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| CAS No.: | 5026-62-0 |
|---|---|
| Name: | Sodium methylparaben |
| Article Data: | 5 |
| Molecular Structure: | |
|
|
|
| Formula: | C8H7NaO3 |
| Molecular Weight: | 174.132 |
| Synonyms: | Benzoicacid, 4-hydroxy-, methyl ester, sodium salt (9CI);Sodium, (p-carboxyphenoxy)-, methyl ester(7CI);Bonomold OMNa;Methyl4-hydroxybenzoate sodium salt;Methylparaben sodium;Sodium 4-(methoxycarbonyl)phenoxide;Sodium methylp-hydroxybenzoate;Sodium methylparaben;Sodium p-methoxycarbonylphenoxide; |
| EINECS: | 225-714-1 |
| Density: | 1.42 g/cm3 (20 °C) |
| Melting Point: | >125 °C |
| Boiling Point: | 265.5 °C at 760 mmHg |
| Flash Point: | 116.4 °C |
| Solubility: | 418g/L at 20℃ |
| Appearance: | white powder |
| Hazard Symbols: |
 Xn
|
| Risk Codes: | 22 |
| Safety: | 22-24/25 |
| PSA: | 49.36000 |
| LogP: | 1.61700 |
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| Conditions | Yield |
|---|---|
| With sodium hydroxide In methanol Inert atmosphere; | 95% |
| In water | |
| With sodium hydride In tetrahydrofuran; DMF (N,N-dimethyl-formamide) for 1.5h; | |
| With sodium hydroxide In ethanol; water at 20℃; for 1.83333h; | 32.4 g |
- 73823-12-8
4-(N-phenyl-benzimidoyloxy)-benzoic acid methyl ester
- 124-41-4
sodium methylate
A
- 6780-39-8
E-[2-methoxy-1-phenyl-methylene]-phenylamine
B
- 5026-62-0
sodium methylparaben
| Conditions | Yield |
|---|---|
| In methanol at 29.9℃; Mechanism; var. base concentrations; |
- 141969-79-1
4-[4'-(1-methoxy carbonyl-1-methylethyl)-phenyl]-1,2-epoxybutane
- 5026-62-0
sodium methylparaben
- 99-76-3
methyl 4-hydroxylbenzoate
| Conditions | Yield |
|---|---|
| In N,N-dimethyl-formamide | 98% |
- 5026-62-0
sodium methylparaben
- 107962-24-3
pyrrole-1-carboxylic acid anhydride
| Conditions | Yield |
|---|---|
| In tetrahydrofuran at 25℃; for 0.25h; | 88% |
- 5026-62-0
sodium methylparaben
- 109241-96-5
indole-1-carboxylic acid anhydride
- 109242-03-7
Indole-1-carboxylic acid 4-methoxycarbonyl-phenyl ester
| Conditions | Yield |
|---|---|
| In tetrahydrofuran at 25℃; for 0.25h; | 78% |
- 5026-62-0
sodium methylparaben
- 870-63-3
prenyl bromide
A
- 34593-50-5
methyl 4-((3-methylbut-2-en-1-yl)oxy)benzoate
B
- 99-76-3
methyl 4-hydroxylbenzoate
| Conditions | Yield |
|---|---|
| In Hexafluorobenzene at 20℃; for 24h; Solvent; Temperature; | A 70% B 26% |
| Conditions | Yield |
|---|---|
| In methanol; water at 45 - 55℃; for 2h; | 68% |
- 956117-80-9
2-bromo-4-furan-2-yl-6-thiophen-2-yl-nicotinonitrile
- 5026-62-0
sodium methylparaben
| Conditions | Yield |
|---|---|
| In N,N-dimethyl-formamide at 90℃; for 18h; | 68% |
| Conditions | Yield |
|---|---|
| With hydrogenchloride; potassium hydroxide In methanol; water | 65% |
- 5026-62-0
sodium methylparaben
- 870-63-3
prenyl bromide
A
- 99-76-3
methyl 4-hydroxylbenzoate
B
- 98969-33-6
methyl 4-hydroxy-3-(3'-methyl-2'-butenyl)-5-(3''-methyl-2''-butenyl)benzoate
| Conditions | Yield |
|---|---|
| at 80℃; for 24h; | A 56% B 39% |
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Chemistry
Molecular Formula: C8H7NaO3
Molecular Weight: 174.13 g/mol
EINECS: 225-714-1
Flash Point: 116.4 °C
Melting point: >125 °C
Solubility: Soluble in water
Appearance: White powder
Enthalpy of Vaporization: 52.38 kJ/mol
Boiling Point: 265.5 °C at 760 mmHg
Vapour Pressure: 0.00555 mmHg at 25 °C
Structure of Sodium methylparaben (CAS NO.5026-62-0):
IUPAC Name: Sodium 4-methoxycarbonylphenolate
Product Category of Sodium methylparaben (CAS NO.5026-62-0): Aromatic Esters;Benzoic acid Series
Uses
Sodium methylparaben (CAS NO.5026-62-0) has been used for water-soluble preservatives in dairy products, pickled products, beverages, fruit juice, jelly and cakes, etc..
