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513-77-9

Basic Information
CAS No.: 513-77-9
Name: Barium carbonate
Molecular Structure:
Molecular Structure of 513-77-9 (Barium carbonate)
Formula: BaCO3
Molecular Weight: 197.35
Synonyms: Pigment White 10;Carbonic acid barium salt (1:1);Carbonic acid, barium salt;Barium monocarbonate;barium(+2) cation carbonate;EPA Pesticide Chemical Code 007501;pigments ;; see also Carbonic acid,compounds,barium salt (1:1);Methane,tetrafluoro-;Carbonic acid, barium salt (1:1);Barium Carbonate Granular;Barium Carbonate, Reagent;Barium Carbonate (Granular);Barium Carbonate (Powder);Barium Carbonate,High purity;Barium carbonate (1:1);Barium Carbonic;Barium carbonate, high purity;
EINECS: 208-167-3
Density: 4.43
Melting Point: 811 °C
Boiling Point: 333.6 °C at 760 mmHg
Flash Point: 169.8 °C
Solubility: 0.002 g/100 mL (20 °C) in water
Appearance: White powder
Hazard Symbols: HarmfulXn
Risk Codes: 22
Safety: 24/25
Transport Information: UN 1564
PSA: 63.19000
LogP: -2.44700
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Chemistry

Molecular Structure of Barium Carbonate (CAS NO.513-77-9):

IUPAC Name: barium(2+) carbonate
Empirical Formula: CBaO3
Molecular Weight: 197.3359
CAS Registry Number: 513-77-9
EINECS: 208-167-3 
Flash Point: 169.8 °C
Enthalpy of Vaporization: 63.37 kJ/mol
Boiling Point: 333.6 °C at 760 mmHg
Vapour Pressure: 2.58E-05 mmHg at 25°C
Melting point: 811 °C
Water solubility: 0.002 g/100 mL (20 °C)
Storage temp: Store at RT. 
Stability: Stable. Incompatible with strong acids.
InChI
InChI=1/CH2O3.Ba/c2-1(3)4;/h(H2,2,3,4);/q;+2/p-2
Smiles
C(=O)([O-])[O-].[Ba+2]
Product Categories: Industrial/Fine Chemicals; Inorganic & organic chemicals; Inorganic Chemicals;Inorganics; Barium SaltsChemical Synthesis; Metal and Ceramic Science; Salts; ACS GradeChemical Synthesis; Essential Chemicals; Inorganic Bases; Routine Reagents; Synthetic Reagents; A-B, Puriss p.a. ACSChemical Synthesis; Analytical Reagents for General Use; Puriss p.a. ACS

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
cat LDLo oral 4mg/kg (4mg/kg)   Yakkyoku. Pharmacy. Vol. 28, Pg. 329, 1977.
dog LDLo oral 400mg/kg (400mg/kg)   Pesticide Chemicals Official Compendium, Association of the American Pesticide Control Officials, Inc., 1966. Vol. -, Pg. 95, 1966.
human LDLo oral 17mg/kg (17mg/kg)   Yakkyoku. Pharmacy. Vol. 28, Pg. 329, 1977.
human TDLo oral 11mg/kg (11mg/kg) GASTROINTESTINAL: ULCERATION OR BLEEDING FROM STOMACH Yakkyoku. Pharmacy. Vol. 31, Pg. 1247, 1980.
human TDLo oral 29mg/kg (29mg/kg) PERIPHERAL NERVE AND SENSATION: FLACCID PARALYSIS WITHOUT ANESTHESIA (USUALLY NEUROMUSCULAR BLOCKAGE)

BEHAVIORAL: MUSCLE WEAKNESS

PERIPHERAL NERVE AND SENSATION: PARESTHESIS
Israel Journal of Medical Sciences. Vol. 3, Pg. 565, 1967.
man LDLo oral 800mg/kg (800mg/kg) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

CARDIAC: CHANGE IN RATE

CARDIAC: OTHER CHANGES
Yakkyoku. Pharmacy. Vol. 28, Pg. 329, 1977.
mouse LD50 intraperitoneal 50mg/kg (50mg/kg)   "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 23, 1982.
mouse LD50 oral 200mg/kg (200mg/kg)   "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 23, 1982.
rat LD50 oral 418mg/kg (418mg/kg)   "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 23, 1982.
rat LDLo intravenous 20mg/kg (20mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
women TDLo oral 800mg/kg (800mg/kg) GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA"

GASTROINTESTINAL: NAUSEA OR VOMITING

LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES
British Medical Journal. Vol. 289, Pg. 882, 1984.

Consensus Reports

Reported in EPA TSCA Inventory. Barium and its compounds are on the Community Right-To-Know List.

Safety Profile

Poison by ingestion, intravenous, and intraperitoneal routes. Human systemic effects by ingestion: stomach ulcers, muscle weakness, paresthesias and paralysis, hypermotility, diarrhea, nausea or vomiting, lung changes. Experimental reproductive effects. Incompatible with BrF3 and 2-furanpercarboxylic acid. See also BARIUM COMPOUNDS (soluble).
Hazard Symbols:HarmfulXn
Risk Codes: R22
R22:Harmful if swallowed.
Safety Description : S24/25
S24/25:Avoid contact with skin and eyes.
RIDADR: UN 1564 6.1/PG 3
RTECS: CQ8600000
HazardClass: 6.1(b)
PackingGroup: III

Standards and Recommendations

OSHA PEL: TWA 0.5 mg(Ba)/m3
ACGIH TLV: TWA 0.5 mg(Ba)/m3; Not Classifiable as a Human Carcinogen
DFG MAK: 0.5 mg(Ba)/m3

Specification

  Barium Carbonate , with CAS number of 513-77-9, can be called (Carbonic acid barium salt ; barium carbonate ; barium (ii) carbonate (gamma-type) ; witherite ; bariumcarbonate(1:1) ; bariumcarbonate(baco3) ; bariummonocarbonate ; bf1(salt) .  The applications of Barium Carbonate (CAS NO.513-77-9) are varied and include use as oil-drilling mud. Barium carbonate is sometimes employed as a neutralizing agent for sulfuric acid and, because both barium carbonate and barium sulfate are insoluble, no contaminating barium ions are introduced. The foregoing application is found in the synthetic dyestuff industry.
Barium carbonate is used in the glass industry and in the brick and clay industry. When barium carbonate is added to the clay used in making bricks, it immobilizes the calcium sulfate and prevents it from migrating to the surface of the bricks and producing a whitish suiface discoloration.