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53439-91-1

Basic Information
CAS No.: 53439-91-1
Name: L-Phenylacetyl Carbinol
Article Data: 41
Molecular Structure:
Molecular Structure of 53439-91-1 (L-Phenylacetyl Carbinol)
Formula: C9H10O2
Molecular Weight: 150.177
Synonyms: (S)-PAC;1S-FP;(S)-(+)-1-hydroxy-1-phenylpropan-2-one;(S)-1-hydroxy-1-phenylpropane-2-one;(S)-(+)-1-hydroxy-1-phenyl-2-propanone;(S)-1-hydroxy-1-phenyl-2-propanone;(1S)-1-hydroxy-1-phenylpropan-2-one;
Density: 1.119±0.06 g/cm3(Predicted)
Boiling Point: 253.3±20.0 °C(Predicted)
PSA: 37.30000
LogP: 1.30900
Synthetic route
579-07-7

1-Phenylpropane-1,2-dione

53439-91-1

(S)-phenylacetylcarbinol

Conditions
ConditionsYield
With Arthrobacter sp. TS-15 recombinant pseudoephedrine dehydrogenase; NADH In aq. phosphate buffer at 25℃; pH=7.5; Kinetics; Green chemistry; Enzymatic reaction; enantioselective reaction;99%
115-22-0

3-Hydroxy-3-methyl-2-butanone

100-52-7

benzaldehyde

53439-91-1

(S)-phenylacetylcarbinol

Conditions
ConditionsYield
With acetoin:dichlorophenolindophenol oxidoreductase from Bacillus licheniformis; thiamine diphosphate; magnesium sulfate In aq. phosphate buffer; dimethyl sulfoxide at 30℃; for 24h; pH=6.5; Catalytic behavior; Solvent; Benzoin Condensation; Green chemistry; Enzymatic reaction; enantioselective reaction;84%
With thiamine diphosphate dependent acetoin:dichlorophenolindophenol oxidoreductase In aq. phosphate buffer; dimethyl sulfoxide at 30℃; for 48h; pH=6.5; Enzymatic reaction;
1026422-63-8

(2S,6R,7S,8aR)-7-Allyl-6-benzyl-6,8a-dimethyl-3-methylene-2-phenyl-hexahydro-oxazolo[3,2-a]pyridin-5-one

A

53439-91-1

(S)-phenylacetylcarbinol

B

(3R,4S)-4-Allyl-3-benzyl-3,6-dimethyl-3,4-dihydro-1H-pyridin-2-one

Conditions
ConditionsYield
With toluene-4-sulfonic acid In tetrahydrofuran; water Heating;A n/a
B 76%
115-22-0

3-Hydroxy-3-methyl-2-butanone

100-52-7

benzaldehyde

A

3,4-dihydroxy-3,4-dimethylpentan-2-one

B

1798-60-3

(R)-1-hydroxy-1-phenyl-2-propanone

C

53439-91-1

(S)-phenylacetylcarbinol

Conditions
ConditionsYield
With acetoin:dichlorophenolindophenol oxidoreductase from Bacillus licheniformis; thiamine diphosphate; magnesium sulfate In aq. phosphate buffer; dimethyl sulfoxide at 30℃; for 12h; pH=6.5; Benzoin Condensation; Green chemistry; Enzymatic reaction; enantioselective reaction;A 2%
B n/a
C n/a
917-64-6

methyl magnesium iodide

120443-82-5

(R)-2-phenyl-2-(trimethylsiloxy)acetonitrile

A

1798-60-3

(R)-1-hydroxy-1-phenyl-2-propanone

B

53439-91-1

(S)-phenylacetylcarbinol

Conditions
ConditionsYield
With hydrogenchloride 1.) ether, reflux, 2 h; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
With sulfuric acid 1.) ether, reflux, 4 h; 2.) 0 deg C, 8 h; Yield given. Multistep reaction. Yields of byproduct given;
43108-63-0

1-phenyl-2-trimethylsiloxy-1-propene

A

1798-60-3

(R)-1-hydroxy-1-phenyl-2-propanone

B

53439-91-1

(S)-phenylacetylcarbinol

Conditions
ConditionsYield
With (+)-(2S,8aS)-(camphorylsulfonyl)oxaziridine; methyllithium 1.) HMPA, THF, 0 deg C, 1h; 2.) -78 deg C; Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
103-79-7

1-phenyl-acetone

A

1798-60-3

(R)-1-hydroxy-1-phenyl-2-propanone

B

53439-91-1

(S)-phenylacetylcarbinol

Conditions
ConditionsYield
With (+)-(2S,8aS)-(camphorylsulfonyl)oxaziridine; lithium diisopropyl amide 1.) HMPA, THF, -78 deg C; 2.) HMPA, -78 deg C; Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
With (+)-(2S,8aS)-(camphorylsulfonyl)oxaziridine; sodium hexamethyldisilazane 1.) THF, HMPA, -78 deg C, 30 min, 2.) -78 deg C, 15 min; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
With Bacillus megaterium cytochrome P450-BM3 V78F mutant Reagent/catalyst; Enzymatic reaction; enantioselective reaction;A n/a
B n/a
With Bacillus megaterium cytochrome P450-BM3 A328R mutant Catalytic behavior; Reagent/catalyst; Enzymatic reaction; enantioselective reaction;A n/a
B n/a
579-07-7