Toxicity Data With Reference
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| mouse | LD50 | intraperitoneal | 760mg/kg (760mg/kg) | PERIPHERAL NERVE AND SENSATION: FLACCID PARALYSIS WITHOUT ANESTHESIA (USUALLY NEUROMUSCULAR BLOCKAGE) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) BEHAVIORAL: ATAXIA | Journal of the American Pharmaceutical Association, Scientific Edition. Vol. 45, Pg. 260, 1956. |
| mouse | LD50 | intravenous | 170mg/kg (170mg/kg) | Journal of the American Pharmaceutical Association, Scientific Edition. Vol. 45, Pg. 260, 1956. | |
| mouse | LD50 | oral | 2gm/kg (2000mg/kg) | Journal of the American Pharmaceutical Association, Scientific Edition. Vol. 45, Pg. 260, 1956. |
Sodium methylparaben (CAS NO.5026-62-0) hasn't been listed as a carcinogen by NTP, IARC, ACGIH, or CA Prop 65. And the toxicological properties have not been fully investigated. You can see actual entry in RTECS for complete information.
Safety Profile
Hazard Codes: 
Xn
Risk Statements: 22
R22:Harmful if swallowed.
Safety Statements: 22-24/25
S22:Do not breathe dust.
S24/25:Avoid contact with skin and eyes.
Specification
Sodium methylparaben , its cas register number is 5026-62-0. It also can be called p-Hydroxybenzoic acid methyl ester sodium salt ; Sodium (p-carboxyphenoxy)-methyl ester ; 4-Hydroxybenzoic acid methyl ester sodium salt ; Methyl 4-hydroxybenzoate sodium salt ; Methyl p-hydroxybenzoate sodium salt ; Methylparaben sodium ; Sodium 4-(methoxycarbonyl)phenoxide ; Sodium 4-carbomethoxyphenolate ; Sodium p-methoxycarbonylphenoxide ; and Sodium methyl p-hydroxybenzoate . It is hazardous, so the first aid measures and others should be known. Such as: When on the skin: first, should flush skin with plenty of water immediately for at least 15 minutes while removing contaminated clothing. Secondly, get medical aid. Or in the eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Then get medical aid soon. While, it's inhaled: Remove from exposure and move to fresh air immediately. Give artificial respiration while not breathing. When breathing is difficult, give oxygen. And as soon as to get medical aid. Then you have the ingesting of the product: Wash mouth out with water, and get medical aid immediately. Notes to physician: Treat supportively and symptomatically.
In addition, Sodium methylparaben (CAS NO.5026-62-0) absorbs moisture or water from the air. It is not compatible with strong oxidizing agents, and you must not take it with incompatible materials, dust generation. It should be exposured to moist air or water. And also prevent it to broken down into hazardous decomposition products: carbon monoxide, carbon dioxide.