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CAS No.: | 51-80-9 |
---|---|
Name: | N,N,N',N'-TETRAMETHYLDIAMINOMETHANE |
Article Data: | 43 |
Molecular Structure: | |
Formula: | C5H14 N2 |
Molecular Weight: | 102.18 |
Synonyms: | 2,4-Dimethyl-2,4-diazapentane;Bis(dimethylamino)methane;Dimethyl[(dimethylamino)methyl]amine;Methylenebis(dimethylamine);N,N,N',N'-Tetramethyldiaminomethane;N,N,N',N'-Tetramethylmethanediamine;N,N,N',N'-Tetramethylmethylenediamine;NSC166169;NSC 54796;Tetramethylmethanediamine; |
EINECS: | 200-124-7 |
Density: | 0.813g/cm3 |
Melting Point: | -55°C |
Boiling Point: |
85 °C(lit.) |
Flash Point: | °C |
Solubility: | Fully miscible in water. |
Appearance: | slightly yellow liquid |
Hazard Symbols: | F,C |
Risk Codes: | 11-34 |
Safety: | Poison by intraperitoneal route. Flammable liquid and very dangerous fire hazard when exposed to powerful oxidizers, heat or open flame. When heated to decomposition it emits toxic fumes of NOx. See also AMINES. |
PSA: | 6.48000 |
LogP: | 0.06710 |
Conditions | Yield |
---|---|
In water at 0 - 20℃; | 92% |
With potassium hydroxide at 20 - 25℃; | 89% |
Cooling with ice; | 81% |
Conditions | Yield |
---|---|
In toluene at 90℃; under 760.051 Torr; for 40h; Kinetics; Temperature; Reagent/catalyst; Solvent; Schlenk technique; | A n/a B n/a C n/a D 62% E n/a |
Conditions | Yield |
---|---|
In benzene-d6 at 70℃; Concentration; Temperature; | A 1.09 mg B 58.4% C n/a D 0.125 mg |
Conditions | Yield |
---|---|
In benzene-d6 at 70℃; under 760.051 Torr; for 288h; Inert atmosphere; | A 1.1 mg B n/a C 58% D 0.13 mg |
Conditions | Yield |
---|---|
In benzene-d6 at 70℃; under 760.051 Torr; for 45h; Reagent/catalyst; Schlenk technique; | A n/a B n/a C 40% D n/a |
N-Methoxy-N-chloro-N',N'-dimethylurea
dimethyl amine
A
bis-(dimethylamino)methane
B
tetramethylurea
Conditions | Yield |
---|---|
at 0℃; for 1h; | A 26.4% B 9.1% |
1,4-dioxane
dimethylchloroamine
diethylmagnesium
dimethyl amine
bis-(dimethylamino)methane
Conditions | Yield |
---|---|
With silver |
dimethylaminomethanol
bis-(dimethylamino)methane
Conditions | Yield |
---|---|
bei der Destillation; | |
With potassium hydroxide | |
With dimethyl amine |
Conditions | Yield |
---|---|
at 70℃; | |
at 70℃; |
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Product Name: N,N,N',N'-Tetramethylmethanediamine (CAS NO.51-80-9)
Molecular Formula: C5H14N2
Molecular Weight: 102.18g/mol
Mol File: 51-80-9.mol
Einecs: 200-124-7
Appearance: Slightly yellow liquid
Melting Point: -55°C
Boiling point: 82.5 °C at 760 mmHg
Storage Temperature: Flammables area
Density: 0.749 g/mL at 25 °C(lit.)
Refractive index: n20/D 1.401(lit.)
Stability: Stable, but highly flammable. Incompatible with acids, acid chlorides, acid anhydrides, strong oxidizing agents, carbon dioxide.
Surface Tension: 25.5 dyne/cm
Enthalpy of Vaporization: 32.31 kJ/mol
Vapour Pressure: 78.4 mmHg at 25°C
XLogP3-AA: 0.4
H-Bond Donor: 0
H-Bond Acceptor: 2
Structure Descriptors of N,N,N',N'-Tetramethylmethanediamine (CAS NO.51-80-9):
IUPAC Name: N,N,N',N'-Tetramethylmethanediamine
Canonical SMILES: CN(C)CN(C)C
InChI: InChI=1S/C5H14N2/c1-6(2)5-7(3)4/h5H2,1-4H3
InChIKey: VGIVLIHKENZQHQ-UHFFFAOYSA-N
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
mouse | LD50 | intraperitoneal | 220mg/kg (220mg/kg) | Arzneimittel-Forschung. Drug Research. Vol. 16, Pg. 734, 1966. | |
quail | LD50 | oral | > 316mg/kg (316mg/kg) | Ecotoxicology and Environmental Safety. Vol. 6, Pg. 149, 1982. |
Reported in EPA TSCA Inventory.
Poison by intraperitoneal route. Flammable liquid and very dangerous fire hazard when exposed to powerful oxidizers, heat or open flame. When heated to decomposition it emits toxic fumes of NOx. See also AMINES.
Safety Information of N,N,N',N'-Tetramethylmethanediamine (CAS NO.51-80-9):
Hazard Codes: F,C
Risk Statements: 11-34
11: Highly Flammable
34: Causes burns
Safety Statements: 16-26-36/37/39-45
16: Keep away from sources of ignition - No smoking
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36: Wear suitable protective clothing
37: Wear suitable gloves
39: Wear eye/face protection
45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
N,N,N',N'-Tetramethylmethanediamine ,its CAS NO. is 51-80-9,the synonyms is AI3-26640 ; Bis(dimethylamino)methane ; Dimethyl((dimethylamino)methyl)amine ; EINECS 200-124-7 ; Methylenebis(dimethylamine) ; Methylenediamine, N,N,N',N'-tetramethyl- ; N,N,N',N'-Tetramethyldiaminomethan ; NSC 166169 ; Tetramethylmethylenediamine .