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51312-42-6

Basic Information
CAS No.: 51312-42-6
Name: SODIUM PHOSPHOTUNGSTATE
Molecular Structure:
Molecular Structure of 51312-42-6 (SODIUM PHOSPHOTUNGSTATE)
Formula: Na4O2•O5P2•O36W12•18H2O
Molecular Weight: 3372.46
Synonyms: phosphotungsticacidsodiumcrystalline;SODIUMPHOSPHOTUNGSTATE
Density: g/cm3
Melting Point: 350°C
Boiling Point: 158°Cat760mmHg
Flash Point: °C
Solubility: very soluble H2O, alcohol [HAW93]
Appearance: Crystalline
Hazard Symbols: An oxidizing agent.
Risk Codes: 36/37/38-22
Safety: Moderately toxic by ingestion. When heated to decomposition it emits toxic fumes of POx and Na2O. See also TUNGSTEN COMPOUNDS.
PSA: 710.58000
LogP: -3.89080
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Chemistry

Molecule structure of Sodium phosphotungstate (CAS NO.51312-42-6) :

IUPAC Name: trisodium; dioxotungsteniooxy-[(oxido(dioxo)tungstenio)oxy-dioxotungstenio]oxy-dioxotungsten; phosphoric acid; hydrate 
Molecular Weight: 2967.038171 g/mol
Molecular Formula: H5Na3O41PW12 
Melting Point: 350 °C
Storage Temp.: store at RT.
H-Bond Donor: 4
H-Bond Acceptor: 41
Rotatable Bond Count: 12
Exact Mass: 2966.185579
MonoIsotopic Mass: 2968.184886
Topological Polar Surface Area: 641
Heavy Atom Count: 57
Complexity: 611
Canonical SMILES: O.OP(=O)(O)O.[O-][W](=O)(=O)O[W](=O)(=O)O[W](=O)(=O)O[W](=O)=O.[O-][W](=
O)(=O)O[W](=O)(=O)O[W](=O)(=O)O[W](=O)=O.[O-][W](=O)(=O)O[W](=O)(=O)O[W](=O)(=O)O[W](=O)=O.[Na+].[Na+].[Na+]
InChIKey: VBTVBWPYDARGPT-UHFFFAOYSA-N
EINECS: 234-716-1

Uses

 Sodium phosphotungstate (CAS NO.51312-42-6) is used for determination of alkaloids, urea acid and potassium reagents.

Toxicity Data With Reference

1.    

orl-rat LD50:1600 mg/kg

    HYSAAV    Hygiene and Sanitation: English Translation of Gigiena Sanitariya. 31 (1966),197.
2.    

orl-mus LD50:700 mg/kg

    HYSAAV    Hygiene and Sanitation: English Translation of Gigiena Sanitariya. 31 (1966),197.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Moderately toxic by ingestion. When heated to decomposition it emits toxic fumes of POx and Na2O. See also TUNGSTEN COMPOUNDS.
Hazard Codes: HarmfulXn
Risk Statements: 36/37/38-22 
R36/37/38:Irritating to eyes, respiratory system and skin. 
R22:Harmful if swallowed.
Safety Statements: 26-36 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36:Wear suitable protective clothing.
RIDADR: 1479
WGK Germany: 3
RTECS: TH5775000
HazardClass: 5.1
PackingGroup III

Standards and Recommendations

ACGIH TLV: TWA 1 mg(W)/m3; STEL 3 mg(W)/m3
NIOSH REL: TWA 1 mg(W)/m3

Specification

 Sodium phosphotungstate (CAS NO.51312-42-6) is also called Sodium tungstophosphate ; Tungstophosphoric acid, sodium salt ; Phosphotungstic acid, sodium salt ; Sodium tungsten hydroxide oxide phosphate . Sodium phosphotungstate (CAS NO.51312-42-6) is crystalline.