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527-07-1

Basic Information
CAS No.: 527-07-1
Name: Sodium gluconate
Article Data: 22
Molecular Structure:
Molecular Structure of 527-07-1 (Sodium gluconate)
Formula: C6H11NaO7
Molecular Weight: 218.139
Synonyms: Gluconic acid sodium salt;Clewat GL;sodium 2,3,4,5,6-pentahydroxyhexanoate;Sunmorl N 60S;Gluconic acid, monosodium salt, D-;D-Gluconic acid,monosodium salt;Recover;Sodium D-gluconate;
EINECS: 208-407-7
Density: 1.763 g/cm3
Melting Point: 206 °C (dec.)(lit.)
Boiling Point: 673.6 °C at 760 mmHg
Flash Point: 375.2 °C
Solubility: Very soluble in water; sparingly soluble in alcohol; insoluble in ether.
Appearance: white or off-white granular powder
Safety: 24/25
PSA: 141.28000
LogP: -4.82780
Synthetic route
492-61-5

β-D-glucose

A

6347-01-9

fructopyranose

B

527-07-1

sodium D-gluconate

C

23846-32-4

sodium D-arabino-hexulosonate

D

28538-09-2

sodium D-xylo-5-hexulosonate

E

D-glucaric acid disodium salt

Conditions
ConditionsYield
With sodium hydroxide; air; Pd-Bi on charcoal at 39.9℃; for 2.58333h; Product distribution; Mechanism; var. time, var. catalyst ratio, var. catalyst;A 0.2%
B 99.4%
C n/a
D n/a
E n/a
50-99-7

D-glucose

527-07-1

sodium D-gluconate

Conditions
ConditionsYield
With oxygen; sodium carbonate In water at 20℃; for 1h; Reagent/catalyst; Time;90.9%
With silver-graphite; oxygen; sodium hydroxide In water at 55℃; for 3.5h; pH=8.5; Reagent/catalyst;51.5%
With sodium hydroxide; potassium bromide Electrolysis.durch elektrolytische Oxydation;
50-99-7

D-glucose

A

527-07-1

sodium D-gluconate

B

868-18-8

sodium tartrate

C

D-glucaric acid disodium salt

Conditions
ConditionsYield
With 2,2,6,6-tetramethyl-piperidine-N-oxyl; sodium hypochlorite; sodium bromide In water at 5℃; pH=11.7;A n/a
B n/a
C 90%
With 2,2,6,6-tetramethyl-piperidine-N-oxyl; sodium hypochlorite; sodium bromide In water at 5℃; pH=11.2; Product distribution; Further Variations:; pH-values; Reaction partners;A n/a
B n/a
C 64%
With 2,2,6,6-tetramethyl-piperidine-N-oxyl; sodium hypochlorite; sodium bromide In water at 5℃; pH=9.5;
50-99-7

D-glucose

A

141-53-7

sodium formate

B

127-09-3

sodium acetate

D

527-07-1

sodium D-gluconate

Conditions
ConditionsYield
With oxygen; sodium hydroxide at 150℃; under 15001.5 Torr; for 2h; Reagent/catalyst; Autoclave;A 5.67%
B 7.7%
C 9.83%
D 38.14%
2280-44-6

D-Glucose

527-07-1

sodium D-gluconate

Conditions
ConditionsYield
With sodium hydrogencarbonate; sodium bromide at 25℃; Rate constant; Kinetics; electrochemical oxidation; var. glucose and NaBr conc., var. potential range;
With glucose dehydrogenase from Bacillus sp.; C44H28ClFeN4O12S4; sodium chloride; sodium hydroxide In water at 20℃; under 760.051 Torr; for 24h; pH=7; Enzymatic reaction;
With GDH; oxygen; sodium chloride; catalase; 7-(trifluoromethyl)-1,10-ethyleneisoalloxazinium chloride In water at 20℃; for 2h; pH=7; Catalytic behavior; Time; Enzymatic reaction;> 99 %Spectr.
With gold-ceria nanoparticle; dihydrogen peroxide; sodium hydroxide In water at 20℃; for 0.0833333h; Catalytic behavior; Reagent/catalyst; Time; Irradiation;
488-79-9

