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Basic Information
| CAS No.: | 507-40-4 |
|---|---|
| Name: | tert-Butyl Hypochlorite |
| Article Data: | 60 |
| Molecular Structure: | |
|
|
|
| Formula: | C4H9 Cl O |
| Molecular Weight: | 108.568 |
| Synonyms: | Hypochlorousacid, tert-butyl ester (8CI); 1,1-Dimethylethyl hypochlorite; tert-Butylhypochlorite |
| EINECS: | 208-072-7 |
| Density: | g/cm3 |
| Boiling Point: | °Cat760mmHg |
| Flash Point: | °C |
| Solubility: |
slight
Stability
Toxicology
|
| Appearance: | yellowish liquid with an irritating odour |
| Risk Codes: | 36/37/38 |
| Safety: | A storage hazard. Ultraviolet light causes exothermic decomposition. Reacts violently with rubber. Reaction with sodium hydrogen cyanamide forms the explosive cyanonitrene. When heated to decomposition it emits toxic fumes of Cl−. See also HYPOCHLORITES. |
| PSA: | 9.23000 |
| LogP: | 1.95530 |
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Synthetic route
Conditions
| Conditions | Yield |
|---|---|
| With sodium hypochlorite; acetic acid In water at 0℃; for 0.166667h; Darkness; | 75% |
| With sodium hypochlorite; acetic acid at 20 - 25℃; | 72.2% |
| With acetic acid for 0.05h; | 66% |
Conditions
| Conditions | Yield |
|---|---|
| In tetrachloromethane; water shaking a soln. of alcohol in CCl4 with an aq. soln. of HClO;; soln. of ester in CCl4 obtained;; | |
| In tetrachloromethane; water shaking a soln. of alcohol in CCl4 with an aq. soln. of HClO;; soln. of ester in CCl4 obtained;; |
Conditions
| Conditions | Yield |
|---|---|
| With acetic acid at 0℃; Darkness; |
- 54760-90-6, 95792-83-9
{bis(trimethylsilyl)amino}-(t-butylimino)phosphane
- 507-40-4
tert-butylhypochlorite
- 79202-19-0
tert-butyl N-tert-butyl-N,N'-bis(trimethylsilyl)phosphoramidochloridimidate
Conditions
| Conditions | Yield |
|---|---|
| In benzene for 2h; Ambient temperature; | 100% |
- 72821-01-3
N-trimethylsilylimidophosphenous acid 2,2,6,6-tetramethylpiperidine
- 507-40-4
tert-butylhypochlorite
Conditions
| Conditions | Yield |
|---|---|
| In benzene at 0℃; for 1h; argon atmosphere; | 100% |
Conditions
| Conditions | Yield |
|---|---|
| In dichloromethane for 3h; anhydrous; | 100% |
- 507-40-4
tert-butylhypochlorite
Conditions
| Conditions | Yield |
|---|---|
| In chlorobenzene at -10 - 20℃; Inert atmosphere; | 100% |
- 507-40-4
tert-butylhypochlorite
- 50732-21-3, 65428-75-3
N,N,N'-tris(trimethylsilyl)phosphenimidous amide
- 79202-16-7
tert-butyl tris(trimethylsilyl)phosphoramidochlorimidate
Conditions
| Conditions | Yield |
|---|---|
| In benzene for 2h; Ambient temperature; | 98% |
- 507-40-4
tert-butylhypochlorite
- 76889-11-7
N'-(1-adamantyl)-N,N-bis(trimethylsilyl)phosphorimidous amide
- 79202-21-4
C20H42ClN2OPSi2
Conditions
| Conditions | Yield |
|---|---|
| In benzene for 2h; Ambient temperature; | 95% |
- 507-40-4
tert-butylhypochlorite
- 1211417-77-4
(1,3-dimethylimidazol-2-ylidene)borane
- 1352941-55-9
(1,3-dimethyl-1H-imidazolium-2-yl)trichloroborate
Conditions
| Conditions | Yield |
|---|---|
| In dichloromethane at -78 - 20℃; for 1.05h; Schlenk technique; Inert atmosphere; | 94% |
Raw Materials
Downstream Products
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tert-Butyl Hypochlorite
Chemistry
MF: C4H9ClO
MW: 108.57
EINECS: 208-072-7
Synonyms/Related:t-Butyl hypochlorite;Tert-Butyl Hypochlorite,Hypochlorous Acid tert-Butyl Ester.
Tert-BUTYL HYPOCHLORITE is a slightly yellowish liquid with a pungent odor. Water insoluble. Flash point near 0°F.
Tert-Butyl hypochlorite is a versatile and inexpensive oxidizing agent, that allows the conversion of alcohols to ketones, aldehydes to acid chlorides, sulfides to sulfoxides, and hydroxylamines to nitroso compounds.The more reactive compound tert-Butyl hypoiodide, can be prepared from tert-butyl hypochlorite and a metal iodide
MW: 108.57
EINECS: 208-072-7
Synonyms/Related:t-Butyl hypochlorite;Tert-Butyl Hypochlorite,Hypochlorous Acid tert-Butyl Ester.
Tert-BUTYL HYPOCHLORITE is a slightly yellowish liquid with a pungent odor. Water insoluble. Flash point near 0°F.
Tert-Butyl hypochlorite is a versatile and inexpensive oxidizing agent, that allows the conversion of alcohols to ketones, aldehydes to acid chlorides, sulfides to sulfoxides, and hydroxylamines to nitroso compounds.The more reactive compound tert-Butyl hypoiodide, can be prepared from tert-butyl hypochlorite and a metal iodide
Uses
tert-BUTYL HYPOCHLORITE is a chlorination agent used in unsaturated rubber.
Safety Profile
A storage hazard. Ultraviolet light causes exothermic decomposition. Reacts violently with rubber. Reaction with sodium hydrogen cyanamide forms the explosive cyanonitrene. When heated to decomposition it emits toxic fumes of Cl−. See also HYPOCHLORITES.
It is corrosive to the skin, eyes, and mucous membranes.
If fire,it will produce irritating, corrosive and/or toxic gases. Inhalation of decomposition products may cause severe injury or death. Contact with substance may cause severe burns to skin and eyes. Runoff from fire control may cause pollution.
It is corrosive to the skin, eyes, and mucous membranes.
If fire,it will produce irritating, corrosive and/or toxic gases. Inhalation of decomposition products may cause severe injury or death. Contact with substance may cause severe burns to skin and eyes. Runoff from fire control may cause pollution.