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| CAS No.: | 527-07-1 |
|---|---|
| Name: | Sodium gluconate |
| Article Data: | 22 |
| Molecular Structure: | |
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|
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| Formula: | C6H11NaO7 |
| Molecular Weight: | 218.139 |
| Synonyms: | Gluconic acid sodium salt;Clewat GL;sodium 2,3,4,5,6-pentahydroxyhexanoate;Sunmorl N 60S;Gluconic acid, monosodium salt, D-;D-Gluconic acid,monosodium salt;Recover;Sodium D-gluconate; |
| EINECS: | 208-407-7 |
| Density: | 1.763 g/cm3 |
| Melting Point: | 206 °C (dec.)(lit.) |
| Boiling Point: | 673.6 °C at 760 mmHg |
| Flash Point: | 375.2 °C |
| Solubility: | Very soluble in water; sparingly soluble in alcohol; insoluble in ether. |
| Appearance: | white or off-white granular powder |
| Safety: | 24/25 |
| PSA: | 141.28000 |
| LogP: | -4.82780 |
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- 548773-13-32-amino-4,6-dimethylpyrimidine-5-carboxylic acid
- 492-61-5
β-D-glucose
A
- 6347-01-9
fructopyranose
B
- 527-07-1
sodium D-gluconate
C
- 23846-32-4
sodium D-arabino-hexulosonate
D
- 28538-09-2
sodium D-xylo-5-hexulosonate
| Conditions | Yield |
|---|---|
| With sodium hydroxide; air; Pd-Bi on charcoal at 39.9℃; for 2.58333h; Product distribution; Mechanism; var. time, var. catalyst ratio, var. catalyst; | A 0.2% B 99.4% C n/a D n/a E n/a |
| Conditions | Yield |
|---|---|
| With oxygen; sodium carbonate In water at 20℃; for 1h; Reagent/catalyst; Time; | 90.9% |
| With silver-graphite; oxygen; sodium hydroxide In water at 55℃; for 3.5h; pH=8.5; Reagent/catalyst; | 51.5% |
| With sodium hydroxide; potassium bromide Electrolysis.durch elektrolytische Oxydation; |
| Conditions | Yield |
|---|---|
| With 2,2,6,6-tetramethyl-piperidine-N-oxyl; sodium hypochlorite; sodium bromide In water at 5℃; pH=11.7; | A n/a B n/a C 90% |
| With 2,2,6,6-tetramethyl-piperidine-N-oxyl; sodium hypochlorite; sodium bromide In water at 5℃; pH=11.2; Product distribution; Further Variations:; pH-values; Reaction partners; | A n/a B n/a C 64% |
| With 2,2,6,6-tetramethyl-piperidine-N-oxyl; sodium hypochlorite; sodium bromide In water at 5℃; pH=9.5; |
- 50-99-7
D-glucose
A
- 141-53-7
sodium formate
B
- 127-09-3
sodium acetate
C
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sodium glycolate
D
- 527-07-1
sodium D-gluconate
| Conditions | Yield |
|---|---|
| With oxygen; sodium hydroxide at 150℃; under 15001.5 Torr; for 2h; Reagent/catalyst; Autoclave; | A 5.67% B 7.7% C 9.83% D 38.14% |
| Conditions | Yield |
|---|---|
| With sodium hydrogencarbonate; sodium bromide at 25℃; Rate constant; Kinetics; electrochemical oxidation; var. glucose and NaBr conc., var. potential range; | |
| With glucose dehydrogenase from Bacillus sp.; C44H28ClFeN4O12S4; sodium chloride; sodium hydroxide In water at 20℃; under 760.051 Torr; for 24h; pH=7; Enzymatic reaction; | |
