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| CAS No.: | 50471-44-8 |
|---|---|
| Name: | VINCLOZOLIN |
| Article Data: | 17 |
| Molecular Structure: | |
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|
|
| Formula: | C12H9 Cl2 N O3 |
| Molecular Weight: | 286.114 |
| Synonyms: | (?à)-Vinclozolin; BAS 352-04F; BAS35202F; BAS 35204; N-3,5-Dichlorophenyl-5-methyl-5-vinyloxazolidine-2,4-dione;Ornalin; Ranilan; Ronilan; Ronilan 50WP; Vinclozolin |
| EINECS: | 256-599-6 |
| Density: | 1.496 g/cm3 |
| Melting Point: | 108 ºC |
| Boiling Point: | 369.9 °C at 760 mmHg |
| Flash Point: | 177.5 °C |
| Solubility: | v.s. in ethanol, acetone, ethyl acetate, cyclohexane, benzene, and xylene |
| Appearance: | Vinclozolin is a colorless crystal with a slight aromatic odor |
| Hazard Symbols: | T,N,Xn,F |
| Risk Codes: | 60-61-40-43-51/53-36-20/21/22-11 |
| Safety: | Low toxicity by ingestion and inhalation. Mutation data reported. When heated to decomposition it emits very toxic fumes of Cl− and NOx. |
| PSA: | 46.61000 |
| LogP: | 3.48630 |
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Chemistry
MF: C12H9Cl2NO3
MW: 286.11
EINECS: 256-599-6
Density: 1.496 g/cm3
Flash Point: 177.5 °C
Storage temp: APPROX 4°C
Index of Refraction: 1.64
Enthalpy of Vaporization: 61.68 kJ/mol
Boiling Point: 369.9 °C at 760 mmHg
Vapour Pressure: 1.15E-05 mmHg at 25°C
Air & Water Reactions: Hydrolysis rapidly occurs under alkaline conditions
Appearance: Colorless crystals with slight aromatic odor
IUPAC Name: 3-(3,5-dichlorophenyl)-5-ethenyl-5-methyl-1,3-oxazolidine-
2,4-dione
Synonyms: vinchlozoline ; Vinclozalin ; Ronilan ; Ronilan(r) ; Vorlan ; vinclozolin ; 3-(3,5-Dichlorophenyl)-5-ethenyl-5-methyl-2,4-oxazolidinedione
Product Categories: Organics ; OxazolesAnalytical Standards ; DicarboximidesPesticides ; OxazolesPesticides&Metabolites ; Q-ZAnalytical Standards ; VMethod Specific ; 2000/60/EC ; Alpha sort ; Alphabetic ; European Community: ISO and DIN ; Fungicides ; Pesticides
Following is the molecular structure of Ronilan (50471-44-8):
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Uses
Ronilan (50471-44-8) is used as a fungicide.
Production
Reactivity Profile of Ronilan (50471-44-8): A halogenated dicarboximide. Organic amides/imides react with azo and diazo compounds to generate toxic gases. Flammable gases are formed by the reaction of organic amides/imides with strong reducing agents. Amides are very weak bases (weaker than water). Imides are less basic yet and in fact react with strong bases to form salts. That is, they can react as acids. Mixing amides with dehydrating agents such as P2O5 or SOCl2 generates the corresponding nitrile. The combustion of these compounds generates mixed oxides of nitrogen (NOx).
Toxicity Data With Reference
| 1. | mma-sat 100 mg/L | ATSUDG Archives of Toxicology, Supplement.(5)(1982),345. | ||
| 2. | mma-ssp 100 mg/L | ATSUDG Archives of Toxicology, Supplement.(5)(1982),345. | ||
| 3. | orl-rat LD50:10 g/kg | PEMNDP Pesticide Manual. 9 (1991),859. | ||
| 4. | ihl-rat LC50:>29,100 mg/m3/4H | PEMNDP Pesticide Manual. 9 (1991),859. | ||
| 5. | skn-rat LD50:>2 g/kg | FMCHA2 Farm Chemicals Handbook .(Meister Publishing,Willoughy, OH.: )1991,C322. | ||
| 6. | orl-mus LD50:>10 g/kg | DOVEAA Defense des Vegetaux. 32 (1978),72. | ||
| 7. | ihl-rbt LC50:1170 mg/m3/4H | FMCHA2 Farm Chemicals Handbook .(Meister Publishing,Willoughy, OH.: )1991,C322. | ||
| 8. | orl-gpg LD50:8000 mg/kg | 85DPAN Wirksubstanzen der Pflanzenschutz und Schadlingsbekampfungsmittel Werner Perkow,Berlin, Germany.: Verlag Paul Parey,1971/76 |
Safety Profile
Low toxicity by ingestion and inhalation. Mutation data reported. When heated to decomposition it emits very toxic fumes of Cl− and NOx
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