6-deoxy-D-glucose

527-07-1

sodium D-gluconate

Conditions
ConditionsYield
With sodium hydroxide; oxygen; Pd-Bi on charcoal In water at 50℃; for 6h;1.4 g
Conditions
ConditionsYield
With 4-acetylamino-2,2,6,6-tetramethylpiperidine-N-oxyl; sodium hypochlorite; sodium bromide In sodium hydroxide at 0 - 5℃; for 1h; pH=11.4 - 11.6; Product distribution; Further Variations:; Reagents; Solvents; reagent concentration;A n/a
B 4 % Spectr.
C n/a
D 90 % Spectr.
2280-44-6

D-Glucose

A

527-07-1

sodium D-gluconate

B

D-glucaric acid disodium salt

Conditions
ConditionsYield
With 1 weight% Au on SiO2; dihydrogen peroxide; sodium hydroxide In water at 20℃; for 0.25h; Catalytic behavior; Reagent/catalyst; Time;
2280-44-6

D-Glucose

A

57-48-7

D-Fructose

B

3458-28-4

D-Mannose

C

50-70-4

D-sorbitol

D

527-07-1

sodium D-gluconate

E

D-glucaric acid disodium salt

F

69-79-4

D-maltose

Conditions
ConditionsYield
With dihydrogen peroxide; sodium hydroxide In water at 50 - 60℃; Sealed tube;
492-61-5

β-D-glucose

527-07-1

sodium D-gluconate

Conditions
ConditionsYield
Stage #1: β-D-glucose With glucose dehydrogenase; 1-(4-hydroxy-3,5-dimethoxy-phenyl)-ethanone; laccase from Myceliophthora thermophila; NAD In aq. buffer at 30℃; pH=7; Enzymatic reaction;
Stage #2: With sodium hydroxide In aq. buffer pH=7;
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Chemistry

Molecular Structure of Glonsen (CAS NO.527-07-1):

IUPAC Name: sodium 2,3,4,5,6-pentahydroxyhexanoate 
Empirical Formula: C6H11NaO7
Molecular Weight: 218.1371
H bond acceptors: 7
H bond donors: 6
Freely Rotating Bonds: 10
Polar Surface Area: 83.45Å2
Flash Point: 375.2 °C
Enthalpy of Vaporization: 113.2 kJ/mol
Boiling Point: 673.6 °C at 760 mmHg
Vapour Pressure: 4.95E-21 mmHg at 25°C
Melting point: 206 °C (dec.)(lit.)
EINECS: 208-407-7
Solubility H2O: 0.1 g/mL
Merck: 14,4456
BRN: 3919651
Stability: Stable. Incompatible with strong oxidizing agents
Product Categories: Biochemistry; Glucose; Sugar Acids; Sugars; Dextrins,Sugar & Carbohydrates
InChI
InChI=1/C6H12O7.Na/c7-1-2(8)3(9)4(10)5(11)6(12)13;/h2-5,7-11H,1H2,(H,12,13);/q;+1/p-1
Smiles
O[C@@H]([C@@H]([C@@H](CO)O)O)[C@@H](C(=O)[O-])O.[Na+]

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
rabbit LDLo intravenous 7630mg/kg (7630mg/kg)   Archivio di Farmacologia Sperimentale e Scienze Affini. Vol. 68, Pg. 1, 1939.

Safety Profile

Safety Statements: 24/25
S24/25:Avoid contact with skin and eyes.
WGK Germany: 1
RTECS: LZ5235000
HS Code: 29181600

Specification

  Glonsen , with CAS number of 527-07-1, can be called D-Gluconic acid, monosodium salt ; Gluconato di sodio ; Monosodium D-gluconate ; Gluconic acid sodium salt ; Sodium D-gluconate ; Sodium gluconate . It is a white or off-white granular powder.