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| CAS No.: | 56183-63-2 |
|---|---|
| Name: | Bis(diisopropylamino)chlorophosphine |
| Article Data: | 31 |
| Molecular Structure: | |
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| Formula: | C12H28ClN2P |
| Molecular Weight: | 266.794 |
| Synonyms: | Phosphorodiamidouschloride, tetrakis(1-methylethyl)- (9CI);Bis(diisopropylamino)chlorophosphine;Chlorobis(N,N-diisopropyl)phosphoramidite;Chlorobis(N,N-diisopropylamino)phosphine;Chlorobis(diisopropylamino)phosphine;Tetraisopropylphosphorodiamidous chloride; |
| Melting Point: | 100-104 °C(lit.) |
| Boiling Point: | 290.9 °C at 760 mmHg |
| Flash Point: | 129.8 °C |
| Appearance: | white to light yellow crystal powde |
| Hazard Symbols: | C |
| Risk Codes: | 14-34 |
| Safety: | 26-27-28-36/37/39-45 |
| PSA: | 20.07000 |
| LogP: | 4.68970 |
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Specification
The Phosphorodiamidouschloride, N,N,N',N'-tetrakis(1-methylethyl)-, with the CAS registry number 56183-63-2, has the systematic name of N,N,N',N'-tetrapropan-2-ylphosphorodiamidous chloride. It is a kind of white to light yellow crystal powder, and belongs to the following product categories: Ligand; Catalysis and Inorganic Chemistry; Phosphorus Compounds; Phosphorus Precursors. And the molecular formula of the chemical is C12H28ClN2P.
The characteristics of Phosphorodiamidouschloride, N,N,N',N'-tetrakis(1-methylethyl)- are as followings: (1)ACD/LogP: 4.91; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 4.87; (4)ACD/LogD (pH 7.4): 4.91; (5)#H bond acceptors: 2; (6)#H bond donors: 0; (7)#Freely Rotating Bonds: 6; (8)Polar Surface Area: 20.07 Å2; (9)Flash Point: 129.8 °C; (10)Enthalpy of Vaporization: 53.03 kJ/mol; (11)Boiling Point: 290.9 °C at 760 mmHg; (12)Vapour Pressure: 0.00201 mmHg at 25°C.
You should be cautious while dealing with this chemical. It reacts violently with water, and irritates to eyes, respiratory system and skin. Therefore, you had better take the following instructions: Take off immediately all contaminated clothing; Wear suitable protective clothing, gloves and eye/face protection; After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer); In case of contacting with eyes, rinse immediately with plenty of water and seek medical advice; In case of accident or if you feel unwell, seek medical advice immediately (show label where possible).
Uses of Phosphorodiamidouschloride, N,N,N',N'-tetrakis(1-methylethyl)-: It can react with 4-nitro-phenethyl alcohol to produce [2-(4-Nitrophenyl)ethyl]bis(diisopropylamino)phosphine. This reaction will need reagent Et3N, and the menstruum diethyl ether. The reaction time is 16 hours with ambient temperature, and the yield is about 95%.
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Addtionally, the following datas could be converted into the molecular structure:
(1)SMILES: CC(C)N(C(C)C)P(N(C(C)C)C(C)C)Cl
(2)InChI: InChI=1/C12H28ClN2P/c1-9(2)14(10(3)4)16(13)15(11(5)6)12(7)8/h9-12H,1-8H3
(3)InChIKey: FEHUTHGOLLQBNW-UHFFFAOYAF