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506-87-6

Basic Information
CAS No.: 506-87-6
Name: Ammonium carbonate
Article Data: 3
Molecular Structure:
Molecular Structure of 506-87-6 (Ammonium carbonate)
Formula: CH8N2O3
Molecular Weight: 96.0861
Synonyms: Carbonicacid, diammonium salt (8CI,9CI);Bis(ammonium) carbonate;Diammonium carbonate;
EINECS: 208-058-0
Density: 2.7 (vs air)
Melting Point: 58 °C
Boiling Point: 333.6 °C at 760 mmHg
Flash Point: 169.8 °C
Solubility: H2O: 0.1 g/mL at 25 °C, clear, colorless
Appearance: white powder
Hazard Symbols: HarmfulXn
Risk Codes: 22
Safety: 24/25
Transport Information: UN 9084
PSA: 64.01000
LogP: 0.87020
Synthetic route

bis(guanidinium)bis(oxalato)cuprate(II)

506-87-6

ammonium carbonate

Conditions
ConditionsYield
at 250 - 310℃; Inert atmosphere;
124-38-9

carbon dioxide

7664-41-7

ammonia

506-87-6

ammonium carbonate

17356-08-0

thiourea

A

124-38-9

carbon dioxide

B

506-87-6

ammonium carbonate

C

S, HI, I2, (NH4)2SO4

S, HI, I2, (NH4)2SO4

Conditions
ConditionsYield
With iodic acid In water at 25℃; for 0.666667h; Rate constant; Product distribution; Mechanism; different ratios of HIO3, reagent and reaction times;
506-87-6

ammonium carbonate

170384-29-9

(+/-)-1-(N-tert-Butoxycarbonylamino)propan-2-one

rac-tert-butyl <(4-methyl-2,5-dioxoimidazolidin-4-yl)methyl>carbamate

Conditions
ConditionsYield
With potassium cyanide In ethanol at 50℃; for 20h;100%
1443-80-7

4-cyanophenyl methyl ketone

151-50-8

potassium cyanide

506-87-6

ammonium carbonate

169808-00-8

4-(R,S)-(4-cyanophenyl)-4-methyl-2,5-dioxoimidazolidine

Conditions
ConditionsYield
In ethanol at 60℃; for 72h;100%
1037368-71-0

2-(tritylamino)methyl-5,6-dihydro-2H-pyran-3(4H)-one

143-33-9

sodium cyanide

506-87-6

ammonium carbonate

1037368-72-1

6-(tritylamino)methyl-7-oxa-1,3-diazaspiro [4.5]decane-2,4-dione

Conditions
ConditionsYield
With ammonia; water; ammonium chloride In ethanol at 60℃; for 23h;100%

potassium cyanide

20061-23-8

spiro<3.3>heptane-2,6-dione

506-87-6

ammonium carbonate

1196087-88-3

C11H12N4O4

Conditions
ConditionsYield
Stage #1: potassium cyanide; spiro<3.3>heptane-2,6-dione; ammonium carbonate In ethanol; water at 60℃; for 75h; Bucherer-Bergs reaction; Inert atmosphere;
Stage #2: With hydrogenchloride; water In ethanol for 1h; pH=2; Inert atmosphere; Cooling with ice;
100%

potassium cyanide

5309-19-3

8-methoxy-2-tetralone

506-87-6

ammonium carbonate

67544-72-3

3',4'-dihydro-8'-methoxyspiro2,5-dione

Conditions
ConditionsYield
With water In ethanol at 80℃; for 12h; Product distribution / selectivity; Sealed tube;100%
In ethanol; water at 80℃; for 12h;100%

potassium cyanide

3612-20-2

1-phenylmethyl-4-piperidone

506-87-6

ammonium carbonate

28936-94-9

8-benzyl-1,3,8-triaza-spiro[4.5]decane-2,4-dione

Conditions
ConditionsYield
Stage #1: 1-phenylmethyl-4-piperidone; ammonium carbonate In methanol; water Cooling with ice;
Stage #2: potassium cyanide With water In methanol at 20℃; for 72h; Cooling with ice;
100%
4746-97-8

cyclohexanedione monoethylene ketal

151-50-8

potassium cyanide

506-87-6

ammonium carbonate

54621-17-9

9,12-dioxa-2,4-diazadispiro[4.2.4Λ{8}.2Λ{5}]tetradecane-1,3-dione

Conditions
ConditionsYield
In ethanol; water at 65℃; for 24h; Bucherer-Bergs reaction;98%
With water In methanol at 65℃; for 18h;68%
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    English name: Ammonium carbonate English synonyms: diammonium carbonate (ammonium carbonate);hartshorn;SALT OF HARTSHORN;HARTSHORN SALT;AMMONIUM CARBONATE;AMMONIUM CARBONATE BUFFER;AMMONIUM CARBONATE BUFFER, FILTERED;AMMONIUM CARBONATE