1-Phenylpropane-1,2-dione

A

5650-40-8

2-hydroxypropiophenone

B

1798-60-3

(R)-1-hydroxy-1-phenyl-2-propanone

C

53439-91-1

(S)-phenylacetylcarbinol

Conditions
ConditionsYield
With NAD; isopropyl alcohol In hexane; water Ambient temperature; PED alcohol dehydrogenase, phosphate buffer pH 7.1; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
1798-60-3

(R)-1-hydroxy-1-phenyl-2-propanone

53439-91-1

(S)-phenylacetylcarbinol

Conditions
ConditionsYield
In water at 30℃; Product distribution; racemization;
19980-24-6

(Z)-1-phenyl-2-(trimethylsiloxy)propene

A

1798-60-3

(R)-1-hydroxy-1-phenyl-2-propanone

B

53439-91-1

(S)-phenylacetylcarbinol

Conditions
ConditionsYield
With sodium hypochlorite; 4-Phenylpyridine 1-oxide; phosphate buffer; 5,5'-MeO-substituted (R,R)-(salen)Mn(III) In dichloromethane at 0℃; Mechanism; other silyl enol ethers and silyl ketene acetals; var. 5,5'-substituted (salen)Mn(III) complexes;
With sodium hypochlorite; 4-Phenylpyridine 1-oxide; phosphate buffer; 5,5'-MeO-substituted (R,R)-(salen)Mn(III) In dichloromethane at 0℃; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
With sodium hypochlorite; 4-Phenylpyridine 1-oxide; phosphate buffer; 5,5'-tBu-substituted (R,R)-(salen)Mn(III) In dichloromethane at 0℃; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
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    United Scientific Company Located in Shanghai of China , is a competitive player in the global specialty and fine chemical market. Fenghua has both the expertise and flexibility to produce a wide range of chemicals. Focusing on developing the innovat

    United Scientific Company (USC) Located in Shanghai of China , is a competitive player in the global specialty and fine chemical market. USC has both the expertise and flexibility

  • Shanghai united Scientific Co.,Ltd.

    China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:+86-21-53535353

    Address:28F No.900 huaihai Road Shanghai China

       Inquiry Now

  • L-Phenylacetyl Carbinol (~80% ee)

  • Casno:

    53439-91-1

    L-Phenylacetyl Carbinol (~80% ee)

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0

    FINETECH INDUSTRY LIMITED is a LONDON based CRO company providing drug discovery & development services to worldwide clients. FINETECH INDUSTRY LIMITED supplies the L-Phenylacetyl Carbinol (~80% ee), CAS:53439-91-1 with the most competitive price and

    Finetech Industry Limited is a company in England,which specializing in developing, manufacturing and marketing fine organic compounds and intermediates for the fine chemical and p

  • Finetech Industry Limited

    China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:86-27-87465837

    Address:wuhan

       Inquiry Now

  • 2-Propanone, 1-hydroxy-1-phenyl-, (1S)- CAS NO.53439-91-1

  • Casno:

    53439-91-1

    2-Propanone, 1-hydroxy-1-phenyl-, (1S)- CAS NO.53439-91-1

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0

    2-Propanone, 1-hydroxy-1-phenyl-, (1S)- CAS NO.53439-91-1Appearance:crystal, powder Storage:keep in dry and cool condition Package:25kg or according to cutomer's demand Application:Chemical research/pharma intermediate Transportation:By Sea,by Air,By

    Nanjing Raymon Biotech Co., Ltd. is specialized in developing and marketing middle & high level pharmaceutical intermediates. We are supplying different categories of high-quality

  • Nanjing Raymon Biotech Co., Ltd.

     China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:86-025-52181296

    Address:Block B, No. 918, Shuanglong Avenue

       Inquiry Now

  • L-Phenylacetyl Carbinol

  • Casno:

    53439-91-1

    L-Phenylacetyl Carbinol

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0

    shanghai sunflower pharmachem co.,ltd. founded in year 2731, is a premium supplier of pharmaceutical apis,and nutraceutical supplements. we build good relations with many gmp factories, which assures us supplying competitive price and prompt shipment

    Shanghai Normway pharmachem Co.,Ltd. founded in year 2015, is a premium supplier of pharmaceutical APIs,and nutraceutical supplements.Core products are glutathione reduced, mebhydr

  • Shanghai Normway Pharmachem Co.,Ltd.

    China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:86-21-50897098 13501889356

    Address:2F No. 450 Husong Road Minhang District Shanghai China

       Inquiry Now

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