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Basic Information
| CAS No.: | 544-64-9 |
|---|---|
| Name: | MYRISTOLEIC ACID |
| Article Data: | 8 |
| Molecular Structure: | |
|
|
|
| Formula: | C14H26 O2 |
| Molecular Weight: | 226.359 |
| Synonyms: | 9-Tetradecenoicacid, (Z)- (8CI); (Z)-9-Tetradecenoic acid; 9(Z)-Tetradecenoic acid;9(Z)-Tetradecenoic acid; 9-cis-Tetradecenoic acid; Myristoleic acid;Myristolenic acid; Oleomyristic acid; cis-9-Tetradecenoic acid; cis-D9-Tetradecenoic acid |
| Density: | 0.913g/cm3 |
| Melting Point: |
−4.5-−4 °C(lit.) |
| Boiling Point: |
144 °C0.6 mm Hg(lit.) |
| Flash Point: | 206.5°C |
| Hazard Symbols: |
 Xi
|
| Risk Codes: | R36/37/38 |
| PSA: | 37.30000 |
| LogP: | 4.54810 |
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Synthetic route
Conditions
| Conditions | Yield |
|---|---|
| With sodium hydroxide In water; acetone for 14h; Heating; | A 80% B 50% |
- 24880-50-0
myristoleic acid ethyl ester
- 544-64-9
myristoleic acid
Conditions
| Conditions | Yield |
|---|---|
| With sodium hydroxide | |
| With sodium hydroxide In methanol | |
| With water; sodium hydroxide at 20℃; for 3h; |
- 55182-92-8
9-tetradecynoic acid
- 544-64-9
myristoleic acid
Conditions
| Conditions | Yield |
|---|---|
| With quinoline; hydrogen; palladium on barium sulfate In methanol |
- 35153-15-2
(Z)-9-tetradecen-1-ol
- 544-64-9
myristoleic acid
Conditions
| Conditions | Yield |
|---|---|
| With dipyridinium dichromate In N,N-dimethyl-formamide at 25℃; for 12h; Oxidation; |
- 17696-11-6
8-bromooctanoic acid
- 544-64-9
myristoleic acid
Conditions
| Conditions | Yield |
|---|---|
| Multi-step reaction with 2 steps 1: (i) LiNH2, liq. NH3, (ii) /BRN= 1756103/, THF 2: H2, quinoline / Pd-BaSO4 / methanol View Scheme | |
| Multi-step reaction with 5 steps 1: acetyl chloride / 4 h / 20 °C 2: 18 h / 20 °C 3: sodium phosphinate / 2 h / 40 °C 4: sodium hexamethyldisilazane / tetrahydrofuran / 2 h / -78 - 20 °C 5: sodium hydroxide; water / 3 h / 20 °C View Scheme |
Conditions
| Conditions | Yield |
|---|---|
| Multi-step reaction with 2 steps 1: (i) LiNH2, liq. NH3, (ii) /BRN= 1756103/, THF 2: H2, quinoline / Pd-BaSO4 / methanol View Scheme |
Conditions
| Conditions | Yield |
|---|---|
| Multi-step reaction with 3 steps 1: (i) O3, CH2Cl2, (ii) Ph3P 2: (i) K, HMPT, (ii) /BRN= 1769505/ 3: aq. NaOH / methanol View Scheme |
Conditions
| Conditions | Yield |
|---|---|
| Multi-step reaction with 2 steps 1: (i) K, HMPT, (ii) /BRN= 1769505/ 2: aq. NaOH / methanol View Scheme | |
| Multi-step reaction with 2 steps 1: sodium hexamethyldisilazane / tetrahydrofuran / 2 h / -78 - 20 °C 2: sodium hydroxide; water / 3 h / 20 °C View Scheme |
- 544-64-9
myristoleic acid
Conditions
| Conditions | Yield |
|---|---|
| Multi-step reaction with 3 steps 1: sodium phosphinate / 2 h / 40 °C 2: sodium hexamethyldisilazane / tetrahydrofuran / 2 h / -78 - 20 °C 3: sodium hydroxide; water / 3 h / 20 °C View Scheme |
- 29823-21-0
Ethyl 8-bromooctanoate
- 544-64-9
myristoleic acid
Conditions
| Conditions | Yield |
|---|---|
| Multi-step reaction with 4 steps 1: 18 h / 20 °C 2: sodium phosphinate / 2 h / 40 °C 3: sodium hexamethyldisilazane / tetrahydrofuran / 2 h / -78 - 20 °C 4: sodium hydroxide; water / 3 h / 20 °C View Scheme |
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