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557-91-5

Basic Information
CAS No.: 557-91-5
Name: 1,1-Dibromoethane
Article Data: 34
Molecular Structure:
Molecular Structure of 557-91-5 (1,1-Dibromoethane)
Formula: C2H4 Br2
Molecular Weight: 187.862
Synonyms: 1,1-Dibromoethane;Ethylidene dibromide
Density: 2.127g/cm3
Melting Point: -63°C
Boiling Point: 104.7°Cat760mmHg
Flash Point: °C
Solubility: Insoluble in water
Appearance: clear colourless to brownish liquid
Hazard Symbols: Xn
Risk Codes: R40; R20/21/22
Safety: Moderately toxic by rectal route. Mutation data reported. Violent reaction with magnesium. When heated to decomposition it emits toxic fumes of Br. See also BROMIDES.
PSA: 0.00000
LogP: 2.12220
Synthetic route
74-88-4

methyl iodide

74-95-3

1,2-dibromomethane

A

557-91-5

1,1-Dibromoethane

B

H2

H2

Conditions
ConditionsYield
With tetraethylammonium chloride In acetonitrile Ambient temperature; electrochemical conditions (Fe cathode);A 55.9%
B n/a
74-96-4

ethyl bromide

557-91-5

1,1-Dibromoethane

Conditions
ConditionsYield
With chloroethane; bromine at 40 - 100℃; under 37 Torr; Irradiation; temperature dependence of the relative rate constants;
With bromine at 170℃;
With bromine at 198℃; unter Belichtung bei Abwesenheit von Eisen;
593-60-2

Vinyl bromide

557-91-5

1,1-Dibromoethane

Conditions
ConditionsYield
With hydrogen bromide
With water; hydrogen bromide
With hydrogen bromide; acetic acid
593-60-2

Vinyl bromide

A

557-91-5

1,1-Dibromoethane

B

106-93-4

ethylene dibromide

Conditions
ConditionsYield
With magnesium hydrosilicate; hydrogen bromide
75-34-3

1,1-dichloroethane

557-91-5

1,1-Dibromoethane

Conditions
ConditionsYield
With aluminum tri-bromide
5875-25-2

2-bromo-propionic acid amide

557-91-5

1,1-Dibromoethane

Conditions
ConditionsYield
With sodium hypobromide
75-07-0

acetaldehyde

557-91-5

1,1-Dibromoethane

Conditions
ConditionsYield
With phosphorus trichloride dibromide
106-93-4

ethylene dibromide

557-91-5

1,1-Dibromoethane

Conditions
ConditionsYield
at 300 - 315℃;
at 300℃;
598-72-1

2-Bromopropionic acid

557-91-5

1,1-Dibromoethane

Conditions
ConditionsYield
With potassium hydroxide; platinum Electrolysis;
123-63-7

paracetaldehyde

557-91-5

1,1-Dibromoethane

Conditions
ConditionsYield
With phosphorus trichloride dibromide
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Chemistry

Product Name: 1,1-Dibromoethane 
CAS Registry Number: 557-91-5 
Synonyms: 1,1-Dibromoethane ; CCRIS 8552 ; EINECS 209-184-9 ; Ethylidene bromide ; Ethylidene dibromide ; HSDB 7382 
Systematic Name: 1,1-Dibromoethane ; Ethane, 1,1-dibromo- 
IUPAC Name: 1,1-dibromoethane
Molecular Weight: 187.86116 [g/mol]
Molecular Formula: C2H4Br2
XLogP3-AA: 2.3
EINECS: 209-184-9 
Surface Tension: 34.1 dyne/cm
Density: 2.127 g/cm3 
Enthalpy of Vaporization: 32.95 kJ/mol
Boiling Point: 104.7 °C at 760 mmHg
Vapour Pressure: 35.4 mmHg at 25°C
Refractive Index: 1.509-1.512
Following is the molecular structure of 1,1-Dibromoethane (CAS NO.557-91-5) is:

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
rabbit LDLo rectal 1250mg/kg (1250mg/kg)   Journal of Pharmacology and Experimental Therapeutics. Vol. 34, Pg. 223, 1928.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Moderately toxic by rectal route. Mutation data reported. Violent reaction with magnesium. When heated to decomposition it emits toxic fumes of Br. See also BROMIDES.
Safty information about 1,1-Dibromoethane (CAS NO.557-91-5) is:
Hazard Codes:
HarmfulXn
Risk Statements:
R40:Limited evidence of a carcinogenic effect. 
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed.
Safety Statements:
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S36/37:Wear suitable protective clothing and gloves.
RIDADR: 2810
RTECS: KH9000000
HazardClass: 6.1(b)
PackingGroup: III

Specification

 1,1-Dibromoethane (CAS NO.557-91-5) is a clear colourless to brownish liquid.
First Aid Measures about it:
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion: Get medical aid. Wash mouth out with water.
Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. 
Handling and Storage about it:
Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Use only in a chemical fume hood.
Storage: Store in a cool, dry place. Store in a tightly closed container.