| With GDH; oxygen; sodium chloride; catalase; 7-(trifluoromethyl)-1,10-ethyleneisoalloxazinium chloride In water at 20℃; for 2h; pH=7; Catalytic behavior; Time; Enzymatic reaction; | > 99 %Spectr. |
| With gold-ceria nanoparticle; dihydrogen peroxide; sodium hydroxide In water at 20℃; for 0.0833333h; Catalytic behavior; Reagent/catalyst; Time; Irradiation; |
| Conditions | Yield |
|---|---|
| With sodium hydroxide; oxygen; Pd-Bi on charcoal In water at 50℃; for 6h; | 1.4 g |
| Conditions | Yield |
|---|---|
| With 4-acetylamino-2,2,6,6-tetramethylpiperidine-N-oxyl; sodium hypochlorite; sodium bromide In sodium hydroxide at 0 - 5℃; for 1h; pH=11.4 - 11.6; Product distribution; Further Variations:; Reagents; Solvents; reagent concentration; | A n/a B 4 % Spectr. C n/a D 90 % Spectr. |
| Conditions | Yield |
|---|---|
| With 1 weight% Au on SiO2; dihydrogen peroxide; sodium hydroxide In water at 20℃; for 0.25h; Catalytic behavior; Reagent/catalyst; Time; |
- 2280-44-6
D-Glucose
A
- 57-48-7
D-Fructose
B
- 3458-28-4
D-Mannose
C
- 50-70-4
D-sorbitol
D
- 527-07-1
sodium D-gluconate
F
- 69-79-4
D-maltose
| Conditions | Yield |
|---|---|
| With dihydrogen peroxide; sodium hydroxide In water at 50 - 60℃; Sealed tube; |
| Conditions | Yield |
|---|---|
| Stage #1: β-D-glucose With glucose dehydrogenase; 1-(4-hydroxy-3,5-dimethoxy-phenyl)-ethanone; laccase from Myceliophthora thermophila; NAD In aq. buffer at 30℃; pH=7; Enzymatic reaction; Stage #2: With sodium hydroxide In aq. buffer pH=7; |
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Chemistry
Molecular Structure of Glonsen (CAS NO.527-07-1):
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IUPAC Name: sodium 2,3,4,5,6-pentahydroxyhexanoate
Empirical Formula: C6H11NaO7
Molecular Weight: 218.1371
H bond acceptors: 7
H bond donors: 6
Freely Rotating Bonds: 10
Polar Surface Area: 83.45Å2
Flash Point: 375.2 °C
Enthalpy of Vaporization: 113.2 kJ/mol
Boiling Point: 673.6 °C at 760 mmHg
Vapour Pressure: 4.95E-21 mmHg at 25°C
Melting point: 206 °C (dec.)(lit.)
EINECS: 208-407-7
Solubility H2O: 0.1 g/mL
Merck: 14,4456
BRN: 3919651
Stability: Stable. Incompatible with strong oxidizing agents
Product Categories: Biochemistry; Glucose; Sugar Acids; Sugars; Dextrins,Sugar & Carbohydrates
InChI
InChI=1/C6H12O7.Na/c7-1-2(8)3(9)4(10)5(11)6(12)13;/h2-5,7-11H,1H2,(H,12,13);/q;+1/p-1
Smiles
O[C@@H]([C@@H]([C@@H](CO)O)O)[C@@H](C(=O)[O-])O.[Na+]
Toxicity Data With Reference
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| rabbit | LDLo | intravenous | 7630mg/kg (7630mg/kg) | Archivio di Farmacologia Sperimentale e Scienze Affini. Vol. 68, Pg. 1, 1939. |
Safety Profile
Safety Statements: 24/25
S24/25:Avoid contact with skin and eyes.
WGK Germany: 1
RTECS: LZ5235000
HS Code: 29181600
Specification
Glonsen , with CAS number of 527-07-1, can be called D-Gluconic acid, monosodium salt ; Gluconato di sodio ; Monosodium D-gluconate ; Gluconic acid sodium salt ; Sodium D-gluconate ; Sodium gluconate . It is a white or off-white granular powder.