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5503-41-3

Basic Information
CAS No.: 5503-41-3
Name: RHODIUM ACETATE, BROWN, WATER SOLUBLE
Molecular Structure:
Molecular Structure of 5503-41-3 (RHODIUM ACETATE, BROWN, WATER SOLUBLE)
Formula: C2H4 O2 . 1/2 Rh
Molecular Weight: 223.03
Synonyms: Rhodiumacetate (7CI); Rhodium diacetate; Rhodium(II) acetate
EINECS: 255-707-9
Density: g/cm3
Boiling Point: 117.1°Cat760mmHg
Flash Point: 40°C
Hazard Symbols: Xi
Risk Codes: R36/38;
Safety: Poison by intraperitoneal route. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes. See also RHODIUM.
PSA: 80.26000
LogP: -2.48760
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Chemistry

IUPAC Name: Rhodium(2+) diacetate
Synonyms: Aceticacid,rhodium(2+)salt ; RH-110 ; Rhodiumdiacetate ; Rhodium acetate, brown, water soluble ; Rhodium (II) acetate ; Rhodium(II)acetate,dimer,Premion99.99%(metalsbasis),Rh46.2%min ; Rhodium(ii) acetate, dimer, premion ; Tetrakis(aceto)dirhodium(ii)
CAS NO: 5503-41-3
Molecular Formula of Rhodium(ii) acetate (CAS NO. 5503-41-3) : C4H6O4Rh
Molecular Weight of Rhodium(ii) acetate (CAS NO. 5503-41-3) : 220.99
Molecular Structure of Rhodium(ii) acetate (CAS NO. 5503-41-3) :
EINECS: 255-707-9
Mol File: 5503-41-3.mol
Flash Point: 40 °C
Enthalpy of Vaporization: 23.7 kJ/mol
Boiling Point: 117.1 °C at 760 mmHg
Vapour Pressure: 13.9 mmHg at 25°C

Toxicity Data With Reference

1.    

dni-mus:ast 10 µmol/L

    PSEBAA    Proceedings of the Society for Experimental Biology and Medicine. 145 (1974),1278.
2.    

dnd-mam:lym 100 µmol/L

    CCROBU    Cancer Chemotherapy Reports, Part 1. 59 (1975),611.
3.    

ipr-mus LD50:27 mg/kg

    PSEBAA    Proceedings of the Society for Experimental Biology and Medicine. 145 (1974),1278.

Safety Profile

Poison by intraperitoneal route. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes. See also RHODIUM.
Hazard CodesIrritantXi
Risk Statements 36/38
R36/38: Rhodium(ii) acetate (CAS NO. 5503-41-3) is irritating to eyes and skin.
Safety Statements 37/39-28-26-15
S15:Keep Rhodium(ii) acetate (CAS NO. 5503-41-3)
away from heat. 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S28:After contact with skin, wash immediately with plenty of soap-suds. 
S37/39:Wear suitable gloves and eye/face protection.


 

Standards and Recommendations

OSHA PEL: TWA 0.001 mg(Rh)/m3
ACGIH TLV: TWA 1 mg(Rh)/m3

Specification

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. 
Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage: Store in a cool, dry place. Store in a tightly closed container.