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Chemistry

Molecular Formula: CH8N2O3
Molar mass: 96.09 g/mol
EINECS: 233-786-0
Flash Point: 169.8 °C
Boiling Point: 333.6 °C at 760 mmHg
Vapour Pressure: 2.58E-05 mmHg at 25°C
Melting point: 58 °C
Water solubility: Soluble
Sensitive: Hygroscopic
Appearance: A colorless crystalline solid or a white powder
Solubility: H2O: 0.1 g/mL at 25 °C, clear, colorless
Product categories: Industrial/Fine Chemicals;Inorganics
Structure of Ammonium carbonate (CAS NO.506-87-6) :

H-Bond Donor: 4
H-Bond Acceptor: 5
IUPAC Name: Azane; carbonic acid
Canonical SMILES: C(=O)(O)O.N.N
InChI: InChI=1S/CH2O3.2H3N/c2-1(3)4;;/h(H2,2,3,4);2*1H3 
InChIKey: PRKQVKDSMLBJBJ-UHFFFAOYSA-N

Uses

 Ammonium carbonate (CAS NO.506-87-6) is used as a leavening agent in particular northern European,particular recipes and Scandinavian. Sometimes,It can be substituted with baking powder, but the finished product will never be as airy and light as the original recipe.

Production

 Ammonium carbonate (CAS NO.506-87-6) was historically obtained by the dry distillation of nitrogenous organic matter such as hair, horn, decomposed urine .The crude product is refined by sublimation, when it is obtained as a white fibrous mass, which consists of a mixture of ammonium bicarbonate, NH4HCO3, and ammonium carbonate, (NH4)2CO3, in molecular proportions; on account of its possessing this constitution it is sometimes called ammonium polycarbonate.Currently, it is produced by heating a mixture of ammonium chloride, or ammonium sulfate and chalk, to redness in iron retorts, the vapors being condensed in leaden receivers.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
dog LDLo intravenous 200mg/kg (200mg/kg)   "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." Vol. 4, Pg. 1289, 1935.
frog LDLo parenteral 758mg/kg (758mg/kg)   "Handbuch der Experimentellen Pharmakologie," Heffter, A., Berlin, Verlag von Julius Springer. V.1-3, 1920-35. For publisher information, see HEPHD2.Vol. 1, Pg. 470, 1923.
frog LDLo subcutaneous 250mg/kg (250mg/kg)   "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." Vol. 4, Pg. 1289, 1935.
mouse LD50 intravenous 96mg/kg (96mg/kg) LUNGS, THORAX, OR RESPIRATION: RESPIRATORY STIMULATION

BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD
American Journal of Veterinary Research. Vol. 29, Pg. 897, 1968.
rabbit LDLo intravenous 200mg/kg (200mg/kg)   "Handbuch der Experimentellen Pharmakologie," Heffter, A., Berlin, Verlag von Julius Springer. V.1-3, 1920-35. For publisher information, see HEPHD2.Vol. 1, Pg. 470, 1923.
rabbit LDLo rectal 800mg/kg (800mg/kg)   Comptes Rendus des Seances de la Societe de Biologie et de Ses Filiales. Vol. 83, Pg. 481, 1920.
rabbit LDLo subcutaneous 900mg/kg (900mg/kg)   Comptes Rendus des Seances de la Societe de Biologie et de Ses Filiales. Vol. 83, Pg. 481, 1920.

Safety Profile

Hazard Codes: HarmfulXn
Risk Statements: 22 
R22:Harmful if swallowed.
Safety Statements: 24/25 
S24/25:Avoid contact with skin and eyes.
RIDADR: UN 9084
WGK Germany: 1
RTECS: BP1925000
F: 13

Specification

 Ammonium carbonate (CAS NO.506-87-6) also can be called Monoammonium carbonate ; Diammonium carbonate ; Carbonic acid, diammonium salt .It is hazardous,so the first aid measures and others should be known.Such as: When on the skin: first,should  flush skin with plenty of water immediatelyfor at least 15 minutes while removing contaminated clothing. Secondly,Get shoesmedical aid . Or in the eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids.Then get medical aid soon.While ,it's Inhaled: Remove from exposure and move to fresh air immediately.Give artificial respiration while not breathing. When breathing is difficult, give oxygen. And as soon as to get medical aid. Then you have the ingesting of the product : Wash mouth out with water,and get medical aid immediately.
In addition, It can be stable at room temperature in closed containers under normal storage and handling conditions..It is not compatible with acids, bases, iron, sodium hypochlorite, zinc, iron salts, calomel,and you must not take it with incompatible materials, and not be exposured to moist air or water and temperatures above 55°C.And also prevent it to broken down into hazardous decomposition products: Nitrogen oxides (NOx) and ammonia (NH3), oxides of carbon.