Products Categories
CAS No.: | 537-92-8 |
---|---|
Name: | 3'-Methylacetanilide |
Article Data: | 144 |
Molecular Structure: | |
Formula: | C9H11NO |
Molecular Weight: | 149.192 |
Synonyms: | Aceto-m-aminotoluene;N-(3-Methylphenyl)acetamide;N-Acetyl-3-methylaniline;N-Acetyl-m-toluidine;N-m-Tolylacetamide;NSC 3103;m-Acetotoluide;m-Methylacetanilide;m-N-Acetyltoluidine;m-Tolylacetamide;m-Acetotoluidide(7CI,8CI);1-Acetamido-3-methylbenzene;3-Acetamidotoluene;3-Methylacetanilide;3'-Methylacetanilide; |
EINECS: | 208-678-1 |
Density: | 1.075 g/cm3 |
Melting Point: | 65-67 °C |
Boiling Point: | 303.758 °C at 760 mmHg |
Flash Point: | 175.156 °C |
Appearance: | white crystalline solid |
Hazard Symbols: | Xi |
Risk Codes: | 22-36/37/38 |
Safety: | 26-36 |
PSA: | 29.10000 |
LogP: | 2.02640 |
Conditions | Yield |
---|---|
In dichloromethane at 20℃; Inert atmosphere; | 100% |
With cadmium(II) oxide at 80℃; for 0.166667h; Neat (no solvent); Microwave irradiation; | 97% |
With pyridine; aluminum oxide at 129 - 131℃; for 2h; microwave irradiation; | 96% |
Conditions | Yield |
---|---|
In dichloromethane at 0 - 20℃; | 100% |
With hydroxyapatite supported copper(I) oxide In acetonitrile at 50℃; for 0.116667h; | 92% |
With triethylamine In dichloromethane at 0 - 25℃; | 92% |
Conditions | Yield |
---|---|
With indium; acetic acid In methanol at 20℃; for 1h; | 99% |
Stage #1: 1-methyl-3-nitrobenzene With sodium tetrahydroborate In water at 60 - 70℃; Green chemistry; Stage #2: acetic anhydride In water at 60 - 70℃; Green chemistry; | 94% |
Stage #1: 1-methyl-3-nitrobenzene In water for 0.0833333h; Stage #2: With sodium tetrahydroborate In water at 65℃; for 0.05h; Stage #3: acetic anhydride In water at 65℃; for 0.0333333h; Catalytic behavior; | 93% |
1-acetyl-2,3,4,6,7,8-hexahydropyrrolo[1,2-a]pyrimidinium tetraphenylborate
1-amino-3-methylbenzene
3-Methylacetanilide
Conditions | Yield |
---|---|
In acetonitrile at 80℃; for 24h; Inert atmosphere; | 99% |
tungsten hexacarbonyl
1-methyl-3-nitrobenzene
carbonic acid dimethyl ester
3-Methylacetanilide
Conditions | Yield |
---|---|
With di(rhodium)tetracarbonyl dichloride; 1,3-bis-(diphenylphosphino)propane; sodium phosphate; sodium iodide In water at 120℃; for 24h; Inert atmosphere; Sealed tube; | 99% |
Conditions | Yield |
---|---|
With platinum(II) acetylacetonate; 1-carboxyethyl-3-methylimidazolium hydrogen bisulfate; zinc diacetate; copper(II) bis(trifluoromethanesulfonate) at 60℃; for 7h; Reagent/catalyst; | 97.1% |
Conditions | Yield |
---|---|
Stage #1: 3-methylbenzenediazonium tetrafluoroborate; acetonitrile for 0.0166667h; Microwave irradiation; Stage #2: With water In diethyl ether | 97% |
Conditions | Yield |
---|---|
With tetrabutylammonium tetrafluoroborate In ethyl acetate at 20℃; for 24h; Electrochemical reaction; | 97% |
With tris(2,2'-bipyridyl)ruthenium dichloride In acetonitrile at 20℃; Irradiation; | 89% |
With copper(II) acetate monohydrate In acetonitrile at 80℃; for 18h; Temperature; Reagent/catalyst; Sealed tube; | 73% |
Conditions | Yield |
---|---|
With potassium tert-butylate at 130℃; for 0.5h; Inert atmosphere; Microwave irradiation; | 96% |
With Imidazole hydrochloride at 150℃; for 3h; Sealed tube; | 90% |
Stage #1: N,N-dimethyl acetamide With 1,1'-carbonyldiimidazole at 120 - 125℃; for 0.5h; Inert atmosphere; Stage #2: 1-amino-3-methylbenzene at 60 - 65℃; for 1.5h; Inert atmosphere; | 86% |
2,4,6-triacetyloxy-1,3,5-triazine
1-amino-3-methylbenzene
3-Methylacetanilide
Conditions | Yield |
---|---|
at 25℃; for 0.0833333h; neat (no solvent); | 95% |
Product Name: 3'-Methylacetanilide
The MF of 3'-Methylacetanilide(537-92-8) is C9H11NO.
The MW of 3'-Methylacetanilide(537-92-8) is 149.19.
Synonyms: 3'-METHYLACETANILIDE;3-METHYLACETANILIDE;(3-METHYLPHENYL)-ACETAMIDE;M-ACETOTOLUIDINE;N-ACETYL-M-TOLUIDINE;N1-(3-METHYLPHENYL)ACETAMIDE;ACETYL-M-TOLUIDINE;M-ACETOTOLUIDIDE
Product Categories: Anilines, Amides & Amines
Mol File: 537-92-8.mol
EINECS: 208-678-1
Surface Tension: 39.8 dyne/cm
Density: 1.074 g/ml
Flash Point: 175.2 °C
Enthalpy of Vaporization: 54.41 kJ/mol
Boiling Point: 303.8 °C at 760 mmHg
Vapour Pressure: 0.000912 mmHg at 25°C
mp: 65-67 °C(lit.)
CAS DataBase Reference: 537-92-8(CAS DataBase Reference)
NIST Chemistry Reference: 537-92-8(NIST)
EPA Substance Registry System: 537-92-8(EPA Substance)
1. | orl-mus LD50:1450 mg/kg | TXAPA9 Toxicology and Applied Pharmacology. 19 (1971),20. |