2-Propenoic acid,1,1'-[2,2-bis[[(1-oxo-2-propen-1-yl)oxy]methyl]-1,3-propanediyl] ester

  • Casno:

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    2-Propenoic acid,1,1'-[2,2-bis[[(1-oxo-2-propen-1-yl)oxy]methyl]-1,3-propanediyl] ester

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Chemistry

Molecular structure of Pentaerythritol tetraacrylate (CAS NO.4986-89-4) is:

Product Name: Pentaerythritol tetraacrylate
CAS Registry Number: 4986-89-4
IUPAC Name: [3-Prop-2-enoyloxy-2,2-bis(prop-2-enoyloxymethyl)propyl] prop-2-enoate
Molecular Weight: 352.3359 [g/mol]  
Molecular Formula: C17H20O8  
XLogP3-AA: 2.3  
H-Bond Donor: 0  
H-Bond Acceptor: 8
EINECS: 225-644-1
Melting Point: 18°C
Refractive index: n20/D 1.487(lit.)
Index of Refraction: 1.483 
Molar Refractivity: 86.77 cm3 
Molar Volume: 303.5 cm3
Surface Tension: 39 dyne/cm 
Density: 1.16 g/cm3 
Flash Point: 196 °C 
Enthalpy of Vaporization: 70.92 kJ/mol 
Boiling Point: 450.3 °C at 760 mmHg 
Vapour Pressure: 2.66E-08 mmHg at 25°C 
Other Registry Number: 113674-04-7 ;124538-16-5 ;150315-46-1 ;152992-37-5 ;154303-16-9 ;255831-13-1
;93218-05-4
Product Categories: Functional Monomer;Acrylic Monomers;C12 to C63Monomers;Carbonyl Compounds;Esters;Polyfunctional Acrylics
Canonical SMILES: C=CC(=O)OCC(COC(=O)C=C)(COC(=O)C=C)COC(=O)C=C
InChI: InChI=1S/C17H20O8/c1-5-13(18)22-9-17(10-23-14(19)6-2,11-24-15(20)7-3)12-25-16(21)8-4/h5-8H,1-4,9-12H2 
InChIKey: KNSXNCFKSZZHEA-UHFFFAOYSA-N

Safety Profile

Safty information about Pentaerythritol tetraacrylate (CAS NO.4986-89-4) is:
Hazard Codes: IrritantXi
Risk Statements: 36/38-43 
R36/38:Irritating to eyes and skin. 
R43:May cause sensitization by skin contact.
Safety Statements: 26-39 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S39:Wear eye / face protection.
WGK Germany: 1

Specification

 Pentaerythritol tetraacrylate , its cas register number is 4986-89-4. It also can be called 2,2-Bis(((1-oxoallyl)oxy)methyl)-1,3-propanediyl diacrylate ; 2-Propenoic acid, 1,1'-(2,2-bis(((1-oxo-2-propen-1-yl)oxy)methyl)-1,3-propanediyl) ester ; 2-Propenoic acid, 2,2-bis(((1-oxo-2-propenyl)oxy)methyl)-1,3-propanediyl ester .