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| CAS No.: | 5130-24-5 |
|---|---|
| Name: | VINYL CHLOROFORMATE |
| Article Data: | 10 |
| Molecular Structure: | |
|
|
|
| Formula: | C3H3ClO2 |
| Molecular Weight: | 106.509 |
| Synonyms: | Formicacid, chloro-, vinyl ester (7CI,8CI);Vinyl chlorocarbonate;Vinylchloroformate;Vinyloxycarbonyl chloride;ethenyl carbonochloridate;carbonochloridic acid, ethenyl ester; |
| EINECS: | 225-874-2 |
| Density: | 1.21 g/cm3 |
| Boiling Point: | 72.1 °C at 760 mmHg |
| Flash Point: | 24 °F |
| Appearance: | clear colourless liquid |
| Hazard Symbols: |
 F； T
|
| Risk Codes: | 23/24/25-34-11 |
| Safety: | 16-26-36-45-36/37 |
| Transport Information: | UN 3390 6 |
| PSA: | 26.30000 |
| LogP: | 1.50530 |
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| Conditions | Yield |
|---|---|
| palladium diacetate In hexanedinitrile at -2 - 2℃; for 63h; Product distribution / selectivity; | 85.2% |
| With palladium diacetate In acetonitrile |
| Conditions | Yield |
|---|---|
| at 425 - 460℃; Pyrolysis; |
- 124-05-0
ethylenebis(chloroformate)
A
- 75-34-3
1,1-dichloroethane
B
- 5130-24-5
Vinyl chloroformate
C
- 50893-53-3
carbonochloridic acid 1-chloro-ethyl ester
D
- 627-11-2
2-Chloroethyl chloroformate
| Conditions | Yield |
|---|---|
| at 460℃; Produkt 5: 1.2-Dichlor-aethan.Pyrolysis; |
| Conditions | Yield |
|---|---|
| Pyrolysis; | |
| at 425 - 460℃; Pyrolysis; |
| Conditions | Yield |
|---|---|
| In diethyl ether; diethylene glycol dimethyl ether |
| Conditions | Yield |
|---|---|
| With pyridine In diethyl ether 1.) 1 h, 0 deg C, 2.) 8 h, 25 deg C; |
- 5130-24-5
Vinyl chloroformate
- 203570-57-4
2-Benzyl-4,4-diphenyl-octahydro-2-aza-4-sila-inden-7-one
- 203570-62-1
7-Oxo-4,4-diphenyl-octahydro-2-aza-4-sila-indene-2-carboxylic acid vinyl ester
| Conditions | Yield |
|---|---|
| With triethylamine In 1,2-dichloro-ethane for 2.5h; Ambient temperature; | 100% |
- 5130-24-5
Vinyl chloroformate
- 189363-85-7
2-(3,4-dimethoxyphenyl)-2-cyclohexen-1-ol
| Conditions | Yield |
|---|---|
| With pyridine In dichloromethane at 0℃; | 100% |
- 5130-24-5
Vinyl chloroformate
- 215609-91-9
2-(3,4-methylenedioxyphenyl)-2-cyclohexen-1-ol
- 335371-05-6
carbonic acid 2-benzo[1,3]dioxol-5-yl-cyclohex-2-enyl ester vinyl ester
| Conditions | Yield |
|---|---|
| With pyridine In dichloromethane at 0℃; | 100% |
- 719-80-2
Ethyl diphenylphosphinite
- 5130-24-5
Vinyl chloroformate
- 1237132-78-3
diphenylvinyloxycarbonylphosphinoxide
| Conditions | Yield |
|---|---|
| at 0 - 20℃; for 3.25h; Michaelis-Arbuzov reaction; | 99% |
- Total:22 Page 1 of 1 1
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Specification
The Vinyl chlorocarbonate, with the CAS registry number 5130-24-5 and EINECS registry number 225-874-2, has the systematic name and IUPAC name of ethenyl carbonochloridate. It is a kind of clear colourless liquid, and belongs to the followiing product categories: Monomers; Polymer Science; Vinyl Esters. And the molecular formula of the chemical is C3H3ClO2. What' s more, it should bestored at 2-8°C.
The characteristics of Vinyl chlorocarbonate are as followings: (1)ACD/LogP: 1.51; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 1.51; (4)ACD/LogD (pH 7.4): 1.51; (5)ACD/BCF (pH 5.5): 8.24; (6)ACD/BCF (pH 7.4): 8.24; (7)ACD/KOC (pH 5.5): 157.52; (8)ACD/KOC (pH 7.4): 157.52; (9)#H bond acceptors: 2; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 2; (12)Polar Surface Area: 26.3 Å2; (13)Index of Refraction: 1.42; (14)Molar Refractivity: 22.29 cm3; (15)Molar Volume: 88 cm3; (16)Polarizability: 8.83×10-24cm3; (17)Surface Tension: 28.6 dyne/cm; (18)Density: 1.21 g/cm3; (19)Enthalpy of Vaporization: 31.35 kJ/mol; (20)Boiling Point: 72.1 °C at 760 mmHg; (21)Vapour Pressure: 120 mmHg at 25°C.
Uses of Vinyl chlorocarbonate: It can react with diazomethane to produce vinyl diazoacetate, and the yield is about 92%.
You should be cautious while dealing with this chemical. It is highly flammable chemical which may cause burns. And it is toxic by inhalation, in contact with skin and if swallowed. Therefore, you had better take the following instructions: Keep away from sources of ignition - No smoking; Wear suitable protective clothing and gloves, and if in case of contacting with eyes, rinse immediately with plenty of water and seek medical advice; In case of accident or if you feel unwell, seek medical advice immediately (show label where possible).
Addtionally, the following datas could be converted into the molecular structure:
(1)SMILES: ClC(=O)O\C=C
(2)InChI: InChI=1/C3H3ClO2/c1-2-6-3(4)5/h2H,1H2
(3)InChIKey: PQLFROTZSIMBKR-UHFFFAOYAD