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55512-33-9

Basic Information
CAS No.: 55512-33-9
Name: Pyridat
Article Data: 2
Molecular Structure:
Molecular Structure of 55512-33-9 (Pyridat)
Formula: C19H23 Cl N2 O2 S
Molecular Weight: 378.923
Synonyms: CL 11344;Fenpyrate; Lentagran; O-(3-Phenyl-6-chloropyridazin-4-yl) octylthiocarbonate;Pl 3419; Pyridate; Tough
EINECS: 259-686-7
Density: 1.183 g/cm3
Melting Point: 27°
Boiling Point: 544.9 °C at 760 mmHg
Flash Point: 283.3 °C
Hazard Symbols:
Risk Codes: R38;R43;R50/53   
Safety: Moderately toxic by ingestion and skin contact. Experimental reproductive effects. When heated to decomposition it emits toxic vapors of NOx, SOx, and Cl.
Transport Information: UN 3077
PSA: 77.38000
LogP: 6.38950
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Chemistry

IUPAC Name: (6-Chloro-3-phenylpyridazin-4-yl) octylsulfanylformate
The MF of Fenpyrate (CAS NO.55512-33-9) is C19H23ClN2O2S.

                          
The MW of Fenpyrate (CAS NO.55512-33-9) is 378.9161.
Synonyms of Fenpyrate (CAS NO.55512-33-9): Carbonothioic acid, O-(6-chloro-3-phenyl-4-pyridazinyl) S-octyl ester ; O-(6-Chlor-3-phenylpyridazin-4-yl)-S-octylthiocarbonat ; pyridate ; Screen ; Thiocarbonate de O-(6-chloro-3-phenyl-4-pyridazinyle) et de S-octyle
Product Categories: PU - PZPesticides&Metabolites;Alpha sort;Herbicides;N-PAlphabetic;P;Pesticides&Metabolites;Pyridazine;Alphabetic
Index of Refraction: 1.56 
EINECS: 259-686-7
Density: 1.183 g/ml 
Flash Point: 283.3 °C
Boiling Point: 544.9 °C
Storage temp: APPROX (4°C) 
Merck: 13,8058

Uses

   Fenpyrate (CAS NO.55512-33-9) is selective postemergence herbicide. Stems and leaves absorbed quickly and it impede the Hill reaction of photosynthesis, so that leaves turn yellow and stop the growth of weeds, withering death. Applies to wheat, rice, corn and other cereal crops Control in broad-leaved weeds, particularly Galium aparine, Amaranthus retroflexus and some undergraduate weeds.

Production

It derived from 6-chloro-3-phenyl-pyridazine-4-Alcohol and S-octyl thio-carbonyl chloride in the presence of triethylamine with benzene as the solvent

Toxicity Data With Reference

1.    

orl-rat LD50:1970 mg/kg

    DEVEAA    Defense des Vegetaux. 38 (1984),310.
2.    

orl-mus LD50:10 g/kg

    DEVEAA    Defense des Vegetaux. 35 (1981),327.
3.    

skn-rbt LD50:3400 mg/kg

    FMCHA2    Farm Chemicals Handbook .(Meister Publishing,Willoughy, OH.: )1991,C257.
4.    

orl-qal LD50:1500 mg/kg

    PEMNDP    Pesticide Manual. 9 (1991),743.
5.    

orl-dck LD50:10 g/kg

    PEMNDP    Pesticide Manual. 9 (1991),743.
6.    

orl-brd LD50:10 g/kg

    PEMNDP    Pesticide Manual. 9 (1991),743.

Safety Profile

Moderately toxic by ingestion and skin contact. Experimental reproductive effects. When heated to decomposition it emits toxic vapors of NOx, SOx, and Cl.Safety information of Fenpyrate (CAS NO.55512-33-9):
Hazard Codes  IrritantXi,DangerousN
Risk Statements 
38 Irritating to the skin
43 May cause sensitization by skin contact
50/53 Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Safety Statements 
24 Avoid contact with skin
37 Wear suitable gloves
60 This material and/or its container must be disposed of as hazardous waste
61 Avoid release to the environment. Refer to special instructions safety data sheet
RIDADR  UN 3077
RTECS  FG3880000